High temperature plastic light conduit and composition of matter therefor

Claim 2

A monofilament fiber optic pipe, wherein the improvement comprises: a substantially transparent, solid, flexible, essentially impurity free, thermoset polymer, said polymer being the polymerization reaction product of at least one monomer selected from the group consisting of esters, vinyl esters, styrenes and hydrocarbon derivatives of styrene and whereby said pipe has the property of being able to transmit substantially white light throughout its length.

Claim 3

The fiber optic pipe of claim 1 enclosed in a sheath.

Claim 4

The fiber optic pipe of claim 2 wherein the sheath is highly polished, clean and essentially free of scratches.

Claim 5

The fiber optic pipe of claim 3 wherein the sheath is a tube of fluorinated ethylene-propylene copolymer.

Claim 6

The fiber optic pipe of claim 4 wherein the monomer is an ester selected from the group consisting of acrylates, acetates, methacrylates and carbonates.

Claim 7

The fiber optic pipe of claim 1 wherein said polymerization reaction is carried out in a tube container inclined at an acute angle from horizontal sufficient to permit escape of substantially all bubbles formed during said polymerization reaction.

Claim 8

The fiber optic pipe of claim 6 wherein said acute angle is an angle of about 30-45 per cent from the horizontal.

Claim 9

The fiber optic pipe of claim 6 wherein said polymerization reaction is established and maintained at a desired temperature through use of a heat transfer medium circulated under pressure around said tube container and wherein said heat transfer medium comprises oil, air, nitrogen or an inert gas.

Claim 10

The fiber optic pipe of claim 6 wherein said tube container is doubled into a U-shaped configuration, placed into a tank such that the U-shaped end of said tube container is closer at the lower most end of the tank.

Claim 11

The fiber optic pipe of claim 6 wherein initiation of said polymerization reaction is prevented through use of a first heat transfer medium circulated under pressure around a first region of said tubular container and maintained at a predetermined relatively cold temperature, and further wherein said polymerization reaction is initiated and maintained at a desired, relatively higher temperature through use of a second heat transfer medium circulated under pressure around a second region of said tube container, said second heat transfer medium having a different specific gravity than said first heat transfer medium.

Claim 12

A monofilament fiber optic pipe having improved light transmission properties comprising: a substantially transparent, solid, flexible, essentially impurity free, essentially inhibitor free, essentially initiator free, essentially bubble free, essentially void free thermoset polymer, said polymer being the polymerization reaction product of at least one monomer selected from the group consisting of esters, vinyl ester, styrene and hydrocarbon derivatives of styrene and whereby said pipe has the property of being able to transmit substantially white light throughout its length.

Claim 13

A monofilament fiber optic pipe having improved light transmission properties comprising: a substantially transparent, solid, flexible, essentially impurity free, essentially inhibitor free, essentially initiator free, essentially bubble free, essentially void free thermoset polymer, said polymer being the polymerization reaction product of at least one monomer selected from the group consisting of esters, vinyl ester, styrene and hydrocarbon derivatives of styrene and whereby said pipe has the property of being able to transmit substantially white light throughout its length.

Claim 14

The fiber optic pipe of claim 11 enclosed in a sheath.

Claim 15

The fiber optic pipe of claim 12 wherein the sheath is highly polished, clean and substantially free of scratches.

Claim 16

The fiber optic pipe of claim 12 wherein the sheath is a tube of fluorinated ethylene-propylene copolymer.

Claim 17

The fiber optic pipe of claim 11 wherein the monomer is an ester selected from the group consisting of acetates, acrylates, methacrylates and carbonates.

Claim 18

A substantially transparent, tubular, flexible, monofilament fiber optic pipe having a length and a diameter and including a crosslinked polymer being the polymerization reaction product of at least one monomer selected from the group consisting of esters, vinyl esters, styrene and hydrocarbon derivatives of styrene, comprising: a uniform composition of polymer throughout the length and diameter of said pipe and whereby said pipe has the property of being able to transmit light color truly throughout its length.

Claim 19

A substantially transparent, tubular, flexible, monofilament fiber optic pipe having a length and a diameter and including a crosslinked polymer being the polymerization reaction product of at least one monomer selected from the group consisting of esters, vinyl esters, styrene and hydrocarbon derivatives of styrene, comprising: a uniform composition of polymer throughout the length and diameter of said pipe and whereby said pipe has the property of being able to transmit light color truly throughout its length.

