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US5321082A Expired / Lapsed US ⏱️ 0.0 years remaining

Curable resin composition

Assignee: Nippon Paint Co Ltd
•
Filing: 1993-04-14
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Granted: 1994-06-14
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Expires: 2013-04-14
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Abstract

Abstract A curable resin composition containing (a) a polymer having a plurality of alkenyl groups, (b) an organohydrogenpolysiloxane having a plurality of hydrosilyl groups, (c) a polymer having a plurality of alkynyl groups, and (d) a hydrosilylation catalyst is disclosed. The composition is stable at room temperature but curable at an elevated temperature.

Inventors

  • 👤 Hiroharu Ohsugi
  • 👤 Yoshio Eguchi

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 10:00
CPC Classifications
C; C08; C08L; C08L101/00; C08L101/02; C08L33/00; C08L33/04; C08L33/06; C08L33/10; C08L83/00; C08L83/04

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 79 words
A curable resin composition comprising: (a) an acrylic, epoxy, polyester or polyether polymer having a plurality of alkenyl groups in the molecule and a number average molecular weight of from 400 to 100,000; (b) an organohydrogenpolysiloxane having a plurality of silicone-hydrogen bonds in the molecule; (c) an acrylic polymer having a plurality of alkynyl groups in the molecule and a number average molecular weight of from 400 to 100,000; and (c) a catalytically effective amount of a hydrosilylation catalyst.
Claim 2
Dependent Claim 79 words
A curable resin composition comprising: (a) an acrylic, epoxy, polyester or polyether polymer having a plurality of alkenyl groups in the molecule and a number average molecular weight of from 400 to 100,000; (b) an organohydrogenpolysiloxane having a plurality of silicone-hydrogen bonds in the molecule; (c) an acrylic polymer having a plurality of alkynyl groups in the molecule and a number average molecular weight of from 400 to 100,000; and (c) a catalytically effective amount of a hydrosilylation catalyst.
Claim 3
Dependent Claim 36 words
The curable resin composition according to claim 1, wherein said alkenyl group-containing acrylic polymer is a homopolymer of an alkenyl group-containing acrylic monomer or a copolymer of an alkenyl group-containing monomer with another monomer copolymerizable therewith.
Claim 4
Dependent Claim 30 words
The curable resin composition according to claim 1, wherein said alkenyl group-containing polyester polymer is a reaction product of a carboxyl group-terminated polyester resin with an alkenyl group-containing epoxy compound.
Claim 5
Dependent Claim 26 words
The curable resin composition according to claim 1, wherein said alkenyl group-containing epoxy polymer is a reaction product of an epoxy resin with an alkenoic acid.
Claim 6
Dependent Claim 32 words
The curable resin composition according to claim 1, wherein said alkenyl group-containing polyether polymer is a polymer produced by addition polymerizing an alkenyl group-containing epoxy compound initiated by an active hydrogen compound.
Claim 7
Dependent Claim 35 words
The curable resin composition according to claim 1, wherein said alkynyl group-containing polymer is a homopolymer of an alkynyl group-containing acrylic monomer or a copolymer of said alkynyl group-containing monomer with another monomer copolymerizable therewith.
Claim 8
Dependent Claim 31 words
The curable resin composition according to claim 6, wherein said alkynyl group-containing acrylic monomer is the acrylic or methacrylic ester of an α, α-dialkylpropargyl alcohol or an alkylene oxide adduct thereof.
Claim 9
Dependent Claim 17 words
The curable resin composition according to claim 7, wherein said ester is 2-methyl-3-butyn-2-yl methacrylate or 3-methyl-1-pentyn-3-yl methacrylate.
Claim 10
Dependent Claim 49 words
The curable resin composition according to claim 1, wherein said organohydrogenpolysiloxane has the formula: ##STR6## wherein R 1 and R 2 are each a C 1 -C 6 alkyl or phenyl, a is zero or an integer up to 100, and b is an integer from 2 to 100.
Claim 11
Dependent Claim 61 words
The curable resin composition according to claim 1, wherein said organohydrogenpolysiloxane has the formula: ##STR7## wherein R 2 is C 1 -C 6 alkyl or phenyl, R 3 is the same as R 2 , c is zero or an integer up to 8, d is an integer from 2 to 10, and the sum of c+d equals 3 to 10.
Claim 12
Dependent Claim 49 words
The curable resin composition according to claim 1, wherein said organohydrogenpolysiloxane has the formula: ##STR8## wherein R 1 and R 2 are C 1 -C 6 alkyl or phenyl, e is an integer from 2 to 100 , and f is zero or an integer up to 100 .
Claim 13
Dependent Claim 15 words
The curable resin composition according to claim 1, wherein said organohydrogenpolysiloxane has the formula: ##STR9##
Claim 14
Dependent Claim 15 words
The curable resin composition according to claim 1, wherein said hydrosilylation catalyst is chloroplatinic acid.
Claim 15
Dependent Claim 49 words
The curable resin composition according to claim 1, wherein the proportions of said component (a), component (b) and component (c) in said composition is such that 0.5 to 4 atoms of the hydrogen atom attached to the silicon atom are present for each of the alkenyl and alkynyl groups.
Claim 16
Dependent Claim 43 words
The curable resin composition according to claim 1, wherein said component (d) is present in said composition an amount between 5 to 1,000 ppm relative to 100 parts by weight of the sum of solids of component (a), component (b) and component (c).

References Cited (Backward Citations)

US3445420A Cited
US4472562A Cited
US5010137A Cited
US5017654A Cited
US5208289A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-13 1997-12-13 1998-06-14 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-13 2001-12-13 2002-06-14 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-13 2005-12-13 2006-06-14 $7700.00 Window Closed / Lapsed

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