Patent US5368994A successfully refreshed from Google Patents.
US5368994A
Expired / Lapsed
US
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Silver halide photographic material
Assignee: Fujifilm Holdings Corp
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Filing: 1993-05-04
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Granted: 1994-11-29
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Expires: 2013-05-04
Abstract
Abstract A silver halide photographic material comprising a hydrophilic colloidal layer structure including at least two silver halide emulsion layers provided on at least one common side of a transparent support, wherein the average content of iridium compound per unit mol of silver in the silver halide emulsion layer on the side nearer to the support is greater than that of the silver halide emulsion layer located further from the support, and, characterized by at least one of (1) when exposed to laser light having a wavelength of 600 to 850 nm, the maximum value of γ on the characteristic curve of optical density versus exposure (logarithm) is not more than 3.2; or (2) the average grain size of the grains in the silver halide emulsion layer located further from the support is greater than that of the grains in the silver halide emulsion layer located nearer to the support. Further, a process for the processing of a silver halide photographic material is provided, characterized in that the silver halide photographic material as defined above is used wherein the total coated amount of gelatin and silver on the side of the support having the silver halide layers are 3.5 g/m 2 or less and 2.7 g/m 2 or less, respectively, is conveyed at a line speed of 1,500 mm/min and all steps of development, fixing, rinse and drying are completed within 60 seconds in a roller type automatic processor.
Inventors
- 👤 Itsuo Fujiwara
- 👤 Tadashi Ito
- 👤 Naoki Arai
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 14:46
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/005; G03C1/46; G03C5/00; G03C5/16; G03C5/164; G03C5/26; G03C1/035; G03C1/06; G03C1/07; G03C1/08; G03C1/10; G03C1/12; G03C1/14; G03C1/18; G03C1/20; G03C1/22; G03C1/26; G03C1/28; G03C2001/03594; G03C1/09; G03C2001/093; G03C7/00; G03C7/30; G03C7/3022; G03C2007/3025; G03C2200/00; G03C2200/27; G03C2200/39; G03C5/02; Y; Y10; Y10S; Y10S430/00; Y10S430/145; Y10S430/146
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
164 words
A silver halide photographic material comprising a hydrophilic colloidal layer structure including at least two silver halide emulsion layers including a lower silver halide emulsion layer comprising silver halide grains and an upper silver halide emulsion layer comprising silver halide grains, both of said emulsion layers being provided on at least one side of a transparent support, and at least said lower silver halide emulsion layer contains an iridium compound, wherein the average amount of iridium compound per unit mol of silver in said lower silver halide emulsion layer located nearer to said support is greater than the iridium content of said upper silver halide emulsion layer located further from said support, and the maximum value of γ on the characteristic curve of optical density versus exposure (logarithm) of said photographic material is not more than 3.2 when said silver halide photographic material is exposed to laser light having a wavelength falling within the range of 600 to 850 nm for forming an image.
Claim 2
Dependent Claim
164 words
A silver halide photographic material comprising a hydrophilic colloidal layer structure including at least two silver halide emulsion layers including a lower silver halide emulsion layer comprising silver halide grains and an upper silver halide emulsion layer comprising silver halide grains, both of said emulsion layers being provided on at least one side of a transparent support, and at least said lower silver halide emulsion layer contains an iridium compound, wherein the average amount of iridium compound per unit mol of silver in said lower silver halide emulsion layer located nearer to said support is greater than the iridium content of said upper silver halide emulsion layer located further from said support, and the maximum value of γ on the characteristic curve of optical density versus exposure (logarithm) of said photographic material is not more than 3.2 when said silver halide photographic material is exposed to laser light having a wavelength falling within the range of 600 to 850 nm for forming an image.
Claim 3
Dependent Claim
97 words
The silver halide photographic material according to claim 1, wherein said lower silver halide emulsion layer and said upper silver halide emulsion layer have different photographic sensitivities, and the ratio of photographic sensitivity of the silver halide emulsion layer having the highest sensitivity to that of the silver halide emulsion layer having the lowest sensitivity is 1.5 or more as calculated in terms of the reciprocal of the exposure at an optical density of fog +1.0 when exposed to laser light having a wavelength falling within the range of 600 to 850 nm for forming an image.
Claim 4
Dependent Claim
41 words
The silver halide photographic material according to claim 2, wherein the ratio of photographic sensitivity of the silver halide emulsion layer having the highest sensitivity to that of the silver halide emulsion layer having the lowest sensitivity is 2 or more.
Claim 5
Dependent Claim
38 words
The silver halide photographic material according to claim 1, wherein said lower silver halide emulsion layer and said upper silver halide emulsion layer each comprises silver bromochloride having a silver chloride content of 5 to 50 mol %.
Claim 6
Dependent Claim
40 words
The silver halide photographic material according to claim 1, wherein the amount of iridium compound in said upper silver halide emulsion layer is up to 90% of the amount of said iridium compound in said lower silver halide emulsion layer.
Claim 7
Dependent Claim
40 words
The silver halide photographic material according to claim 5, wherein the amount of iridium compound in said upper silver halide emulsion layer is 5 to 80% of the amount of said iridium compound in said lower silver halide emulsion layer.
Claim 8
Dependent Claim
47 words
The silver halide photographic material according to claim 1, wherein the iridium compound is selected from a hexachloroiridium (III) complex salt, a hexachloroiridium (IV) complex salt, a hexamineiridium (III) complex salt, a hexamineiridium (IV) complex salt, a trioxalateiridium (III) complex salt and a trioxalateiridium (IV) complex salt.
Claim 9
Dependent Claim
31 words
The silver halide photographic material according to claim 1, wherein the iridium compound is added during formation of at least the silver halide grains of the lower silver halide emulsion layer.
Claim 10
Dependent Claim
31 words
The silver halide photographic material according to claim 1, wherein said lower silver halide emulsion layer contains at least 1×10 -8 mol of said iridium compound per mol of silver halide.
Claim 11
Dependent Claim
32 words
The silver halide photographic material according to claim 9, wherein said lower silver halide emulsion layer contains 1×10 -8 to 1×10 -5 mol of said iridium compound per mol of silver halide.
Claim 12
Dependent Claim
32 words
The silver halide photographic material according to claim 10, wherein said lower silver halide emulsion layer contains 5×10 -8 to 5×10 -6 mol of said iridium compound per mol of silver halide.
References Cited (Backward Citations)
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-11-28 | 1998-05-30 | 1998-11-29 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-11-28 | 2002-05-30 | 2002-11-29 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-11-28 | 2006-05-30 | 2006-11-29 | $7700.00 | Window Closed / Lapsed |