Claim 20

A substantially tubular, flexible, monofilament fiber optic pipe having a length and a diameter and including a thermoset polymer being the polymerization reaction product of at least one monomer selected from the group consisting of esters, vinyl esters, styrene and hydrocarbon derivatives of styrene, comprising: a uniform index of refraction throughout the length and diameter of said pipe and whereby said pipe has the property of being able to transmit substantially white light throughout its length.

Claim 21

A substantially tubular, flexible, monofilament fiber optic pipe having a length and a diameter and including a thermoset polymer being the polymerization reaction product of at least one monomer selected from the group consisting of esters, vinyl esters, styrene and hydrocarbon derivatives of styrene, comprising: a uniform index of refraction throughout the length and diameter of said pipe and whereby said pipe has the property of being able to transmit substantially white light throughout its length.

Claim 22

The fiber optic pipe of claim 16 or claim 17 wherein the polymer is produced by a free radical polymerization reaction.

Claim 23

The fiber optic pipe of either claim 16 or claim 17 further including a fluorinated ethylene-propylene copolymer cladding surrounding the radial periphery of the pipe.

Claim 24

The fiber optic pipe of claim 16 or claim 17 wherein the monomer selected is methyl methacrylate.

Claim 25

The fiber optic pipe of claim 16 or claim 17 wherein said monomer selected is n-butyl methacrylate.

Claim 26

A substantially tubular, flexible, monofilament fiber optic pipe having a length and a diameter, comprising a thermoset polymer being the polymerization reaction product of a monomer mix including diethylene glycol bis(allyl carbonate), said fiber optic pipe having a substantially uniform index of refraction throughout the length and diameter of said pipe and whereby said pipe has the property of being able to transmit substantially white light throughout its length.

Claim 27

A substantially tubular, flexible, monofilament fiber optic pipe having a length and a diameter, comprising a thermoset polymer being the polymerization reaction product of a monomer mix including diethylene glycol bis(allyl carbonate), said fiber optic pipe having a substantially uniform index of refraction throughout the length and diameter of said pipe and whereby said pipe has the property of being able to transmit substantially white light throughout its length.

Claim 28

The fiber optic pipe of claim 22 further including a tubular fluorinated ethylene-propylene copolymer cladding surrounding said fiber optic pipe.

Claim 29

A solid, flexible, essentially impurity-free, bubble-free and void-free cross-linked organic polymer light conduit made from the free radical polymerization of reactants comprising: essentially inhibitor-free methyl methacrylate at about 50 to 80 parts by volume; n-butyl methacrylate at about 20 to 80 parts by volume; isopropyl percarbonate at about 0.10 to 0.50 parts by volume; diallyl phthalate at about 1 to 5 parts by volume; and n-butyl mercaptan at about 0.5 to 5.0 parts by volume.

Claim 30

A solid, flexible, essentially impurity-free, bubble-free and void-free cross-linked organic polymer light conduit made from the free radical polymerization of reactants comprising: essentially inhibitor-free methyl methacrylate at about 50 to 80 parts by volume; n-butyl methacrylate at about 20 to 80 parts by volume; isopropyl percarbonate at about 0.10 to 0.50 parts by volume; diallyl phthalate at about 1 to 5 parts by volume; and n-butyl mercaptan at about 0.5 to 5.0 parts by volume.

Claim 31

A composition of matter comprising: a substantially transparent, flexible, cross-linked, void-free organic polymeric solid having a length dimension and containing; methyl methacrylate monomeric units in about 20 to about 160 parts by volume; and cross-linking agent units in about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terephthalate, 1,4-butanediol diacrylate 1,4, butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4-dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate; and whereby said composition has the property of being able to transmit substantially white light throughout its length dimension.

Claim 32

A composition of matter comprising: a substantially transparent, flexible, cross-linked, void-free organic polymeric solid having a length dimension and containing; methyl methacrylate monomeric units in about 20 to about 160 parts by volume; and cross-linking agent units in about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terephthalate, 1,4-butanediol diacrylate 1,4, butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4-dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate; and whereby said composition has the property of being able to transmit substantially white light throughout its length dimension.

Claim 33

A composition of matter comprising: a transparent, flexible, cross-linked organic polymer formed in a generally uniformly cylindrical shape containing: essentially inhibitor-free methyl methacrylate monomeric units in about 20 to about 160 parts by volume; cross-linking agent units in about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terephthalate, 1,4-butanediol, diacrylate, 1,4-butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4-dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate, whereby said composition has the property of being able to transmit substantially white light throughout its length.

