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US5319226A Expired / Lapsed US ⏱️ 0.0 years remaining

Method of fabricating an ion sensitive field effect transistor with a Ta2 O5 hydrogen ion sensing membrane

Assignee: Individual
•
Filing: 1992-03-05
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Granted: 1994-06-07
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Expires: 2012-03-05
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Abstract

Abstract A fabricating method of an ion sensitive field effect transistor (ISFET) with a Ta2O5 hydrogen ion sensing membrane, which comprises the steps of forming Ta2O5 film with a thickness of about 400 to 500 A by RF reactive sputtering on a Si3N4/SiO2 gate dielectric layer of the pH-ISFET, and annealing the resultant film at about 375 DEG to 450 DEG C. in oxygen gas ambience for about one hour. In forming the Ta2O5 film on the pH-ISFET, the Ta2O5 film formed in the area except the gate region of the pH-ISFET is removed by a lift-off process utilizing a positive PR film. The Ta2O5 gate pH-ISFET according to the present invention has higher sensitivity and more stable operation characteristics than those of the conventional pH-ISFET, while the productivity and stability thereof are greatly improved by effecting a whole wafer process.

Inventors

  • 👤 Byung K. Sohn
  • 👤 Dae H. Kwon

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 11:46
CPC Classifications
G; G01; G01N; G01N27/00; G01N27/26; G01N27/403; G01N27/414

