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US5360833A Expired / Lapsed US ⏱️ 0.0 years remaining

Controlled release compositions for UV curable epoxysilicone release agents

Assignee: General Electric Co
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Filing: 1992-11-25
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Granted: 1994-11-01
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Expires: 2012-11-25
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Abstract

Abstract A UV curable epoxysilicone blend of an epoxy functional silicone resin containing Q groups, epoxy functional M groups, and at least one member selected from D groups and T groups, at least 5 parts of the sum of M groups and epoxy functional M groups per 10 parts of the sum of Q groups, D groups and T groups; and an epoxy-stopped silicone fluid containing epoxy functional M groups.

Inventors

  • 👤 Richard P. Eckberg
  • 👤 Robert F. Agars

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 06:19
CPC Classifications
C; C08; C08L; C08L83/00; C08L83/04; C08L83/06; C08G; C08G59/00; C08G59/18; C08G59/20; C08G59/32; C08G59/3254; C09; C09D; C09D183/00; C09D183/04; C09D183/06

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 121 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids which in the presence of an efficacious amount of 'onium photocatalyst is curable when exposed to ultraviolet radiation, said blend comprising: (A) about 60% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 40% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 2
Dependent Claim 121 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids which in the presence of an efficacious amount of 'onium photocatalyst is curable when exposed to ultraviolet radiation, said blend comprising: (A) about 60% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 40% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 3
Dependent Claim 14 words
An epoxysilicone composition as in claim 1, wherein said epoxy-functional M group is ##STR5##
Claim 4
Dependent Claim 128 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids which in the presence of an efficacious amount of 'onium photocatalyst is curable when exposed to ultraviolet radiation, said blend comprising: (A) from about 80 to about 20% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 20 to about 80% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 5
Dependent Claim 128 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids which in the presence of an efficacious amount of 'onium photocatalyst is curable when exposed to ultraviolet radiation, said blend comprising: (A) from about 80 to about 20% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 20 to about 80% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 6
Dependent Claim 14 words
An epoxysilicone composition as in claim 1, wherein said epoxy-functional M group is ##STR6##
Claim 7
Dependent Claim 116 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids curable in the presence of an efficacious amount of photocatalyst and ultraviolet radiation, said blend comprising: (A) about 60% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 40% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 8
Dependent Claim 116 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids curable in the presence of an efficacious amount of photocatalyst and ultraviolet radiation, said blend comprising: (A) about 60% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 40% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 9
Dependent Claim 14 words
An epoxysilicone composition as in claim 5, wherein said epoxy-functional M group is ##STR7##
Claim 10
Dependent Claim 123 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids curable in the presence of an efficacious amount of photocatalyst and ultraviolet radiation, said blend comprising: (A) from about 80 to about 20% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 20 to about 80% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 11
Dependent Claim 123 words
An ultraviolet radiation-curable epoxysilicone composition comprising a blend of epoxy-functional silicone resins and epoxy-stopped silicone fluids curable in the presence of an efficacious amount of photocatalyst and ultraviolet radiation, said blend comprising: (A) from about 80 to about 20% by weight epoxy-functional silicone resin, said resin containing Q groups, epoxy-functional M groups and at least one member selected from D groups and T groups, wherein said resin comprises at least 5 parts of the sum of M groups and epoxy-functional M groups per 10 parts of the sum of Q groups, D groups and T groups; (B) about 20 to about 80% by weight epoxy-stopped silicone fluids containing epoxy-functional M groups; and said blend having an epoxy equivalent weight of greater than 1000.
Claim 12
Dependent Claim 14 words
An epoxysilicone composition as in claim 7, wherein said epoxy-functional M group is ##STR8##
Claim 13
Dependent Claim 16 words
An epoxysilicone as in claim 7, wherein the photocatalyst is selected from iodonium and sulfonium salts.
Claim 14
Dependent Claim 55 words
An epoxysilicone as in claim 9, wherein the epoxy functional silica resin has the formula M.sup.E M.sub.8 D.sub.3 T.sub.2 Q.sub.5 wherein M E comprises: ##STR9## M comprises: (CH 3 ) 3 SiO 178 -- D comprises: (CH 3 ) 2 SiO-- T comprises: (CH 3 ) SiO 3/2 -- and Q comprises: SiO 4/2 --.
Claim 15
Dependent Claim 12 words
An epoxysilicone composition as in claim 7, wherein (B) has an EEW<8000.
Claim 16
Dependent Claim 19 words
An epoxysilicone composition as in claim 7, wherein (B) has an EEW ranging from about 500 to about 2500.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-10-31 1998-05-02 1998-11-01 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-10-31 2002-05-02 2002-11-01 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-10-31 2006-05-02 2006-11-01 $7700.00 Window Closed / Lapsed

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