Claim 34

A composition of matter comprising: a transparent, flexible, cross-linked organic polymer formed in a generally uniformly cylindrical shape containing: essentially inhibitor-free methyl methacrylate monomeric units in about 20 to about 160 parts by volume; cross-linking agent units in about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terephthalate, 1,4-butanediol, diacrylate, 1,4-butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4-dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate, whereby said composition has the property of being able to transmit substantially white light throughout its length.

Claim 35

A composition of matter comprising: a transparent, flexible, essentially cross-linked, bubble-free and void-free organic polymer formed in a generally uniformly cylindrical shape and containing: methyl methacrylate monomeric units in about 20 to about 160 parts by volume; cross-linking agent units in about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terphthalate, 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4-dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate; and whereby said composition has the property of being able to transmit substantially white light throughout its length.

Claim 36

A composition of matter comprising: a transparent, flexible, essentially cross-linked, bubble-free and void-free organic polymer formed in a generally uniformly cylindrical shape and containing: methyl methacrylate monomeric units in about 20 to about 160 parts by volume; cross-linking agent units in about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terphthalate, 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4-dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate; and whereby said composition has the property of being able to transmit substantially white light throughout its length.

Claim 37

A composition of matter comprising; a transparent, flexible tubular-shaped, cross-linked, essentially bubble-free, essentially void-free polymer containing: essentially inhibitor-free methyl methacrylate monomeric units of about 20 to about 160 parts by volume; cross-linking agent units of about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terephthalate, 1,4-butanediol diacrylate, 1,4 -butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate; and a tubular-shaped clad surrounding the tubular-shaped polymer whereby said composition has the property of being able to transmit substantially white light throughout its length.

Claim 38

A composition of matter comprising; a transparent, flexible tubular-shaped, cross-linked, essentially bubble-free, essentially void-free polymer containing: essentially inhibitor-free methyl methacrylate monomeric units of about 20 to about 160 parts by volume; cross-linking agent units of about 1 to about 80 parts by volume selected from the group consisting of allyl diglycol carbonate, diallyl isocyanate, diallyl isophthalate, diallyl maleate, diallyl phthalate, diallyl terephthalate, ethylene dimethacrylate, methallyl methacrylate, triallyl cyanurate, 1,3-butylene dimethacrylate, trimethylpropane trimethacrylate, diethylene glycol bis (allyl carbonate), diallyl malonate, bis (2-methacryloxyethyl) isophthalate, bis (allylyl) carbonate, bis (2-methacryloxyethyl) phthalate, bis (2-methacryloxyethyl) phthlate, bis (2-methacryloxyethyl) terephthalate, 1,4-butanediol diacrylate, 1,4 -butanediol dimethacrylate, 2-butene 1,4-diacrylate, 2-butene, 1,4dimethacrylate, 1,3-butylene glycol diacrylate, 1,4-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,4-butylene glycol dimethacrylate, diallyl adipate, diallyl carbonate, diallyl fumarate, diallyl malonate, diethylene glycol diacrylate, dimethallyl maleate, divinylbenzene, ethylene diacrylate, 1,6-hexamethylene diacrylate, 1,6-hexamethylene dimethacrylate, methallyl acrylate, neopentyl glycol diacrylate, 1,9-nonanediol diacrylate, 1,9-nonanediol dimethacrylate, pentacrythediol tetracrylate, pentacrythediol tetramethacrylate, 1-phenylethylene-1,2-dimethacrylate, p-phenylene dimethacrylate, 2,3-propylene glycol dimethacrylate, styrene glycol dimethacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, tetramethylene diacrylate, tetramethylene dimethacrylate, triallyl trimesate, triethylene glycol diacrylate, triethylene glycol dimethacrylate and trimethylolethane trimethacrylate; and a tubular-shaped clad surrounding the tubular-shaped polymer whereby said composition has the property of being able to transmit substantially white light throughout its length.

