Liquid toners for use with perfluorinated solvents

Claim 2

A process of forming an ge comprising the a) providing a dielectric medium having at least one region of electrostatic charge, b) intimately contacting the dielectric medium with a liquid toner having a highly fluorinated solvent and polymer resin-bound pigment particles, and C) depositing said toner in a pattern corresponding to the electrostatic charge on the dielectric medium.

Claim 3

The process of claim 1 wherein after depositing said polymer, the deposited polymer resin bound pigment particles are transferred to a receptor.

Claim 4

The process of claim 2 wherein said polymer resin comprises a copolymer of a) 65 to 89.5% by weight non-fluorinated free-radically polymerizable monomer, b) 10 to 20% by weight of a highly fluorinated macromer having only one terminating free-radically polymerizable group, and c) 0.5 to 15% by weight of a free radically polymerizable monomer having a group binding a polyvalent metal ion.

Claim 5

The process of claim 3 wherein monomer a) comprises an ethylenically unsaturated monomer.

Claim 6

The process of claim 4 wherein monomer a) comprises an acryloyl or methacryloyl monomer.

Claim 7

The process of claim 3 wherein macromer b) has a number average molecular weight between 10,000 and 250,000 grams/mole and a fluorine content of from 40 to 95% by weight.

Claim 8

The process of claim 6 wherein said macromer b) comprises a polymer formed from monomers selected from the group consisting of perfluorinated epoxides, fluorinated alkenes, fluorinated acrylates, perfluorinated vinyl ethers, and fluorinated alkyl acrylonitrile.

Claim 9

The process of claim 5 wherein said macromer b) comprises a polymer formed from monomers selected from the group consisting of perfluorinated epoxides, fluorinated alkenes, fluorinated acrylates, perfluorinated vinyl ethers, and fluorinated alkyl acrylonitrile.

Claim 10

The process of claim 2 wherein said polymer resin comprises a copolymer of 75 to 98% by weight of a highly fluorinated free-radical polymerizable, 2 to 25% by weight of a free-radically polymerizable non-fluorinated polymer, wherein from 0.5 to 25% by weight of the total polymer comprises units derived from free-radically polymerizable non-fluorinated monomer having groups capable of binding polyvalent metal ion.

Claim 11

A process of claim 1 wherein said polymer comprises a copolymer of highly fluorinated monomers selected from the group consisting of perfluorinated epoxides, fluorinated alkenes, fluorinated acrylates, perfluorinated vinyl ethers, and fluorinated alkyl acrylonitrile.

Claim 12

A liquid toner composition comprising an organic, fluorinated carrier liquid, a polymeric resin and a pigment, wherein said pigment is in intimate association with said polymeric resin, and wherein said polymeric resin is a polymer or copolymer of one or more highly fluorinated free-radically polymerizable monomers.

Claim 13

A liquid toner composition comprising an organic, fluorinated carrier liquid, a polymeric resin and a pigment, wherein said pigment is in intimate association with said polymeric resin, and wherein said polymeric resin is a polymer or copolymer of one or more highly fluorinated free-radically polymerizable monomers.

Claim 14

The toner composition of claim 11 wherein said monomers are acrylic monomers.

Claim 15

The toner of claim 11 wherein said carrier liquid comprises a fluorinated hydrocarbon.

Claim 16

A process for forming an emulsion of a hydrocarbon polymer stabilized by a fluorocarbon shell in a highly fluorinated solvent, said process comprising the steps of: 1) combining at least one free radically polymerizable monomer in a highly fluorinated solvent, with a macromer soluble in said highly fluorinated solvent, and a second monomer capable of free radical polymerization and having at least one group thereon which can sequester a metal cation, 2) emulsifying said monomers in said highly fluorinated solvent, and 3) free radically polymerizing said monomers in the presence of a metal cation charging agent.

Claim 17

A process for forming an emulsion of a hydrocarbon polymer stabilized by a fluorocarbon shell in a highly fluorinated solvent, said process comprising the steps of: 1) combining at least one free radically polymerizable monomer in a highly fluorinated solvent, with a macromer soluble in said highly fluorinated solvent, and a second monomer capable of free radical polymerization and having at least one group thereon which can sequester a metal cation, 2) emulsifying said monomers in said highly fluorinated solvent, and 3) free radically polymerizing said monomers in the presence of a metal cation charging agent.