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US5397614A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure sensitive adhesive composition which is water dispersible under alkaline pH conditions

Assignee: 3M Co
•
Filing: 1993-07-16
•
Granted: 1995-03-14
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Expires: 2013-07-16
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Abstract

Abstract A pressure sensitive adhesive which is dispersible at an alkaline pH but not at an acidic or a neutral pH is disclosed. The adhesive is essentially free from plasticizers (i.e., it contains less than 0.1 part of plasticizer per part of polymer). The polymer is formed from A, B and C monomers. The A monomer is hydrophobic and is an acrylic or methacrylic ester of a non-tertiary C 2 -C 14 alcohol. It comprises from 50 to 80 weight % of the polymer. The B monomer contains β-carboxyethyl acrylate (BCEA) or a salt thereof or a mixture of BCEA or a salt thereof with a vinyl carboxylic acid or a salt thereof. The polymer contains from 10 to 30 weight % of B monomer. The acid groups of the polymer have been neutralized with from 0.5 to 2 equivalents of an alkali metal hydroxide. The C monomer is an X--Y--Z macromer. X is copolymerizable with the A and B monomers. Y is a divalent linking group. Z is a water dispersible group that contains at least two units which are essentially unreactive under free radical conditions used to form the polymer. C comprises from 10 to 30 weight % of the polymer.

Inventors

  • 👤 Gregg A. Patnode
  • 👤 Donald R. Battles
  • 👤 Francois C. D'Haese

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 16:30
CPC Classifications
C; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/062; C09J7/00; C09J7/30; C09J7/38; C09J7/381; C09J7/385; C08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L33/062; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10T; Y10T428/00; Y10T428/14; Y10T428/1462; Y10T428/28; Y10T428/2813; Y10T428/283; Y10T428/2852; Y10T442/00; Y10T442/20; Y10T442/2738; Y10T442/2754