Claim 39

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts methyl methacrylate, (ii) 25 parts n-butyl methacrylate, (iii) 10 parts 1,3 butylene dimethacrylate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts benzoyl peroxide, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 80 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 100 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 40

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts methyl methacrylate, (ii) 25 parts n-butyl methacrylate, (iii) 10 parts 1,3 butylene dimethacrylate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts benzoyl peroxide, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 80 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 100 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 41

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts Styrene, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts Diallyl Phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts benzoyl peroxide, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a col fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 80 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 100 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 42

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts Styrene, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts Diallyl Phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts benzoyl peroxide, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a col fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 80 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 100 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 43

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts methyl methacrylate, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts Triallyl cyanurate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts benzoyl peroxide, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 80 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 100 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 44

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts methyl methacrylate, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts Triallyl cyanurate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts benzoyl peroxide, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 80 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 100 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 45

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts methyl methacrylate, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts Diallyl Phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts diisopropyl peroxy-dicarbonate and 5 parts diethylene glycol bis, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 46

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 70 parts methyl methacrylate, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts Diallyl Phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 0.5 parts diisopropyl peroxy-dicarbonate and 5 parts diethylene glycol bis, to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 47

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 40 parts methyl methacrylate; (ii) 30 parts n-butyl methacrylate; (iii) 5 parts diallyl phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 30 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; `d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 48

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 40 parts methyl methacrylate; (ii) 30 parts n-butyl methacrylate; (iii) 5 parts diallyl phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 30 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; `d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 49

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 40 parts methyl methacrylate; (ii) 30 parts n-butyl methacrylate, (iii) 10 parts triallyl cyanurate, (iv) 0.5 parts n-butyl mercaptan, (v) 30 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight if isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 50

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 40 parts methyl methacrylate; (ii) 30 parts n-butyl methacrylate, (iii) 10 parts triallyl cyanurate, (iv) 0.5 parts n-butyl mercaptan, (v) 30 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight if isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 51

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 30 parts methyl methacrylate, (ii) 30 parts n-butyl methacrylate, (iii) 10 parts triallyl cyanurate, (iv) 0.5 parts n-butyl mercaptan, (b) 40 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; 3. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 52

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 30 parts methyl methacrylate, (ii) 30 parts n-butyl methacrylate, (iii) 10 parts triallyl cyanurate, (iv) 0.5 parts n-butyl mercaptan, (b) 40 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; 3. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per hour along the length of said tank, over a period of 20 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 53

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 40 parts styrene, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts diallyl phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 30 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per 75 minutes along the length of said tank, over a period of 25 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for additional two hours.

Claim 54

A composition of matter comprising the products of reaction resulting from: a. simultaneously mixing at room temperature: (i) 40 parts styrene, (ii) 30 parts n-butyl methacrylate, (iii) 5 parts diallyl phthalate, (iv) 0.5 parts n-butyl mercaptan, (v) 30 parts diethylene glycol bis (allyl carbonate), (vi) 5 parts 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 45 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at a rate of approximately 1 foot per 75 minutes along the length of said tank, over a period of 25 hours; g. raising the temperature of the hot fluid to approximately 50 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 60 degrees centigrade and maintaining this temperature for additional two hours.

Claim 55

A composition of matter comprising the products of reaction resulting from; a. simultaneously mixing at room temperature: (i) 10 parts vinyl acetate, (ii) 10 parts triallyl cyanurate, (iii) 80 parts diethylene glycol bis (allyl carbonate), (vi) 10 parts (of 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate)), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 55 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at rate of approximately 1 foot per 120 minutes along the length of said tank, over a period of 40 hours; g. raising the temperature of the hot fluid to approximately 70 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours.

Claim 56

A composition of matter comprising the products of reaction resulting from; a. simultaneously mixing at room temperature: (i) 10 parts vinyl acetate, (ii) 10 parts triallyl cyanurate, (iii) 80 parts diethylene glycol bis (allyl carbonate), (vi) 10 parts (of 10% by weight of isopropyl percarbonate in diethylene glycol bis (allyl carbonate)), to thereby create a reactive monomer mixture; b. placing said monomer mixture in a tube container; c. doubling said tube container containing said monomer mixture into a U-shaped configuration and placing the tube in a tank maintained at an upwardly extending angle to the horizontal such that the U-shaped end is closer to the lowermost end of the tank; d. filling said tank with a cold fluid maintained at approximately 0 degrees centigrade; e. pressurizing said tank to a pressure of approximately 80 psi; f. introducing hot fluid heated to a temperature of approximately 55 degrees centigrade into the bottom of the tank and causing added hot fluid to replace an equal volume of cold fluid at rate of approximately 1 foot per 120 minutes along the length of said tank, over a period of 40 hours; g. raising the temperature of the hot fluid to approximately 70 degrees centigrade and maintaining this temperature for an additional two hours; h. raising the temperature of the hot fluid to approximately 90 degrees centigrade and maintaining this temperature for an additional two hours.