Method for measuring physical properties of hydrocarbons

Claim 1

A method for determining at least one physical property of a sample hydrocarbon using spectrometry, said method comprising the steps of: (a) selecting a reference hydrocarbon; (b) selecting a teaching set of hydrocarbons, each having at least one physical property of the at least one physical property to be determined; (c) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell; (d) placing one of said hydrocarbons from said teaching set into said sample cell; (e) measuring a reference absorption spectrum of said reference hydrocarbon; (f) measuring a teaching absorption spectrum of said hydrocarbon within said sample cell wherein a set of wavelengths used for said measuring is the same as a set used in step (e); (g) combining said reference absorption spectrum and said teaching absorption spectrum to create a teaching adjusted spectrum; (h) computing a plurality of teaching sample values, one for each of a plurality of sample points of said teaching adjusted spectrum; (i) inputting each of said teaching sample values into a multivariate analysis system to build a multivariate calibration model; (j) repeating steps (d) through (i) for each hydrocarbon in said teaching set; (k) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell containing said unknown-hydrocarbon sample; (l) measuring a test reference absorption spectrum of said reference hydrocarbon in said reference cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (e); (m) measuring a sample absorption spectrum of said unknown hydrocarbon in said sample cell wherein a set of wavelengths used for said measuring is the same as a set used in step (e); (n) combining said test reference absorption spectrum and said sample absorption spectrum to create a test adjusted spectrum; (o) computing a plurality of test sample values, one for each of a plurality of sample points of said second adjusted spectrum; and (p) inputting each of said test sample values into said multivariate analysis system to compare said test sample values to said multivariate calibration model to determine said at least one physical property of said sample hydrocarbon.

Claim 2

A method for determining at least one physical property of a sample hydrocarbon using spectrometry, said method comprising the steps of: (a) selecting a reference hydrocarbon; (b) selecting a teaching set of hydrocarbons, each having at least one physical property of the at least one physical property to be determined; (c) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell; (d) placing one of said hydrocarbons from said teaching set into said sample cell; (e) measuring a reference absorption spectrum of said reference hydrocarbon; (f) measuring a teaching absorption spectrum of said hydrocarbon within said sample cell wherein a set of wavelengths used for said measuring is the same as a set used in step (e); (g) combining said reference absorption spectrum and said teaching absorption spectrum to create a teaching adjusted spectrum; (h) computing a plurality of teaching sample values, one for each of a plurality of sample points of said teaching adjusted spectrum; (i) inputting each of said teaching sample values into a multivariate analysis system to build a multivariate calibration model; (j) repeating steps (d) through (i) for each hydrocarbon in said teaching set; (k) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell containing said unknown-hydrocarbon sample; (l) measuring a test reference absorption spectrum of said reference hydrocarbon in said reference cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (e); (m) measuring a sample absorption spectrum of said unknown hydrocarbon in said sample cell wherein a set of wavelengths used for said measuring is the same as a set used in step (e); (n) combining said test reference absorption spectrum and said sample absorption spectrum to create a test adjusted spectrum; (o) computing a plurality of test sample values, one for each of a plurality of sample points of said second adjusted spectrum; and (p) inputting each of said test sample values into said multivariate analysis system to compare said test sample values to said multivariate calibration model to determine said at least one physical property of said sample hydrocarbon.

Claim 10

A method for determining at least one physical property of a sample hydrocarbon using spectrometry, said method comprising the steps of: (a) selecting a reference hydrocarbon and placing said reference hydrocarbon in a reference cell adjacent a sample cell; (b) selecting a teaching set of hydrocarbons, each having at least one physical property of the at least one physical property to be determined; (c) selecting one hydrocarbon from said teaching set and placing said selected hydrocarbon in said sample cell; (d) measuring a reference absorption spectrum of said reference hydrocarbon; (e) measuring a teaching absorption spectrum of said hydrocarbon in said sample cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (f) measuring a peak location and area of said reference spectrum; (g) subtracting said reference absorption spectrum peak location from each wavelength of said teaching absorption spectrum and dividing said reference absorption area into each absorption value of said teaching absorption spectrum to create an adjusted spectrum; (h) computing a plurality of sample values each sampling one point of said adjusted spectrum; (i) inputting each of said teaching sample values into a multivariate analysis system to build a multivariate calibration model; (j) repeating steps (c) through (i) for each hydrocarbon in said teaching set; (k) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell containing said unknown hydrocarbon sample; measuring a test reference absorption spectrum of said reference hydrocarbon in said reference cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (m) measuring a sample absorption spectrum of said unknown hydrocarbon in said sample cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (n) measuring a peak location and area of said test reference spectrum; (o) subtracting said test reference absorption spectrum peak location from each wavelength of said unknown hydrocarbon absorption spectrum and dividing said reference absorption area into each absorption value of said unknown hydrocarbon absorption spectrum to create a test adjusted spectrum; (p) computing a plurality of test sample values each sampling one point of said test adjusted spectrum; and (q) inputting each of said test sample values into said multivariate analysis system to compare said test sample values to said multivariate calibration model to determine said physical properties.

