US5318850A
Expired / Lapsed
US
⏱️ 0.0 years remaining
UV curable abrasion-resistant coatings with improved weatherability
Assignee: General Electric Co
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Filing: 1992-07-29
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Granted: 1994-06-07
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Expires: 2012-07-29
Abstract
Abstract UV curable hardcoat compositions are provided which impart improved abrasion resistance to thermoplastic substrates when applied and cured thereon. Enhancement in abrasion and weathering properties have been achieved by the use of certain UV curable branched or carbocyclic monoacrylates, such as isobornyl acrylate.
Inventors
- 👤 James E. Pickett
- 👤 Gautam A. Patel
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 06:43
CPC Classifications
C; C09; C09D; C09D4/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31507; Y10T428/31652; Y10T428/31663
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
163 words
A UV curable hardcoat composition comprising by weight, (A) 1% to 60% of colloidal silica, (B) 1% to 50% of the hydrolysis product of an alkoxysilyl acrylate of the formula, ##STR2## (C) 25% to 90% of acrylate monomer consisting essentially of a mixture of 20 wt. % to 90 wt. % of hexanediol diacrylate and 10 wt. % to 80 wt. % of a monofunctional acrylate selected from the group consisting of isobornyl acrylate, cyclohexyl acrylate, and 1-adamantyl acrylate, and (D) an effective amount of a photoinitiator, where R is a C.sub.(1-13) monovalent hydrocarbon radical, R 1 is a C.sub.(1-8) alkyl radical, R 2 is a divalent C.sub.(2-8) alkylene radical, R 3 is a monovalent radical selected from hydrogen and a C.sub.(1-8) alkyl radical, a is a whole number equal to 0 or 1, b is an integer equal to 1 to 3 inclusive, c is an integer equal to 1 to 3 inclusive, and the sum of a+b+c is equal to 4.
Claim 2
Dependent Claim
163 words
A UV curable hardcoat composition comprising by weight, (A) 1% to 60% of colloidal silica, (B) 1% to 50% of the hydrolysis product of an alkoxysilyl acrylate of the formula, ##STR2## (C) 25% to 90% of acrylate monomer consisting essentially of a mixture of 20 wt. % to 90 wt. % of hexanediol diacrylate and 10 wt. % to 80 wt. % of a monofunctional acrylate selected from the group consisting of isobornyl acrylate, cyclohexyl acrylate, and 1-adamantyl acrylate, and (D) an effective amount of a photoinitiator, where R is a C.sub.(1-13) monovalent hydrocarbon radical, R 1 is a C.sub.(1-8) alkyl radical, R 2 is a divalent C.sub.(2-8) alkylene radical, R 3 is a monovalent radical selected from hydrogen and a C.sub.(1-8) alkyl radical, a is a whole number equal to 0 or 1, b is an integer equal to 1 to 3 inclusive, c is an integer equal to 1 to 3 inclusive, and the sum of a+b+c is equal to 4.
Claim 3
Dependent Claim
17 words
A UV curable hardcoat composition in accordance with claim 1, where the alkoxysilyl acrylate is 3-methacryloyloxypropyl trimethoxysilane.
Claim 4
Dependent Claim
19 words
A UV curable hardcoat composition in accordance with claim 1, where the UV photoinitiator is 2,4,6-trimethylbenzoyl diphenyl phosphine oxide.
Claim 5
Dependent Claim
16 words
A thermoplastic substrate coated with a UV cured hardcoat of the hardcoat composition of claim 1.
Claim 6
Dependent Claim
13 words
A thermoplastic substrate in accordance with claim 4, which is a polycarbonate substrate.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-06-06 | 1997-12-06 | 1998-06-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-06-06 | 2001-12-06 | 2002-06-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-06-06 | 2005-12-06 | 2006-06-07 | $7700.00 | Window Closed / Lapsed |