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US5380779A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure sensitive adhesive composition which is repulpable under acidic pH conditions

Assignee: 3M Co
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Filing: 1994-03-21
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Granted: 1995-01-10
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Expires: 2014-03-21
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Abstract

Abstract A pressure sensitive adhesive composition is described which is water-dispersible under acidic conditions. The composition comprises a terpolymer of a hydrophobic monomeric acrylic or methacrylic ester of a non-tertiary alcohol (monomer A); a polar monomer copolymerizable with said A monomer and having carboxylic, sulfonic acid or hydroxyl functionality or combinations thereof (monomer B); and a water soluble or water-dispersible macromolecular monomer of the formula X-Y-Z which is copolymerizable with A and B wherein X is a copolymerizable moiety containing a double bond, Y is a divalent linking group and Z is a water-dispersible polymeric moiety (monomer C). The combined acid groups employed in the B monomer are neutralized from 5 to 100% based on the total amount of acid groups in B. The composition further comprises tackifier and/or plasticizers at a level such that the ratio of terpolymer to additives falls within a range of from 0.2:1 to 5:1. The pressure sensitive adhesive composition is dispersible under a variety of pH conditions. Also described are tapes comprising the repulpable composition of the invention and their use in papermaking industry.

Inventors

  • 👤 Francois C. D'Haese

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 15:59
CPC Classifications
C; C09; C09J; C09J133/00; C09J133/04; C09J133/06; C09J133/08; C09J7/00; C09J7/10; C09J7/30; C09J7/38; C09J7/381; C09J7/385; C08; C08L; C08L2666/00; C08L2666/02; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10T; Y10T428/00; Y10T428/28; Y10T428/2852

