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US5318850A Expired / Lapsed US ⏱️ 0.0 years remaining

UV curable abrasion-resistant coatings with improved weatherability

Assignee: General Electric Co
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Filing: 1992-07-29
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Granted: 1994-06-07
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Expires: 2012-07-29
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Abstract

Abstract UV curable hardcoat compositions are provided which impart improved abrasion resistance to thermoplastic substrates when applied and cured thereon. Enhancement in abrasion and weathering properties have been achieved by the use of certain UV curable branched or carbocyclic monoacrylates, such as isobornyl acrylate.

Inventors

  • 👤 James E. Pickett
  • 👤 Gautam A. Patel

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 06:59
CPC Classifications
C; C09; C09D; C09D4/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31652; Y10T428/31663

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 163 words
A UV curable hardcoat composition comprising by weight, (A) 1% to 60% of colloidal silica, (B) 1% to 50% of the hydrolysis product of an alkoxysilyl acrylate of the formula, ##STR2## (C) 25% to 90% of acrylate monomer consisting essentially of a mixture of 20 wt. % to 90 wt. % of hexanediol diacrylate and 10 wt. % to 80 wt. % of a monofunctional acrylate selected from the group consisting of isobornyl acrylate, cyclohexyl acrylate, and 1-adamantyl acrylate, and (D) an effective amount of a photoinitiator, where R is a C.sub.(1-13) monovalent hydrocarbon radical, R 1 is a C.sub.(1-8) alkyl radical, R 2 is a divalent C.sub.(2-8) alkylene radical, R 3 is a monovalent radical selected from hydrogen and a C.sub.(1-8) alkyl radical, a is a whole number equal to 0 or 1, b is an integer equal to 1 to 3 inclusive, c is an integer equal to 1 to 3 inclusive, and the sum of a+b+c is equal to 4.
Claim 2
Dependent Claim 163 words
A UV curable hardcoat composition comprising by weight, (A) 1% to 60% of colloidal silica, (B) 1% to 50% of the hydrolysis product of an alkoxysilyl acrylate of the formula, ##STR2## (C) 25% to 90% of acrylate monomer consisting essentially of a mixture of 20 wt. % to 90 wt. % of hexanediol diacrylate and 10 wt. % to 80 wt. % of a monofunctional acrylate selected from the group consisting of isobornyl acrylate, cyclohexyl acrylate, and 1-adamantyl acrylate, and (D) an effective amount of a photoinitiator, where R is a C.sub.(1-13) monovalent hydrocarbon radical, R 1 is a C.sub.(1-8) alkyl radical, R 2 is a divalent C.sub.(2-8) alkylene radical, R 3 is a monovalent radical selected from hydrogen and a C.sub.(1-8) alkyl radical, a is a whole number equal to 0 or 1, b is an integer equal to 1 to 3 inclusive, c is an integer equal to 1 to 3 inclusive, and the sum of a+b+c is equal to 4.
Claim 3
Dependent Claim 17 words
A UV curable hardcoat composition in accordance with claim 1, where the alkoxysilyl acrylate is 3-methacryloyloxypropyl trimethoxysilane.
Claim 4
Dependent Claim 19 words
A UV curable hardcoat composition in accordance with claim 1, where the UV photoinitiator is 2,4,6-trimethylbenzoyl diphenyl phosphine oxide.
Claim 5
Dependent Claim 16 words
A thermoplastic substrate coated with a UV cured hardcoat of the hardcoat composition of claim 1.
Claim 6
Dependent Claim 13 words
A thermoplastic substrate in accordance with claim 4, which is a polycarbonate substrate.

References Cited (Backward Citations)

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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1997-06-06 1997-12-06 1998-06-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2001-06-06 2001-12-06 2002-06-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2005-06-06 2005-12-06 2006-06-07 $7700.00 Window Closed / Lapsed

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