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 286 words
A pressure sensitive adhesive composition which is dispersible at an alkaline pH but not at an acidic or neutral pH, comprising (a) a polymer formed from A, B, and C monomers wherein A is a hydrophobic monomer selected from the group consisting of an acrylic or a methacrylic ester of a non-tertiary alcohol having from 2 to 14 carbon atoms, wherein A comprises from 50 to 80% by weight of A plus B plus C B is a monomer which contains (1) β-carboxyethyl acrylate or a salt thereof, (2) a mixture of the β-carboxyethyl acrylate or the salt thereof and a vinyl carboxylic acid or a salt thereof other than the carboxyethyl acrylate or the salt of the carboxyethyl acrylate, wherein B comprises from 10 to 30% by weight of A plus B plus C, and wherein the carboxylic acid groups of said polymer have been neutralized with from about 0.5 to about 2 equivalents of an alkali metal hydroxide per carboxylic acid group, and wherein when the mixture of the β-carboxyethyl acrylate and the vinyl carboxylic acid is used, the β-carboxyethyl acrylate comprises at least 10% by weight of A plus B plus C, and C is a water-dispersible macromolecular monomer which has the formula X--Y--Z wherein X is a moiety copolymerizable with A and B, Y is a divalent linking group which joins X to Z and Z is a water-dispersible group which contains at least two units which are essentially unreactive under free radical initiated copolymerization conditions used to form the polymer, and wherein C comprises from 10 to 30% by weight of A plus B plus C; and (b) less than about 0.1 part of a plasticizer per part of said polymer.
Claim 2
Dependent Claim 286 words
A pressure sensitive adhesive composition which is dispersible at an alkaline pH but not at an acidic or neutral pH, comprising (a) a polymer formed from A, B, and C monomers wherein A is a hydrophobic monomer selected from the group consisting of an acrylic or a methacrylic ester of a non-tertiary alcohol having from 2 to 14 carbon atoms, wherein A comprises from 50 to 80% by weight of A plus B plus C B is a monomer which contains (1) β-carboxyethyl acrylate or a salt thereof, (2) a mixture of the β-carboxyethyl acrylate or the salt thereof and a vinyl carboxylic acid or a salt thereof other than the carboxyethyl acrylate or the salt of the carboxyethyl acrylate, wherein B comprises from 10 to 30% by weight of A plus B plus C, and wherein the carboxylic acid groups of said polymer have been neutralized with from about 0.5 to about 2 equivalents of an alkali metal hydroxide per carboxylic acid group, and wherein when the mixture of the β-carboxyethyl acrylate and the vinyl carboxylic acid is used, the β-carboxyethyl acrylate comprises at least 10% by weight of A plus B plus C, and C is a water-dispersible macromolecular monomer which has the formula X--Y--Z wherein X is a moiety copolymerizable with A and B, Y is a divalent linking group which joins X to Z and Z is a water-dispersible group which contains at least two units which are essentially unreactive under free radical initiated copolymerization conditions used to form the polymer, and wherein C comprises from 10 to 30% by weight of A plus B plus C; and (b) less than about 0.1 part of a plasticizer per part of said polymer.
Claim 3
Dependent Claim 30 words
The pressure sensitive adhesive of claim 1 wherein said carboxylic acid groups have been neutralized with from 0.75 to 1.5 equivalents of said alkali metal hydroxide per carboxylic acid group.
Claim 4
Dependent Claim 57 words
The pressure sensitive adhesive of claim 1 wherein said A monomer comprises from 60 to 75% by weight of A plus B plus C, said B monomer comprises from 10 to 20% by weight of A plus B plus C, and said C monomer comprises from 10 to 30% by weight of A plus B plus C.
Claim 5
Dependent Claim 23 words
The pressure sensitive adhesive of claim 1 wherein said B monomer is a mixture of β-carboxyethyl acrylate, acrylic acid, and acrylic acid oligomers.
Claim 6
Dependent Claim 24 words
The pressure sensitive adhesive of claim 1 wherein said C monomer has a weight average molecular weight in the range of 350 to 5,000.
Claim 7
Dependent Claim 24 words
The pressure sensitive adhesive of claim 5 wherein said C monomer has a weight average molecular weight in the range of 400 to 750.
Claim 8
Dependent Claim 26 words
The pressure sensitive adhesive of claim 5 wherein said C monomer has an inherent viscosity of from 0.7 to 1.5 dl/g in 2-butanone at 27.5° C.
Claim 9
Dependent Claim 15 words
A pressure sensitive adhesive tape comprising a layer of pressure sensitive adhesive of claim 1.
Claim 10
Dependent Claim 25 words
The pressure sensitive adhesive tape of claim 8 further comprising a supporting layer carrying said pressure sensitive adhesive layer on at least one surface thereof.
Claim 11
Dependent Claim 16 words
The pressure sensitive adhesive tape of claim 9 wherein said supporting layer is a release liner.
Claim 12
Dependent Claim 23 words
The pressure sensitive adhesive tape of claim 9 wherein said supporting layer and said pressure sensitive adhesive layer are anchored to one another.
Claim 13
Dependent Claim 18 words
The pressure sensitive adhesive tape of claim 11 wherein said supporting layer is dispersible at an alkaline pH.
Claim 14
Dependent Claim 14 words
The pressure sensitive adhesive tape of claim 11 wherein said supporting layer is polymeric.
Claim 15
Dependent Claim 18 words
The pressure sensitive adhesive tape of claim 13 wherein said polymeric layer is dispersible at an alkaline pH.
Claim 16
Dependent Claim 21 words
The pressure sensitive adhesive tape of claim 9 wherein said supporting layer carries said pressure sensitive adhesive on opposed surfaces thereof.
Claim 17
Dependent Claim 14 words
A fabric bearing a portion of the pressure sensitive adhesive tape of claim 8.
Claim 18
Dependent Claim 14 words
A fabric according to claim 16 in the form of a mammalian body covering.
Claim 19
Dependent Claim 21 words
A closure system comprising an article to be closed and a portion of the pressure sensitive adhesive tape of claim 8.
Claim 20
Dependent Claim 15 words
The pressure sensitive adhesive tape of claim 11 in the form of a sterilization indicator.
Claim 21
Dependent Claim 15 words
A polymer film bearing a portion of the pressure sensitive adhesive tape of claim 8.
Claim 22
Dependent Claim 15 words
A polymer film according to claim 20 in the form of a mammalian body covering.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-03-13 1998-09-12 1999-03-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-03-13 2002-09-12 2003-03-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-03-13 2006-09-12 2007-03-14 $7700.00 Window Closed / Lapsed

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