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US4298738A Expired / Lapsed US ⏱️ 0.0 years remaining

Acylphosphine oxide compounds their preparation and use

Assignee: BASF SE
•
Filing: 1980-05-12
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Granted: 1981-11-03
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Expires: 2000-05-12
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Abstract

Abstract Acylphosphine oxide compounds of the general formula ##STR1## where R 1 is alkyl, cyclohexyl, cyclopentyl, aryl which is unsubstituted or substituted by halogen, alkyl or alkoxy, or an S-containing or N-containing five-membered or six-membered heterocyclic radical, R 2 has one of the meanings of R 1 (but R 1 and R 2 may be identical or different) or is alkoxy, aryloxy or aralkoxy, or R 1 and R 2 together form a ring and R 3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkythio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R 3 is α-naphthyl substituted by A and B at least in the 2- and 8-positions or is β-naphthyl substituted by A and B at least in the 1- and 3-positions, a process for the preparation of these acylphosphine oxide compounds from acid halides of the general formula ##STR2## where X is chlorine or bromine, and a phosphine of the general formula ##STR3## and the use of these acylphosphine oxide compounds as photoinitiators in photopolymerizable surface coatings, finishes and printing inks.

Inventors

  • 👤 Peter Lechtken
  • 👤 Ingolf Buethe
  • 👤 Manfred Jacobi
  • 👤 Werner Trimborn

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 18:52
CPC Classifications
C; C07; C07F; C07F9/00; C07F9/02; C07F9/28; C07F9/38; C07F9/40; C07F9/4003; C07F9/4062; C07F9/4065; C07F9/30; C07F9/32; C07F9/3205; C07F9/3247; C07F9/3252; C07F9/46; C07F9/48; C07F9/4808; C07F9/4841; C07F9/50; C07F9/53; C07F9/5337; G; G03; G03F; G03F7/00; G03F7/004; G03F7/027; G03F7/028; G03F7/029

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 291 words
An acylphosphine oxide compound of the formula ##STR9## where R 1 is straight-chain or branched alkyl of 1 to 6 carbon atoms cyclohexyl, cyclopentyl, phenyl or naphthyl which is unsubstituted or substituted by halogen, alkyl of 1 to 6 carbon atoms or alkoxy of 1 to 6 carbon atoms, or a fully aromatic S-containing or N-containing five-membered or six-membered heterocyclic radical having one hetero atom, selected from pyridyl or thienyl, R 3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkylthio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R 3 is α-naphthyl substituted by A and B at least in the 2- and 8-positions or is β-naphthyl substituted by A and B at least in the 1- and 3-positions and R 2 has one of the meanings of R 1 (but R 1 and R 2 may be identical or different with the proviso that R 1 and R 2 do not stand simultaneously for alkyl of 1 to 5 carbon atoms or alkoxy of 1 to 5 carbon atoms if R 3 is phenyl which carries the substituents A and B, in the same positions as defined above, but in which the meanings of A and B are restricted to alkoxy of 1 to 5 carbon atoms or halogen) or is alkoxy of 1 to 6 carbon atoms, phenoxy, methylphenoxy or benzyloxy, or R 1 and R 2 may be joined together to form a five- or six-membered P-containing ring.
Claim 2
Dependent Claim 291 words
An acylphosphine oxide compound of the formula ##STR9## where R 1 is straight-chain or branched alkyl of 1 to 6 carbon atoms cyclohexyl, cyclopentyl, phenyl or naphthyl which is unsubstituted or substituted by halogen, alkyl of 1 to 6 carbon atoms or alkoxy of 1 to 6 carbon atoms, or a fully aromatic S-containing or N-containing five-membered or six-membered heterocyclic radical having one hetero atom, selected from pyridyl or thienyl, R 3 is an at least disubstituted phenyl, pyridyl, furyl or thienyl radical which carries, at least at the two carbon atoms adjacent to the linkage point of the carbonyl group, the substituents A and B, which may be identical or different, and each of which is alkyl, alkoxy or alkylthio of 1 to 6 carbon atoms, cycloalkyl of 5 to 7 carbon atoms, phenyl or halogen, or R 3 is α-naphthyl substituted by A and B at least in the 2- and 8-positions or is β-naphthyl substituted by A and B at least in the 1- and 3-positions and R 2 has one of the meanings of R 1 (but R 1 and R 2 may be identical or different with the proviso that R 1 and R 2 do not stand simultaneously for alkyl of 1 to 5 carbon atoms or alkoxy of 1 to 5 carbon atoms if R 3 is phenyl which carries the substituents A and B, in the same positions as defined above, but in which the meanings of A and B are restricted to alkoxy of 1 to 5 carbon atoms or halogen) or is alkoxy of 1 to 6 carbon atoms, phenoxy, methylphenoxy or benzyloxy, or R 1 and R 2 may be joined together to form a five- or six-membered P-containing ring.
Claim 3
Dependent Claim 20 words
An acylphosphine compound as set forth in claim 1, wherein R 3 is 2,4,6-trimethylphenyl, 2,3,6-trimethylphenyl, 2,6-dimethoxyphenyl, 2,6-dichlorophenyl, 2,6-di-(methylthio)phenyl or 2,3,5,6-tetramethylphenyl.
Claim 4
Dependent Claim 17 words
An acylphosphine oxide compound as set forth in claim 1, wherein R 3 is 2,4,6-trimethylpyrid-3-yl or 2,4-dimethylthien-3-yl.
Claim 5
Dependent Claim 19 words
An acylphosphine oxide compound as set forth in claim 1, wherein R 3 is 1,3-dimethylnaphthalen-2-yl, 2,8-dimethylnaphthalen-1-yl, 1,3-dimethoxynaphthalen-2-yl or 2,8-dimethoxynaphthalen-1-yl.
Claim 6
Dependent Claim 25 words
An acylphosphine oxide compound as set forth in claim 1, wherein R 1 and R 2 are phenyl or C 1 -C 6 -alkyl-substituted phenyl.

References Cited (Backward Citations)

US3826640A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1984-11-02 1985-05-04 1985-11-03 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1988-11-02 1989-05-04 1989-11-03 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1992-11-02 1993-05-04 1993-11-03 $7700.00 Window Closed / Lapsed

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