Claim 11

A method for determining at least one physical property of a sample hydrocarbon using spectrometry, said method comprising the steps of: (a) selecting a reference hydrocarbon and placing said reference hydrocarbon in a reference cell adjacent a sample cell; (b) selecting a teaching set of hydrocarbons, each having at least one physical property of the at least one physical property to be determined; (c) selecting one hydrocarbon from said teaching set and placing said selected hydrocarbon in said sample cell; (d) measuring a reference absorption spectrum of said reference hydrocarbon; (e) measuring a teaching absorption spectrum of said hydrocarbon in said sample cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (f) measuring a peak location and area of said reference spectrum; (g) subtracting said reference absorption spectrum peak location from each wavelength of said teaching absorption spectrum and dividing said reference absorption area into each absorption value of said teaching absorption spectrum to create an adjusted spectrum; (h) computing a plurality of sample values each sampling one point of said adjusted spectrum; (i) inputting each of said teaching sample values into a multivariate analysis system to build a multivariate calibration model; (j) repeating steps (c) through (i) for each hydrocarbon in said teaching set; (k) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell containing said unknown hydrocarbon sample; measuring a test reference absorption spectrum of said reference hydrocarbon in said reference cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (m) measuring a sample absorption spectrum of said unknown hydrocarbon in said sample cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (n) measuring a peak location and area of said test reference spectrum; (o) subtracting said test reference absorption spectrum peak location from each wavelength of said unknown hydrocarbon absorption spectrum and dividing said reference absorption area into each absorption value of said unknown hydrocarbon absorption spectrum to create a test adjusted spectrum; (p) computing a plurality of test sample values each sampling one point of said test adjusted spectrum; and (q) inputting each of said test sample values into said multivariate analysis system to compare said test sample values to said multivariate calibration model to determine said physical properties.

Claim 18

A method for determining the antiknock index of a sample gasoline using spectrometry, said method comprising the steps of: (a) selecting a reference hydrocarbon and placing said reference hydrocarbon in a reference cell adjacent a sample cell; (b) selecting a teaching set of gasolines, each having an antiknock index within a range of antiknock indexes for said sample gasoline; (c) selecting one gasoline from said teaching set and placing said selected gasoline in said sample cell; (d) measuring a reference absorption spectrum of said reference hydrocarbon; (e) measuring a teaching absorption spectrum of one gasoline within said teaching set, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (f) measuring a peak location and area of said reference spectrum; (g) subtracting said reference absorption spectrum peak location from each wavelength of said teaching absorption spectrum and dividing said reference absorption area into each absorption value of said teaching absorption spectrum to create a teaching adjusted spectrum; (h) computing a plurality of teaching sample values, one for each of a plurality of sample points of said teaching adjusted spectrum; (i) inputting each of said sample values into a multivariate analysis system to build a multivariate calibration model; (j) repeating steps (c) through (i) for each gasoline in said teaching set; (k) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell containing said sample gasoline; measuring a test reference absorption spectrum of said reference hydrocarbon in said reference cell, Wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (m) measuring a sample absorption spectrum of said sample gasoline in said sample cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (n) measuring a peak location and area of said test reference spectrum; (o) subtracting said test reference absorption spectrum peak location from each wavelength of said sample absorption spectrum and dividing said reference absorption area into each absorption value of said unknown hydrocarbon absorption spectrum to create a test adjusted spectrum; (p) computing a plurality of test sample values, one for each of a plurality of sample points of said second adjusted spectrum; and (q) inputting each of said test sample values into said multivariate analysis system to compare said test sample values to said multivariate calibration model to determine said antiknock index.

Claim 19

A method for determining the antiknock index of a sample gasoline using spectrometry, said method comprising the steps of: (a) selecting a reference hydrocarbon and placing said reference hydrocarbon in a reference cell adjacent a sample cell; (b) selecting a teaching set of gasolines, each having an antiknock index within a range of antiknock indexes for said sample gasoline; (c) selecting one gasoline from said teaching set and placing said selected gasoline in said sample cell; (d) measuring a reference absorption spectrum of said reference hydrocarbon; (e) measuring a teaching absorption spectrum of one gasoline within said teaching set, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (f) measuring a peak location and area of said reference spectrum; (g) subtracting said reference absorption spectrum peak location from each wavelength of said teaching absorption spectrum and dividing said reference absorption area into each absorption value of said teaching absorption spectrum to create a teaching adjusted spectrum; (h) computing a plurality of teaching sample values, one for each of a plurality of sample points of said teaching adjusted spectrum; (i) inputting each of said sample values into a multivariate analysis system to build a multivariate calibration model; (j) repeating steps (c) through (i) for each gasoline in said teaching set; (k) placing said reference hydrocarbon in a reference cell in thermal contact with a sample cell containing said sample gasoline; measuring a test reference absorption spectrum of said reference hydrocarbon in said reference cell, Wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (m) measuring a sample absorption spectrum of said sample gasoline in said sample cell, wherein a set of wavelengths used for said measuring is the same as a set used in step (d); (n) measuring a peak location and area of said test reference spectrum; (o) subtracting said test reference absorption spectrum peak location from each wavelength of said sample absorption spectrum and dividing said reference absorption area into each absorption value of said unknown hydrocarbon absorption spectrum to create a test adjusted spectrum; (p) computing a plurality of test sample values, one for each of a plurality of sample points of said second adjusted spectrum; and (q) inputting each of said test sample values into said multivariate analysis system to compare said test sample values to said multivariate calibration model to determine said antiknock index.