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US5328803A
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Photopolymerizable composition
Assignee: Fujifilm Holdings Corp
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Filing: 1991-09-11
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Granted: 1994-07-12
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Expires: 2011-09-11
Abstract
Abstract A photopolymerizable composition developable with an alkali aqueous solution which comprises a carboxyl group-containing high polymer binder, a photopolymerizable monomer, a photopolymerization initiator system and a compound of a specific structure is disclosed. The photopolymerizable composition shows a good keeping stability in a state of lamination on a metal board and thus is highly useful in the production of, for example, dry films for print basic boards, photoresists, photomasks, lithograph boards and resin relief boards.
Inventors
- 👤 Sadao Fujikura
- 👤 Masayuki Iwasaki
- 👤 Yuichi Wakata
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-05 20:13
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/111; Y10S430/114; Y10S430/12; Y10S430/121; Y10S430/127
Claims Analysis
Total Claims: 4
Claim 1
Independent Claim
341 words
A photopolymerizable composition developable with an alkali aqueous solution which comprises: (1) a carboxyl group-containing high polymer binder having the weight-average molecular weight of 5,000 to 2,000,000 in the amount of 40 to 90% by weight; (2) a photopolymerizable monomer in the amount of 10 to 60% by weight; (3) a photopolymerization initiator system comprising a lophine dimer in the amount of 0.1 to 20% by weight; and (4) at least one compound selected from the group consisting of compound represented by the general formulae (I), (II) and (III) in the amount of 0.1 to 10% by weight: wherein R 1 to R 10 may be either the same or different and each represents H, NR 11 2 , OR 11 , SR 11 , COOR 11 , CN a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, an aryl group having 6 to 10 carbon atoms, an alkyl group having 1 to 10 carbon atoms, an aminoalkyl group having 1 to 10 carbon atoms, a hydroxyalkyl group having 1 to 10 carbon atoms, a carboxyalkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or a monophorino group; Y represents an alkylene group having 1 to 10 carbon atoms, an arylene group having 6 to 12 carbon atoms or an aralkylene group having 7 to 25 carbon atoms which may be substituted by NR 11 2 , OR 11 , SR 11 , COOR 11 , CN, a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, or a monophorino group, and which may contain between two carbon atoms a bivalent intervenient group of pyperadine residue, COO, NR 11 , SO 2 , SO 2 NR 11 , O, S, CONR 11 , CONHCO or COONR 11 ; wherein R 11 represents H, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms.
Claim 2
Dependent Claim
341 words
A photopolymerizable composition developable with an alkali aqueous solution which comprises: (1) a carboxyl group-containing high polymer binder having the weight-average molecular weight of 5,000 to 2,000,000 in the amount of 40 to 90% by weight; (2) a photopolymerizable monomer in the amount of 10 to 60% by weight; (3) a photopolymerization initiator system comprising a lophine dimer in the amount of 0.1 to 20% by weight; and (4) at least one compound selected from the group consisting of compound represented by the general formulae (I), (II) and (III) in the amount of 0.1 to 10% by weight: wherein R 1 to R 10 may be either the same or different and each represents H, NR 11 2 , OR 11 , SR 11 , COOR 11 , CN a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, an aryl group having 6 to 10 carbon atoms, an alkyl group having 1 to 10 carbon atoms, an aminoalkyl group having 1 to 10 carbon atoms, a hydroxyalkyl group having 1 to 10 carbon atoms, a carboxyalkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or a monophorino group; Y represents an alkylene group having 1 to 10 carbon atoms, an arylene group having 6 to 12 carbon atoms or an aralkylene group having 7 to 25 carbon atoms which may be substituted by NR 11 2 , OR 11 , SR 11 , COOR 11 , CN, a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, or a monophorino group, and which may contain between two carbon atoms a bivalent intervenient group of pyperadine residue, COO, NR 11 , SO 2 , SO 2 NR 11 , O, S, CONR 11 , CONHCO or COONR 11 ; wherein R 11 represents H, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms.
Claim 3
Dependent Claim
25 words
A photopolymerizable composition as claimed in claim 1, wherein the weight-average molecular weight of said carboxyl group-containing high polymer binder is from 40,000 to 85,000.
Claim 4
Dependent Claim
28 words
A photopolymerizable composition as claimed in claim 2, wherein said carboxyl group-containing high polymer binder is a tetrapolymer of methacrylic acid, methyl methacrylate, benzyl methacrylate and 2-ethylhexyl acrylate.
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