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US4677167A Expired / Lapsed US ⏱️ 0.0 years remaining

Pressure sensitive adhesive reaction product of bicyclic amide acetal and acrylate interpolymer

Assignee: Ashland LLC
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Filing: 1985-07-26
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Granted: 1987-06-30
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Expires: 2005-07-26
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Abstract

Abstract Curing of a pressure-sensitive adhesive resin based on an acrylic interpolymer containing pendent carboxylic acid or anhydride groups is effected through reaction with a bicyclic amide acetal cross-linking agent. The cross-linked resins exhibit a high degree of relatively permanent cohesive strength.

Inventors

  • 👤 Anil B. Goel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 09:53
CPC Classifications
C; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/30; C08G18/38; C08G18/3819; C08G18/3823; C08G18/3825; C08G18/3827; C08K; C08K5/00; C08K5/0008; C08K5/0016; C08L; C08L75/00; C08L75/04

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 186 words
A pressure-sensitive adhesive composition comprising the reaction product of: (1) a normally tacky interpolymer derived by the addition polymerization of 100 parts by wegiht of a monomer mixture consisting essentially of (a) at least 40 parts of a C 4 -C 18 alkyl acrylate or methacrylate; (b) from 0.5-10 parts of an ethylenically unsaturated monomer having at least one carboxylic acid or anhydride group (c) any balance selected from the group consisting of (i) a C 3 -C 10 vinyl ester of an alkanoic acid, and (ii) a methyl or ethyl ester or acrylic acid or methacrylic acid; (2) from 0.1-10% by weight based on said interpolymer (1) of a bicyclic amide acetal corresponding to the formula: ##STR2## where R represents a substituent selected from the group consisting of H, alkyl and aryl; R 1 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, and either alkylene or arylene attached to another bicyclic amide acetal radical; and R 2 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, alkoxy, and alkylene attached to another bicyclic amide acetal radical.
Claim 2
Dependent Claim 186 words
A pressure-sensitive adhesive composition comprising the reaction product of: (1) a normally tacky interpolymer derived by the addition polymerization of 100 parts by wegiht of a monomer mixture consisting essentially of (a) at least 40 parts of a C 4 -C 18 alkyl acrylate or methacrylate; (b) from 0.5-10 parts of an ethylenically unsaturated monomer having at least one carboxylic acid or anhydride group (c) any balance selected from the group consisting of (i) a C 3 -C 10 vinyl ester of an alkanoic acid, and (ii) a methyl or ethyl ester or acrylic acid or methacrylic acid; (2) from 0.1-10% by weight based on said interpolymer (1) of a bicyclic amide acetal corresponding to the formula: ##STR2## where R represents a substituent selected from the group consisting of H, alkyl and aryl; R 1 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, and either alkylene or arylene attached to another bicyclic amide acetal radical; and R 2 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, alkoxy, and alkylene attached to another bicyclic amide acetal radical.
Claim 3
Dependent Claim 183 words
A pressure sensitive adhesive composition comprising the reaction product of: (1) a normally tacky interpolymer derived by the addition polymerization of 100 parts by weight of a monomer mixture consisting essentially of (1) at least 60 parts of a C 4 -C 18 alkyl acrylate or methacrylate; (b) from 0.5-10 parts of an ethylenically unsaturated monomer having at least one carboxyl group; (c) any balance selected from the group consisting of a C 3 -C 10 vinyl ester of an alkanoic acid, and (ii) a methly or ethyl ester of acrylic acid or methacrylic acid; (2) from 0.1-10% by weight based on said interpolymer (1) of a bicyclic amide acetal corresponding to the formula: ##STR3## where R represents a substituent selected from the group consisting of H, alkyl and aryl; R 1 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, and either alkylene or arylene attached to another bicyclic amide acetal radical; and R 2 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, alkoxy, and alkylene attached to another bicyclic amide acetal radical.
Claim 4
Dependent Claim 183 words
A pressure sensitive adhesive composition comprising the reaction product of: (1) a normally tacky interpolymer derived by the addition polymerization of 100 parts by weight of a monomer mixture consisting essentially of (1) at least 60 parts of a C 4 -C 18 alkyl acrylate or methacrylate; (b) from 0.5-10 parts of an ethylenically unsaturated monomer having at least one carboxyl group; (c) any balance selected from the group consisting of a C 3 -C 10 vinyl ester of an alkanoic acid, and (ii) a methly or ethyl ester of acrylic acid or methacrylic acid; (2) from 0.1-10% by weight based on said interpolymer (1) of a bicyclic amide acetal corresponding to the formula: ##STR3## where R represents a substituent selected from the group consisting of H, alkyl and aryl; R 1 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, and either alkylene or arylene attached to another bicyclic amide acetal radical; and R 2 represents a substituent selected from the group consisting of H, alkyl, aryl, alkaryl, alkoxy, and alkylene attached to another bicyclic amide acetal radical.
Claim 5
Dependent Claim 17 words
The pressure sensitive adhesive composition according to claim 1 wherein said bicyclic amide acetal is tetrahydro-(7a-methyl-oxazolo-(2,3-b) oxazolo.
Claim 6
Dependent Claim 21 words
The pressure sensitive adhesive composition according to claim 1 wherein said bicyclic amide acetal is 1,4( bis [tetrahydro (7a-methyl)-oxazolo-(2,3-b) oxazole] butane.
Claim 7
Dependent Claim 17 words
The pressure sensitive adhesive composition according to claim 2 wherein said bicyclic amide acetal is tetrahydro-(7a-methyl)-oxazolo-(2,3-b) oxazole.
Claim 8
Dependent Claim 21 words
The pressure sensitive adhesive composition according to claim 2 wherein said bicyclic amide acetal is 1,4( 2',2")bis [tetrahydro (7a-methyl)-oxazolo-(2,3-b) oxazolo] butane.

References Cited (Backward Citations)

US4539376A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1990-06-29 1990-12-29 1991-06-30 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1994-06-29 1994-12-29 1995-06-30 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1998-06-29 1998-12-29 1999-06-30 $7700.00 Window Closed / Lapsed

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