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Method of improving or producing oxide superconductor

Assignee: Canon Anelva Corp
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Filing: 1992-03-09
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Granted: 1994-12-27
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Expires: 2012-03-09
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Abstract

Abstract Herein is disclosed a method of improving or producing an oxide superconductor. An oxide superconductor or starting material of oxide superconductor as an object material is irradiated with active oxygen species. The irradiation process is carried out while keeping the object material at a temperature at which the object material is effectively oxidized with the active oxygen species. The active oxygen species are formed on the inside or in the peripheral portion of a nonequilibrium or equilibrium, high-temperature plasma.

Inventors

  • 👤 Atsushi Sekiguchi
  • 👤 Hideo Mito

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 18:29
CPC Classifications
C; C23; C23C; C23C16/00; C23C16/56; C23C16/22; C23C16/30; C23C16/40; C23C16/408; C23C16/44; C23C16/448; C23C16/452; H; H10; H10N; H10N60/00; H10N60/01; H10N60/0268; H10N60/0661; Y; Y10; Y10S; Y10S505/00; Y10S505/725; Y10S505/73; Y10S505/742

Claims Analysis

Total Claims: 18
Claim 1
Independent Claim 119 words
A method of producing a final oxide superconductor, comprising the steps of: mounting an object material of an initial oxide superconductor or a starting material of the initial oxide superconductor to an object holder; maintaining said object material separate from a locally pinched plasma in a space surrounded by an electrode; irradiating said object material with active oxygen species formed from said pinched plasma to change the structure of said object material to orthorhombic; wherein said pinched plasma is defined by an emission spectrum for at least one oxygen (O) atom, which has an emission intensity substantially greater than the largest emission intensity in the visible spectra for oxygen (O 2 + ) molecules observed for said pinched plasma.
Claim 2
Independent Claim 119 words
A method of producing a final oxide superconductor, comprising the steps of: mounting an object material of an initial oxide superconductor or a starting material of the initial oxide superconductor to an object holder; maintaining said object material separate from a locally pinched plasma in a space surrounded by an electrode; irradiating said object material with active oxygen species formed from said pinched plasma to change the structure of said object material to orthorhombic; wherein said pinched plasma is defined by an emission spectrum for at least one oxygen (O) atom, which has an emission intensity substantially greater than the largest emission intensity in the visible spectra for oxygen (O 2 + ) molecules observed for said pinched plasma.
Claim 3
Dependent Claim 55 words
A method as claimed in claim 1, wherein while said object material is being irradiated, said method further comprising the step of: controlling the temperature of said object holder between approximately 300° C. to 450° C. to maintain said object material at a temperature at which it is effectively oxidized with said active oxygen species.
Claim 4
Dependent Claim 28 words
A method as claimed in claim 1, wherein said irradiating step comprises the step of: irradiating said object material with said pinched plasma not more than five minutes.
Claim 5
Dependent Claim 38 words
A method as claimed in claim 1, further comprising the step of: selecting said object material to have a composition Ba 2 YCu 3 O x , where x is the quantitative proportion of oxygen in said composition.
Claim 6
Dependent Claim 26 words
A method as claimed in claim 1, further comprising the step of: providing a power to an rf coil electrode to generate said locally pinched plasma.
Claim 7
Dependent Claim 27 words
A method as claimed in claim 1, wherein said pinched plasma is generated with an rf input power of 3 kW under a pressure of 0.7 Torr.
Claim 8
Dependent Claim 36 words
A method as claimed in claim 1, further comprising the step of: causing said O atoms to undergo an energy level transition from 3p 5 P to 3s 5 S 0 to effect said emission spectrum.
Claim 9
Dependent Claim 49 words
A method as claimed in claim 1, wherein the plasma emission of the oxygen (O) atoms has an intensity, at 777 nm-wavelength, of approximately 100 times stronger than the strongest emission intensity observed for said pinched plasma in the visible spectra of said oxygen (O 2 + ) molecules.
Claim 10
Independent Claim 113 words
A method of producing a final oxide superconductor, comprising the steps of: mounting an object material of an initial oxide superconductor or starting material of the initial superconductor to an object holder; maintaining said object material separate from a plasma whose emission is substantially confined in a space surrounded by an electrode; irradiating said object material with active oxygen species formed from said plasma to change the structure of said object material to orthorhombic, said plasma being defined by an emission spectrum for oxygen (O) atoms which has an emission intensity substantially greater than the largest emission intensity in the visible spectra for oxygen (O 2 + ) molecules observed for said plasma.
Claim 11
Independent Claim 113 words
A method of producing a final oxide superconductor, comprising the steps of: mounting an object material of an initial oxide superconductor or starting material of the initial superconductor to an object holder; maintaining said object material separate from a plasma whose emission is substantially confined in a space surrounded by an electrode; irradiating said object material with active oxygen species formed from said plasma to change the structure of said object material to orthorhombic, said plasma being defined by an emission spectrum for oxygen (O) atoms which has an emission intensity substantially greater than the largest emission intensity in the visible spectra for oxygen (O 2 + ) molecules observed for said plasma.
Claim 12
Dependent Claim 55 words
The method as claimed in claim 9, wherein while said object material is being irradiated, said method further comprising the step of: controlling the temperature of said object holder between approximately 300° C. to 450° C. to maintain said object material at a temperature at which it is effectively oxidized with said active oxygen species.
Claim 13
Dependent Claim 29 words
The method as claimed in claim 9, wherein said irradiating step comprises the step of: irradiating said object material with said substantially confined plasma not more than five minutes.
Claim 14
Dependent Claim 38 words
The method as claimed in claim 9, further comprising the step of: selecting said object material to have a composition Ba 2 YCu 3 O x , where x is the quantitative proportion of oxygen in said composition.
Claim 15
Dependent Claim 31 words
The method as claimed in claim 9, further comprising the step of: providing a power to said electrode to generate said substantially confined plasma, said electrode being an rf coil electrode.
Claim 16
Dependent Claim 28 words
The method as claimed in claim 13, wherein said substantially confined plasma is generated with an rf input power of 3 kW under a pressure of 0.7 Torr.
Claim 17
Dependent Claim 37 words
The method of as claimed in claim 9, further comprising the step of: causing said O atom to undergo an energy level transition from 3p 5 P to 3s 5 S 0 to effect said emission spectrum.
Claim 18
Dependent Claim 57 words
The method as claimed in claim 9, wherein said emission intensity of said O atoms are further defined to be, at the emission of said O atoms at 777 nm-wavelength, approximately, at least, 100 times greater than the largest emission intensity observed for said substantially confined plasma in the visible spectra for said O 2 + molecules.

References Cited (Backward Citations)

US4664747A Cited
US4900716A Cited
US4929598A Cited
JPS6460808A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-12-26 1998-06-27 1998-12-27 $2000.00 Window Closed / Lapsed
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