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 97 words
A method of fabricating an ion sensitive field effect transistor with a Ta 2 O 5 hydrogen ion sensing membrane, comprising the steps of: forming a Si 3 N 4 /SiO 2 dielectric layer over a gate region of said ion sensitive field effect transistor; depositing a film of Ta 2 O 5 having a thickness of about 400 to 500 Å on said Si 3 N 4 /SiO 2 dielectric layer on said ion sensitive field effect transistor; and annealing the resultant film at a temperature of about 375° to 450° C. in oxygen gas ambience.
Claim 2
Independent Claim 97 words
A method of fabricating an ion sensitive field effect transistor with a Ta 2 O 5 hydrogen ion sensing membrane, comprising the steps of: forming a Si 3 N 4 /SiO 2 dielectric layer over a gate region of said ion sensitive field effect transistor; depositing a film of Ta 2 O 5 having a thickness of about 400 to 500 Å on said Si 3 N 4 /SiO 2 dielectric layer on said ion sensitive field effect transistor; and annealing the resultant film at a temperature of about 375° to 450° C. in oxygen gas ambience.
Claim 3
Dependent Claim 20 words
The method according to claim 1, wherein said film of Ta 2 O 5 is deposited by RF reactive sputtering.
Claim 4
Dependent Claim 69 words
The method according to claim 1, wherein said film of Ta 2 O 5 formed in the areas surrounding said gate region of said ion sensitive field effect transistor are removed by a lift-off process utilizing a positive photosensitive film during a formation of said film of Ta 2 O 5 on said ion sensitive field effect transistor with said Si 3 N 4 /SiO 2 gate dielectric layer.
Claim 5
Dependent Claim 147 words
An ion sensitive field-effect transistor, comprising: a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, said first and second diffusion regions respectively defining a source region and a drain region; a dielectric layer positioned upon the surface of said semiconductor substrate covering said source region, said gate region and said drain region; an ion sensitive membrane formed on the dielectric layer over said gate region, said ion sensitive membrane being a Ta 2 O 5 compound having a thickness of approximately 400-500 Å; and first and second metal layers formed in V-shape and positioned upon the dielectric layer over said source region and said drain region, each of said first and second metal layers having a base at a center of one of said source region and said drain region.
Claim 6
Dependent Claim 147 words
An ion sensitive field-effect transistor, comprising: a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, said first and second diffusion regions respectively defining a source region and a drain region; a dielectric layer positioned upon the surface of said semiconductor substrate covering said source region, said gate region and said drain region; an ion sensitive membrane formed on the dielectric layer over said gate region, said ion sensitive membrane being a Ta 2 O 5 compound having a thickness of approximately 400-500 Å; and first and second metal layers formed in V-shape and positioned upon the dielectric layer over said source region and said drain region, each of said first and second metal layers having a base at a center of one of said source region and said drain region.
Claim 7
Dependent Claim 48 words
The ion sensitive field-effect transistors as claimed in claim 4, wherein said ion sensitive membrane is formed on the dielectric layer by RF reactive sputtering and annealing at a temperature in the range of 300° to 900° C. in a reactive oxygen gas ambience for approximately one hour.
Claim 8
Dependent Claim 37 words
The ion sensitive field-effect transistor as claimed in claim 5, wherein the range of temperature of the annealing is prefer to be of 375° to 425° C. in a reactive oxygen gas ambience for approximately one hour.
Claim 9
Dependent Claim 48 words
The ion sensitive field-effect transistor as claimed in claim 4, wherein said ion sensitive membrane is formed on the dielectric layer by RF reactive sputtering and annealing at a temperature in the range of 375° to 400° C. in a reactive oxygen gas ambience for approximately one hour.
Claim 10
Dependent Claim 25 words
The method according to claim 1, wherein the temperature of the annealing of approximately 400° in a reactive oxygen gas ambience for approximately one hour.
Claim 11
Dependent Claim 34 words
The ion sensitive field-effect transistor as claimed in claim 4, wherein the temperature of the annealing is preferred to be of approximately 400° C. in a reactive oxygen gas ambience for approximately one hour.
Claim 12
Independent Claim 177 words
A method of fabricating an ion sensitive field effect transistor on a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, said first and second diffusion regions respectively defining a source region and a drain region, comprising the steps of: forming a dielectric layer over the surface of said semiconductor substrate covering said source region, said gate region and said drain region; forming first and second metal layers in V-shape positioned upon the dielectric layer over said source region and said drain region, each of said first and second metal layers having a base at a center of one of said source region and said drain region; depositing an ion sensitive layer of Ta 2 O 5 compound having a thickness of approximately 400-500 Å on the dielectric layer over said gate region; and annealing said ion sensitive layer of Ta 2 O 5 compound at a temperature in the range of 375° to 425° C. in a reactive gas ambience.
Claim 13
Independent Claim 177 words
A method of fabricating an ion sensitive field effect transistor on a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, said first and second diffusion regions respectively defining a source region and a drain region, comprising the steps of: forming a dielectric layer over the surface of said semiconductor substrate covering said source region, said gate region and said drain region; forming first and second metal layers in V-shape positioned upon the dielectric layer over said source region and said drain region, each of said first and second metal layers having a base at a center of one of said source region and said drain region; depositing an ion sensitive layer of Ta 2 O 5 compound having a thickness of approximately 400-500 Å on the dielectric layer over said gate region; and annealing said ion sensitive layer of Ta 2 O 5 compound at a temperature in the range of 375° to 425° C. in a reactive gas ambience.
Claim 14
Dependent Claim 22 words
The method of fabricating an ion sensitive field effect transistor as claimed in claim 10, wherein said reactive gas ambience is oxygen.
Claim 15
Dependent Claim 26 words
The method of fabricating an ion sensitive field effect transistor as claimed in claim 10, wherein said ion sensitive layer is deposited by RF reactive sputtering.
Claim 16
Dependent Claim 31 words
The method of fabricating an ion sensitive field effect transistor as claimed in claim 10, wherein said ion sensitive layer is annealed in said reactive gas ambience for approximately one hour.
Claim 17
Dependent Claim 37 words
The method of fabricating an ion sensitive field effect transistor as claimed in claim 10, wherein the temperature of the annealing is approximately at 400° C. in said reactive gas ambience of oxygen for approximately one hour.
Claim 18
Independent Claim 243 words
