Patent US5401060A successfully refreshed from Google Patents.
US5401060A
Expired / Lapsed
US
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Document with heat and pressure sensitive chromogentic composition thereon
Assignee: MOORE WALLACE USA LLC
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Filing: 1993-06-14
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Granted: 1995-03-28
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Expires: 2013-06-14
Abstract
Abstract A pressure and heat-sensitive composition comprising chromogen-containing pressure-rupturable microcapsules and heat-sensitive color developer useful for verification of document authenticity system when applied as a localized coating on documents, such as checks and prescriptions. Quickly striking the chromogenic composition with a fingernail or blunt object to generate pressure and heat in the coating produces a colored image by friction. The chromogenic composition possesses a fugitive characteristic, whereby the colored image gradually disappears and can be made to reappear when the chromogenic coating is again subjected to external pressure and heat. This feature can be used for repeated verification of the authenticity of the document.
Inventors
- 👤 John C. H. Chang
- 👤 Richard H. Johnson
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 22:04
CPC Classifications
B; B41; B41M; B41M3/00; B41M3/14; B41M3/142; G; G07; G07D; G07D7/00; G07D7/14; B41M5/00; B41M5/124; B41M5/165; Y; Y10; Y10T; Y10T428/00; Y10T428/24; Y10T428/24802; Y10T428/24835; Y10T428/249921; Y10T428/249994; Y10T428/249995; Y10T428/249997
Claims Analysis
Total Claims: 31
Claim 1
Independent Claim
153 words
A document comprising: a support having a first surface and a second surface, said first surface having a localized coating of a heat and pressure-sensitive chromogenic composition, said composition comprising: (a) chromogen-containing microscopic pressure-rupturable capsules, and (b) a solid, heat-sensitive color developing material having a softening point of at least about 40° C.; said localized coating of said capsules and said color developing material being formed from a mixture of said capsules and color developing material, from superposed coatings of said capsules and said color developing material, or from superposed printing and coating of said capsules and said color developing material, said chromogen and said color developing material reacting only under application of both external pressure and heat, said external pressure causing said capsules to rupture and release said chromogen and said external heat causing said heat-sensitive color developing material to soften and react with said chromogen to produce a visible colored image.
Claim 2
Dependent Claim
153 words
A document comprising: a support having a first surface and a second surface, said first surface having a localized coating of a heat and pressure-sensitive chromogenic composition, said composition comprising: (a) chromogen-containing microscopic pressure-rupturable capsules, and (b) a solid, heat-sensitive color developing material having a softening point of at least about 40° C.; said localized coating of said capsules and said color developing material being formed from a mixture of said capsules and color developing material, from superposed coatings of said capsules and said color developing material, or from superposed printing and coating of said capsules and said color developing material, said chromogen and said color developing material reacting only under application of both external pressure and heat, said external pressure causing said capsules to rupture and release said chromogen and said external heat causing said heat-sensitive color developing material to soften and react with said chromogen to produce a visible colored image.
Claim 3
Dependent Claim
30 words
The document of claim 1, wherein said localized coating of said chromogenic composition is present in at least one verification area on said support for verifying authenticity of said document.
Claim 4
Dependent Claim
33 words
The document of claim 2, wherein said localized coating of said chromogenic composition comprises a substantially homogeneous mixture of said (a) chromogen-containing microscopic pressure-rupturable capsules, and (b) a solid, heat-sensitive color developing material.
Claim 5
Dependent Claim
17 words
The document of claim 2, wherein said support bears an information area having a visible principal image.
Claim 6
Dependent Claim
14 words
The document of claim 4, wherein said visible principal image includes a dollar amount.
Claim 7
Dependent Claim
22 words
The document of claim 1, wherein said verification area comprises a localized chromogenic composition in the form of a latent image message.
Claim 8
Dependent Claim
21 words
The document of claim 2, wherein said visible colored image will fade away within about thirty minutes to a few days.
Claim 9
Dependent Claim
25 words
The document of claim 7, wherein said localized coating can be repeatedly subjected to external heat and pressure and to produce a visible colored image.
Claim 10
Dependent Claim
30 words
The document of claim 1, wherein said heat-sensitive color developer comprises a color developer compound having a melting point in the range of about 40° C. to about 200° C.
