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US5362816A Expired / Lapsed US ⏱️ 0.0 years remaining

High cohesive strength pressure-sensitive adhesives incorporating acetoacetate

Assignee: Rohm and Haas Co
•
Filing: 1992-06-04
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Granted: 1994-11-08
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Expires: 2012-06-04
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Abstract

Abstract A pressure-sensitive adhesive having improved shear strength obtained by virtue of the formation of the enamine of a pendent acetoacetate is described. These materials contain acetoacetate functional monomer in a low Tg emulsion polymer. Shear strength is improved without compromise of either peel strength or tack.

Inventors

  • 👤 Barry S. Snyder
  • 👤 Daniel A. Bors

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 05:12
CPC Classifications
C; C09; C09J; C09J157/00; C09J157/06; C09J157/12; C08; C08F; C08F8/00; C08F8/30; C08F8/32; C09J133/00; C09J133/04; C09J133/06; C09J133/062; C09J2301/00; C09J2301/30; C09J2301/302; Y; Y10; Y10S; Y10S526/00; Y10S526/931; Y10T; Y10T428/00; Y10T428/28; Y10T428/2852; Y10T428/31504; Y10T428/31942

Claims Analysis

Total Claims: 5
Claim 1
Independent Claim 50 words
A pressure-sensitive adhesive comprising a polymer prepared by free radical emulsion polymerization having a Tg below about 0° C. and having pendent acetoacetate functional groups wherein the pendent acetoacetate groups have been reacted with ammonia or a primary amine to form an enamine-containing composition at a pH greater than 9.
Claim 2
Dependent Claim 50 words
A pressure-sensitive adhesive comprising a polymer prepared by free radical emulsion polymerization having a Tg below about 0° C. and having pendent acetoacetate functional groups wherein the pendent acetoacetate groups have been reacted with ammonia or a primary amine to form an enamine-containing composition at a pH greater than 9.
Claim 3
Dependent Claim 25 words
The pressure-sensitive adhesive of claim 1, wherein the amount of acetoacetate functional monomer in the polymer is from about 0.05 to about 10 weight percent.
Claim 4
Dependent Claim 25 words
The pressure-sensitive adhesive of claim 1, wherein the amount of acetoacetate functional monomer in the polymer is from about 0.5 to about 5 weight percent.
Claim 5
Dependent Claim 25 words
The pressure-sensitive adhesive of claim 1, wherein the amount of acetoacetate functional monomer in the polymer is from about 1 to about 5 weight percent.

References Cited (Backward Citations)

US4048214A Cited
GB1185216A Cited
US4540739A Cited
US4677167A Cited
US5071914A Cited
US4908403A Cited
US5053452A Cited
US4759983A Cited
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EP0492847A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-11-07 1998-05-09 1998-11-08 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-11-07 2002-05-09 2002-11-08 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-11-07 2006-05-09 2006-11-08 $7700.00 Window Closed / Lapsed

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