A method of fabricating an ion sensitive field effect transistor on a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, each of said first and second diffusion regions respectively defining a source region and a drain region, comprising the steps of: forming an insulation layer over the surface of said semiconductor substrate covering said source region, said gate region and said drain region; forming first and second metal layers in a V-shape, positioned upon the insulation layer over said source region and said drain region, each of said first and second metal layers having a base at a center of each of said source and drain regions, and a channel having two ends extending in opposite directions away from the center of each of said source and drain regions; depositing a photoresist layer on the surface of said first and second metal layers, thereby exposing said gate region; sputtering a film of Ta 2 O 5 having a thickness of approximately 400-500 Å over the surface of said photoresist layer and said gate region in a first gas ambience; and removing said photoresist layer, thereby exposing the film of Ta 2 O 5 having a thickness of approximately 400-500 Å over said gate region; and annealing said semiconductor substrate having said film of Ta 2 O 5 over the gate region in a second gas ambience.
Claim 19
Independent Claim 243 words
A method of fabricating an ion sensitive field effect transistor on a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, each of said first and second diffusion regions respectively defining a source region and a drain region, comprising the steps of: forming an insulation layer over the surface of said semiconductor substrate covering said source region, said gate region and said drain region; forming first and second metal layers in a V-shape, positioned upon the insulation layer over said source region and said drain region, each of said first and second metal layers having a base at a center of each of said source and drain regions, and a channel having two ends extending in opposite directions away from the center of each of said source and drain regions; depositing a photoresist layer on the surface of said first and second metal layers, thereby exposing said gate region; sputtering a film of Ta 2 O 5 having a thickness of approximately 400-500 Å over the surface of said photoresist layer and said gate region in a first gas ambience; and removing said photoresist layer, thereby exposing the film of Ta 2 O 5 having a thickness of approximately 400-500 Å over said gate region; and annealing said semiconductor substrate having said film of Ta 2 O 5 over the gate region in a second gas ambience.
Claim 20
Dependent Claim 51 words
The method of fabricating an ion sensitive field effect transistor as claimed in claim 15, wherein said first gas ambience comprises argon and oxygen and said second gas ambience comprises oxygen, and said film of Ta 2 O 5 is being annealed in said second gas ambience for approximately one hour.
Claim 21
Dependent Claim 36 words
The method of fabricating an ion sensitive field effect transistor as claimed in claim 15, wherein said film of Ta 2 O 5 is being annealed at a temperature range of approximately 375° to 425° C.
Claim 22
Dependent Claim 45 words
The method of fabricating an ion sensitive field effect transistor as claimed in claim 16, wherein said film of Ta 2 O 5 is being annealed at a temperature range of approximately 400° C. in said second gas ambience of oxygen for approximately one hour.
Claim 23
Dependent Claim 288 words
An ion sensitive field effect transistor, comprising: a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, each of said first and second diffusion regions respectively defining a source region and a drain region; an insulation layer disposed over the surface of said semiconductor substrate covering said source region, said gate region and said drain region; first and second metal layers positioned upon the insulation layer over said source region and said drain region, each of said first and second metal layers having a base at a center of each of said source and drain regions, and a channel having two ends extending in opposite directions away from the center of each of said source and drain regions; and an ion sensitive layer of Ta 2 O 5 having a thickness of approximately 400-500 Å disposed on the insulation layer over the gate region, wherein said ion sensitive layer being disposed on said insulation layer over the gate region comprises the steps of: depositing a photoresist layer on the surface of said first and second metal layers, thereby exposing said gate region; sputtering said ion sensitive layer of Ta 2 O 5 having a thickness of approximately 400-500 Å over the surface of said photoresist layer and said gate region in a first gas ambience of argon and oxygen; and removing said photoresist layer, thereby exposing said ion sensitive layer of Ta 2 O 5 having a thickness of approximately 400-500 Å over said gate region; and annealing said semiconductor substrate having said ion sensitive layer of Ta 2 O 5 over the gate region in a second gas ambience of oxygen.
Claim 24
Dependent Claim 288 words
An ion sensitive field effect transistor, comprising: a semiconductor substrate of a first conductivity type having first and second diffusion regions of a second conductivity type separated and spaced-apart by a gate region, each of said first and second diffusion regions respectively defining a source region and a drain region; an insulation layer disposed over the surface of said semiconductor substrate covering said source region, said gate region and said drain region; first and second metal layers positioned upon the insulation layer over said source region and said drain region, each of said first and second metal layers having a base at a center of each of said source and drain regions, and a channel having two ends extending in opposite directions away from the center of each of said source and drain regions; and an ion sensitive layer of Ta 2 O 5 having a thickness of approximately 400-500 Å disposed on the insulation layer over the gate region, wherein said ion sensitive layer being disposed on said insulation layer over the gate region comprises the steps of: depositing a photoresist layer on the surface of said first and second metal layers, thereby exposing said gate region; sputtering said ion sensitive layer of Ta 2 O 5 having a thickness of approximately 400-500 Å over the surface of said photoresist layer and said gate region in a first gas ambience of argon and oxygen; and removing said photoresist layer, thereby exposing said ion sensitive layer of Ta 2 O 5 having a thickness of approximately 400-500 Å over said gate region; and annealing said semiconductor substrate having said ion sensitive layer of Ta 2 O 5 over the gate region in a second gas ambience of oxygen.
Claim 25
Dependent Claim 41 words
The ion sensitive field effect transistor as claimed in claim 19, wherein said ion sensitive layer of Ta 2 O 5 is annealed in said second gas ambience for approximately one hour at a temperature range of 375° to 425° C.

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Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-06 1997-12-06 1998-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-06 2001-12-06 2002-06-07 $3760.00 Window Closed / Lapsed
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