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 265 words
A pressure sensitive adhesive composition comprising (a) a terpolymer formed from A, B and C monomers wherein, A is a hydrophobic monomer selected from the group consisting of acrylic or a methacrylic ester of a non-tertiary alcohol, the alcohol having 2 to 14 carbon atoms, wherein A comprises from 30 to 85% by total weight of the A plus B plus C; B is a polar monomer copolymerizable with said A monomer and having hydroxyl, carboxyl, sulfonic acid functionality or combinations thereof, with the proviso that if B contains the hydroxyl functionality it is combined with a monomer having an acid group, wherein B comprises from 2 to 50% by total weight of A plus B plus C, and wherein from 5 to 100% of any said acidic group has been neutralized; and C is a water-dispersible macromolecular monomer which is copolymerizable with A and B and has the formula X--Y--Z wherein X is a structural element comprising a moiety which is copolymerizable with A and B, Y is a divalent linking group joining X to Z, and Z is a water-dispersible moiety containing at least two units which are essentially unreactive under free radical initiated copolymerization conditions used to form the terpolymer, wherein C comprises from 10 to 50% by total weight of A plus B plus C; and (b) an additive selected from the group consisting of tackifiers, plasticizers, and combinations thereof wherein the ratio of said additive to said terpolymer is in the range of from 0.2:1 to 5:1 wherein said composition is repulpable at a pH of from 2 to 11.
Claim 2
Dependent Claim 265 words
A pressure sensitive adhesive composition comprising (a) a terpolymer formed from A, B and C monomers wherein, A is a hydrophobic monomer selected from the group consisting of acrylic or a methacrylic ester of a non-tertiary alcohol, the alcohol having 2 to 14 carbon atoms, wherein A comprises from 30 to 85% by total weight of the A plus B plus C; B is a polar monomer copolymerizable with said A monomer and having hydroxyl, carboxyl, sulfonic acid functionality or combinations thereof, with the proviso that if B contains the hydroxyl functionality it is combined with a monomer having an acid group, wherein B comprises from 2 to 50% by total weight of A plus B plus C, and wherein from 5 to 100% of any said acidic group has been neutralized; and C is a water-dispersible macromolecular monomer which is copolymerizable with A and B and has the formula X--Y--Z wherein X is a structural element comprising a moiety which is copolymerizable with A and B, Y is a divalent linking group joining X to Z, and Z is a water-dispersible moiety containing at least two units which are essentially unreactive under free radical initiated copolymerization conditions used to form the terpolymer, wherein C comprises from 10 to 50% by total weight of A plus B plus C; and (b) an additive selected from the group consisting of tackifiers, plasticizers, and combinations thereof wherein the ratio of said additive to said terpolymer is in the range of from 0.2:1 to 5:1 wherein said composition is repulpable at a pH of from 2 to 11.
Claim 3
Dependent Claim 22 words
The adhesive according to claim 1 where the A monomer is selected from said acrylic or methacrylic ester of said non-tertiary alcohol.
Claim 4
Dependent Claim 17 words
The adhesive according to claim 1 wherein the non-tertiary alcohol is selected from butyl and isooctyl alcohol.
Claim 5
Dependent Claim 40 words
The adhesive according to claim 1 wherein the B monomer is a vinyl carboxylic acid selected from the group consisting of acrylic acid, methacrylic acid, itaconic acid, maleic acid, fumaric acid, β-carboxyethylacrylate, salts of these monomeric acids and combinations thereof.
Claim 6
Dependent Claim 48 words
The adhesive according to claim 1 where the polar B monomer contains at least one vinyl sulfonic acid functionality selected from the group consisting of 2-acrylamido-2-methylpropane sulfonic acid, sulfoethyl methacrylate, sulfopropyl methacrylate, sodium styrene sulfonate, N-(3-sulfopropyl)-N-methacroyloxyethyl-N,N-dimethyl-ammonium betaine, 1-(3-sulfopropyl)-2-vinylpyridinium-betaine, bis-(3-sulfo-propyl)-itaconic acid ester, salts of these monomers, and combinations thereof.
Claim 7
Dependent Claim 56 words
The adhesive according to claim 1 wherein the B monomer is a combination of (i) one or more hydroxy functional materials selected from the group consisting of hydroxyethylacrylate, hydroxypropyl-acrylate, hydroxyethylmethacrylate and hydroxypropyl-methacrylate and (ii) and acidic group containing material selected from the group consisting of acrylic acid, methacrylic acid and an acid with vinyl sulfonic functionality.
Claim 8
Dependent Claim 18 words
The adhesive according to claim 1 where the C monomer has a molecular weight of 300 to 30,000.
Claim 9
Dependent Claim 31 words
The adhesive according to claim 1 wherein the Z portion of the C monomer is selected from the group consisting of polyethyloxazoline, N-vinylpyrrolidone-acrylamide copolymer, and a polyalkyleneoxide copolymer, and combinations thereof.
Claim 10
Dependent Claim 29 words
The adhesive of claim 1 wherein said tackifier has a glass transition temperature higher than said terpolymer and said plasticizer has a glass transition temperature lower than said terpolymer.
Claim 11
Dependent Claim 30 words
The adhesive of claim 9 where the tackifier is selected from the group consisting of rosin and rosin derivatives, acidic rosin and rosin derivatives, acidic terpenephenolic resins, and combinations thereof.
Claim 12
Dependent Claim 23 words
The adhesive of claim 9 where the plasticizer is selected from the group consisting of polyoxyethylenealkyl-phenyletherphosphate, polyoxyethylenealkylether-phosphate, polyethyleneglycolmonophenylether, octylphenoxypoly(ethyleneoxy)ethanol, nonylphenoxypoly(ethyleneoxy)ethanol, and combinations thereof.
Claim 13
Dependent Claim 7 words
A crosslinked adhesive according to claim 1.
Claim 14
Dependent Claim 25 words
The adhesive of claim 1 further comprising a neutralizing agent selected from the group consisting of alkanol amines, water-soluble/dispersible alkali metal hydroxides and combinations thereof.
Claim 15
Dependent Claim 17 words
The adhesive of claim 1 wherein said terpolymer has an inherent viscosity of from 0.4 to 3.0.
Claim 16
Dependent Claim 59 words
Process for the preparation of a pressure sensitive adhesive of claim 1, comprising the steps of: copolymerizing the monomers A, B and C in presence of a radical chain initiator, adding to the formed copolymer, a plasticizer, tackifier, a neutralizing agent and optionally, a cross-linking agent, in an organic solvent system comprising ethyl acetate, methanol, isopropanol and optionally water.
Claim 17
Dependent Claim 10 words
Pressure sensitive adhesive tape comprising the composition of claim 1.
Claim 18
Dependent Claim 22 words
Pressure sensitive adhesive tape of claim 16 having at least one pressure sensitive adhesive composition of claim 1 on a backing layer.
Claim 19
Dependent Claim 16 words
Pressure sensitive adhesive tape of claim 16 being a transfer or splicing tape for paper industries.
Claim 20
Dependent Claim 15 words
A substrate bearing a layer of a pressure sensitive adhesive tape according to claim 1.
Claim 21
Dependent Claim 21 words
A repulpable splice comprising at least two sections of paper joined together by a pressure sensitive adhesive according to claim 1.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1998-01-09 1998-07-11 1999-01-10 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2002-01-09 2002-07-11 2003-01-10 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2006-01-09 2006-07-11 2007-01-10 $7700.00 Window Closed / Lapsed

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