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US5308596A
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US
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Process for the production of crystalline sodium disilicate in an externally heated rotary kiln having temperature zones
Assignee: Clariant Produkte Deutschland GmbH
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Filing: 1992-12-08
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Granted: 1994-05-03
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Expires: 2012-12-08
Abstract
Abstract To prepare crystalline sodium disilicates having a laminar structure, a molar ratio of SiO 2 to Na 2 O of (1.9 to 2.1) 1 and a water content of less than 0.3% by weight, a water glass solution is first obtained by reacting sand with sodium hydroxide solution in a molar ratio of SiO 2 to Na 2 O of (2.0 to 2.3) : 1 at temperatures of 180° to 240° C. and pressures of 10 to 30 bar. This water glass solution having at least 20% by weight of solids is treated in a spray drier with hot air at 200° to 300° C. with the formation of a pulverulent amorphous sodium disilicate having a water content (determined as loss on heating at 700° C.) of 15 to 23% by weight and a bulk density of at least 300 g/l. The spray-dried pulverulent, amorphous sodium disilicate is ground. The ground sodium disilicate is introduced into a rotary kiln equipped with devices for moving solids, externally heated via the wall and having in its interior a plurality of different temperature zones, and is treated therein at temperatures of 400° to 800° C. for 1 to 60 minutes with formation of crystalline sodium disilicate.
Inventors
- 👤 Michael Kotzian
- 👤 Gunther Schimmel
- 👤 Alexander Tapper
- 👤 Knut Bauer
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 19:23
CPC Classifications
C; C01; C01B; C01B33/00; C01B33/20; C01B33/36; C01B33/38; C01B33/32
Claims Analysis
Total Claims: 6
Claim 1
Independent Claim
258 words
A process for the preparation of crystalline sodium disilicates having a laminar structure, a molar ratio of SiO 2 to Na 2 O of (1.9 to 2.1) : 1 and a water content of less than 0.3% by weight, which comprises: reacting sand with sodium hydroxide solution in a molar ratio of SiO 2 to Na 2 O of (2.0 to 2.3): 1 at temperature of 180° to 240° C. and pressures of 10 to 30 bar with formation of a water glass solution having at least 20% by weight of solids; spray-drying the water glass solution with hot air at 200° to 300° C. with the formation of a pulverulent amorphous sodium disilicate having a water content (determined at loss on heating at 700° C.) of 15 to 23% by weight and a bulk density of more than 300 g/l; grinding the spray-dried pulverulent amorphous sodium disilicate; introducing the ground sodium disilicate into a rotary kiln equipped with devices for moving solids, externally heated via the wall and having at least four different temperature zones in its interior, wherein in the first temperature zone adjacent to the entry opening 200° to 500° C. is maintained, in the second temperature zone 400° to 600° C. is maintained, in the third temperature zone 550° to 700° C. is maintained and in the fourth temperature zone adjacent to the discharge opening 650° to 800° C. is maintained; and treating the ground sodium disilicate in said externally heated rotary kiln for 1 to 60 minutes with formation of crystalline sodium disilicate.
Claim 2
Dependent Claim
258 words
A process for the preparation of crystalline sodium disilicates having a laminar structure, a molar ratio of SiO 2 to Na 2 O of (1.9 to 2.1) : 1 and a water content of less than 0.3% by weight, which comprises: reacting sand with sodium hydroxide solution in a molar ratio of SiO 2 to Na 2 O of (2.0 to 2.3): 1 at temperature of 180° to 240° C. and pressures of 10 to 30 bar with formation of a water glass solution having at least 20% by weight of solids; spray-drying the water glass solution with hot air at 200° to 300° C. with the formation of a pulverulent amorphous sodium disilicate having a water content (determined at loss on heating at 700° C.) of 15 to 23% by weight and a bulk density of more than 300 g/l; grinding the spray-dried pulverulent amorphous sodium disilicate; introducing the ground sodium disilicate into a rotary kiln equipped with devices for moving solids, externally heated via the wall and having at least four different temperature zones in its interior, wherein in the first temperature zone adjacent to the entry opening 200° to 500° C. is maintained, in the second temperature zone 400° to 600° C. is maintained, in the third temperature zone 550° to 700° C. is maintained and in the fourth temperature zone adjacent to the discharge opening 650° to 800° C. is maintained; and treating the ground sodium disilicate in said externally heated rotary kiln for 1 to 60 minutes with formation of crystalline sodium disilicate.
Claim 3
Dependent Claim
24 words
The process as claimed in claim 1, wherein the spray-dried, pulverulent, amorphous sodium disilicate is ground to particle sizes of 1 to 50 μm.
Claim 4
Dependent Claim
38 words
The process as claimed in claim 1, wherein the pulverulent crystalline sodium disilicate having particle sizes from 0.1 to 12 mm exiting the rotary kiln is ground using a mill to particle sizes of 2 to 400 μm.
Claim 5
Dependent Claim
40 words
The process as claimed in claim 3, wherein the ground crystalline sodium disilicate is fed to a roller compactor, by means of which is compressed to compacted pieces at a roller pressure of 5 to 40 kN/cm of roller width.
Claim 6
Dependent Claim
28 words
The process as claimed in claim 4, wherein the compacted pieces are processed by mechanical comminution to give granules having a bulk density of 700 to 1000 g/l.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1997-05-02 | 1997-11-01 | 1998-05-03 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2001-05-02 | 2001-11-01 | 2002-05-03 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2005-05-02 | 2005-11-01 | 2006-05-03 | $7700.00 | Window Closed / Lapsed |