Claim 11
Dependent Claim
24 words
The document of claim 9, wherein said color developer compound has a melting point in the range of about 40° to about 140° C.
Claim 12
Dependent Claim
15 words
The document of claim 1, wherein said microcapsules additionally contain an ultraviolet light absorbing compound.
Claim 13
Dependent Claim
14 words
The document of claim 11 wherein said ultraviolet light absorbing compound is a benzotriazole.
Claim 14
Dependent Claim
32 words
The document of claim 12 wherein said ultraviolet light absorbing compound is present in an amount of from about 5 to about 150 weight percent based upon the weight of said chromogen.
Claim 15
Dependent Claim
32 words
The document of claim 13 wherein said ultraviolet light absorbing compound is present in an amount of from about 20 to about 80 weight percent based upon the weight of said chromogen.
Claim 16
Dependent Claim
18 words
The document of claim 1 wherein said pressure-rupturable microcapsules additionally contain a hindered phenol to stabilize said chromogen.
Claim 17
Dependent Claim
25 words
The document of claim 1 wherein said hindered phenol antioxidant is Irganox 129, Irganox 245, Irganox 1010, Irganox 1035, Irganox MD 1024 or Irganox 1076.
Claim 18
Dependent Claim
30 words
The document of claim 16 wherein said hindered phenol is present in an amount of from about 5 to about 150 weight percent based upon the weight if said chromogen.
Claim 19
Dependent Claim
30 words
The document of claim 17 wherein said hindered phenol is present in an amount of from about 20 to about 80 weight percent based upon the weight of said chromogen.
Claim 20
Dependent Claim
20 words
The document of claim 1, wherein the combination of external pressure and heat are provided by frictionally applying a stylus.
Claim 21
Dependent Claim
41 words
The document of claim 1, wherein said color developing material comprises finely divided inorganic particles each substantially surrounded by a coating of a color developer compound, said inorganic particles having a melting point greater than that of said color developer compound.
Claim 22
Dependent Claim
23 words
The document of claim 20, wherein said particles have an average diameter in the range of between about 0.8 and about 5 microns.
Claim 23
Dependent Claim
23 words
The document of claim 20, wherein said inorganic particles are calcium carbonate, clay, talc, barium sulfate, magnesium sulfate, aluminum oxide or zinc oxide.
Claim 24
Dependent Claim
12 words
The document of claim 22, wherein said inorganic particles are calcium carbonate.
Claim 25
Dependent Claim
22 words
The document of claim 20, wherein said color developer compound has a melting point of between about 40° and about 200° C.
Claim 26
Dependent Claim
10 words
A paper coated with the chromogenic composition of claim 24.
Claim 27
Dependent Claim
13 words
The paper of claim 25, wherein said chromogenic coating comprises a localized coating.
Claim 28
Dependent Claim
43 words
The document of claim 20, wherein said color developing material is produced by melting said color developer compound, mixing said melted color developer compound with finely divided particles of said inorganic particle to surround and coat said particles, and grinding said coated particles.
Claim 29
Dependent Claim
20 words
The document of claim 1, wherein said document is a negotiable instrument, a pharmaceutical prescription blank or a redeemable coupon.
Claim 30
Dependent Claim
13 words
The document of claim 28, wherein said document is a pharmaceutical prescription blank.
Claim 31
Dependent Claim
14 words
The document of claim 1, wherein external heat is a temperature above ambient temperature.
References Cited (Backward Citations)
US2929736A
Cited
US3713861A
Cited
US3829133A
Cited
US4037007A
Cited
US4186020A
Cited
GB1520919A
Cited
US4183989B1
Cited
US4183989A
Cited
US4140733A
Cited
DE2722427A1
Cited
US4210346A
Cited
US4109047A
Cited
US4303307A
Cited
US4175774B1
Cited
US4175774A
Cited
US4197346A
Cited
DE2913321A1
Cited
US4360548A
Cited
US4425386B1
Cited
US4425386A
Cited
US4846502A
Cited
US4726608A
Cited
US5212219A
Cited
US4839396A
Cited
US4873219A
Cited
WO1991000390A1
Cited
US5132034A
Cited
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| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1998-03-27 | 1998-09-26 | 1999-03-28 | $2000.00 | Window Closed / Lapsed |
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