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US5328803A Expired / Lapsed US ⏱️ 0.0 years remaining

Photopolymerizable composition

Assignee: Fujifilm Holdings Corp
•
Filing: 1991-09-11
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Granted: 1994-07-12
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Expires: 2011-09-11
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Abstract

Abstract A photopolymerizable composition developable with an alkali aqueous solution which comprises a carboxyl group-containing high polymer binder, a photopolymerizable monomer, a photopolymerization initiator system and a compound of a specific structure is disclosed. The photopolymerizable composition shows a good keeping stability in a state of lamination on a metal board and thus is highly useful in the production of, for example, dry films for print basic boards, photoresists, photomasks, lithograph boards and resin relief boards.

Inventors

  • 👤 Sadao Fujikura
  • 👤 Masayuki Iwasaki
  • 👤 Yuichi Wakata

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-05 04:49
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; Y; Y10; Y10S; Y10S430/00; Y10S430/1053; Y10S430/1055; Y10S430/106; Y10S430/111; Y10S430/114; Y10S430/12; Y10S430/121; Y10S430/127

Claims Analysis

Total Claims: 4
Claim 1
Independent Claim 341 words
A photopolymerizable composition developable with an alkali aqueous solution which comprises: (1) a carboxyl group-containing high polymer binder having the weight-average molecular weight of 5,000 to 2,000,000 in the amount of 40 to 90% by weight; (2) a photopolymerizable monomer in the amount of 10 to 60% by weight; (3) a photopolymerization initiator system comprising a lophine dimer in the amount of 0.1 to 20% by weight; and (4) at least one compound selected from the group consisting of compound represented by the general formulae (I), (II) and (III) in the amount of 0.1 to 10% by weight: wherein R 1 to R 10 may be either the same or different and each represents H, NR 11 2 , OR 11 , SR 11 , COOR 11 , CN a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, an aryl group having 6 to 10 carbon atoms, an alkyl group having 1 to 10 carbon atoms, an aminoalkyl group having 1 to 10 carbon atoms, a hydroxyalkyl group having 1 to 10 carbon atoms, a carboxyalkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or a monophorino group; Y represents an alkylene group having 1 to 10 carbon atoms, an arylene group having 6 to 12 carbon atoms or an aralkylene group having 7 to 25 carbon atoms which may be substituted by NR 11 2 , OR 11 , SR 11 , COOR 11 , CN, a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, or a monophorino group, and which may contain between two carbon atoms a bivalent intervenient group of pyperadine residue, COO, NR 11 , SO 2 , SO 2 NR 11 , O, S, CONR 11 , CONHCO or COONR 11 ; wherein R 11 represents H, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms.
Claim 2
Dependent Claim 341 words
A photopolymerizable composition developable with an alkali aqueous solution which comprises: (1) a carboxyl group-containing high polymer binder having the weight-average molecular weight of 5,000 to 2,000,000 in the amount of 40 to 90% by weight; (2) a photopolymerizable monomer in the amount of 10 to 60% by weight; (3) a photopolymerization initiator system comprising a lophine dimer in the amount of 0.1 to 20% by weight; and (4) at least one compound selected from the group consisting of compound represented by the general formulae (I), (II) and (III) in the amount of 0.1 to 10% by weight: wherein R 1 to R 10 may be either the same or different and each represents H, NR 11 2 , OR 11 , SR 11 , COOR 11 , CN a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, an aryl group having 6 to 10 carbon atoms, an alkyl group having 1 to 10 carbon atoms, an aminoalkyl group having 1 to 10 carbon atoms, a hydroxyalkyl group having 1 to 10 carbon atoms, a carboxyalkyl group having 1 to 10 carbon atoms, an aralkyl group having 7 to 20 carbon atoms or a monophorino group; Y represents an alkylene group having 1 to 10 carbon atoms, an arylene group having 6 to 12 carbon atoms or an aralkylene group having 7 to 25 carbon atoms which may be substituted by NR 11 2 , OR 11 , SR 11 , COOR 11 , CN, a halogen atom, NO 2 , CHO, SO 3 R 11 , R 11 CONHNH, R 11 SO 2 NH, or a monophorino group, and which may contain between two carbon atoms a bivalent intervenient group of pyperadine residue, COO, NR 11 , SO 2 , SO 2 NR 11 , O, S, CONR 11 , CONHCO or COONR 11 ; wherein R 11 represents H, an alkyl group having 1 to 10 carbon atoms or an aryl group having 6 to 10 carbon atoms.
Claim 3
Dependent Claim 25 words
A photopolymerizable composition as claimed in claim 1, wherein the weight-average molecular weight of said carboxyl group-containing high polymer binder is from 40,000 to 85,000.
Claim 4
Dependent Claim 28 words
A photopolymerizable composition as claimed in claim 2, wherein said carboxyl group-containing high polymer binder is a tetrapolymer of methacrylic acid, methyl methacrylate, benzyl methacrylate and 2-ethylhexyl acrylate.

References Cited (Backward Citations)

US4282309A Cited
US4543318A Cited
US4987054A Cited
US4904564A Cited
US5030548A Cited
US5096799A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-07-11 1998-01-10 1998-07-12 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-07-11 2002-01-10 2002-07-12 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-07-11 2006-01-10 2006-07-12 $7700.00 Window Closed / Lapsed

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