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Alkylpolyol ethers as cosolvents for ink jet inks

Assignee: EIDP Inc
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Filing: 1992-12-22
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Granted: 1993-12-07
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Expires: 2012-12-22
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Abstract

Abstract An aqueous ink jet ink comprises an aqueous carrier medium, a colorant and at least one alkylpolyol ether cosolvent selected from the group of alkyl-bis-oxyalkyldiols, olefinic oxyalkyl diols, alkyl-tris-oxyalkyldiols and alkyl-tetrakis-oxyalkyldiols exhibit rapid drying, excellent image definition, are storage stable, have low odor and have excellent decap properties.

Inventors

  • 👤 Dominic M. Chan
  • 👤 Howard Matrick
  • 👤 Glenn M. Russo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 17:24
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 401 words
An aqueous ink jet ink composition comprising: (a) an aqueous carrier medium, (b) a colorant; and (c) from 1% to 70% by weight of at least one alkylpolyol ether cosolvent having a solubility in water of at least 4.5% at 25° C., and which is selected from the group consisting of: (1) alkyl-bis-oxyalkyldiol compounds represented by the formula: D--C.sub.n H.sub.2n --D where n=2-6, and D is a compound represented by the formula: ##STR26## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 on each of D represents the bond between D and --C n H 2n ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (2) olefinic-oxyalkyl diol compounds represented by the formula: ##STR27## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 represents --C(R) 2 (CH 2 ) d CR═C(R) 2 , where d=0 or 1 and R is --H or --CH 3 ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (3) alkyl-tris-oxyalkyldiol compounds represented by the formula: ##STR28## wherein X 1 , X 2 , and X 3 represent --H or --CH 2 CH(OH)CH 2 OH, with the proviso that any two of X 1 , X 2 , or X 3 represent --CH 2 CH(OH)CH 2 OH; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1, and (4) alkyl-tetrakis-oxyalkyldiol compounds represented by the formula: ##STR29## where L is a tetravalent alkyl group, and J is is --OCH 2 CH(OH)CH 2 OH or --OH.
Claim 2
Dependent Claim 401 words
An aqueous ink jet ink composition comprising: (a) an aqueous carrier medium, (b) a colorant; and (c) from 1% to 70% by weight of at least one alkylpolyol ether cosolvent having a solubility in water of at least 4.5% at 25° C., and which is selected from the group consisting of: (1) alkyl-bis-oxyalkyldiol compounds represented by the formula: D--C.sub.n H.sub.2n --D where n=2-6, and D is a compound represented by the formula: ##STR26## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 on each of D represents the bond between D and --C n H 2n ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (2) olefinic-oxyalkyl diol compounds represented by the formula: ##STR27## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 represents --C(R) 2 (CH 2 ) d CR═C(R) 2 , where d=0 or 1 and R is --H or --CH 3 ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (3) alkyl-tris-oxyalkyldiol compounds represented by the formula: ##STR28## wherein X 1 , X 2 , and X 3 represent --H or --CH 2 CH(OH)CH 2 OH, with the proviso that any two of X 1 , X 2 , or X 3 represent --CH 2 CH(OH)CH 2 OH; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1, and (4) alkyl-tetrakis-oxyalkyldiol compounds represented by the formula: ##STR29## where L is a tetravalent alkyl group, and J is is --OCH 2 CH(OH)CH 2 OH or --OH.
Claim 3
Dependent Claim 19 words
The ink composition of claim 1, wherein said colorant is a pigment dispersion comprising a pigment and a dispersant.
Claim 4
Dependent Claim 13 words
The ink composition of claim 2, wherein the dispersant is a polymeric dispersant.
Claim 5
Dependent Claim 50 words
The ink composition of claim 3, wherein said polymeric dispersant comprises a block copolymer and wherein the ink composition comprises approximately 0.1 to 8% pigment, 0.1 to 8% block copolymer, and 94 to 99.8% aqueous carrier medium and alkylpolyol ether cosolvent, based upon the total weight of the ink composition.
Claim 6
Dependent Claim 45 words
The ink composition of claim 1, wherein said colorant is a dye, and wherein said ink composition comprises approximately 0.2 to 20% dye, and 80 to 99.8% aqueous carrier medium and alkylpolyol ether alkylpolyol ether cosolvent, based on the total weight of the ink composition.
Claim 7
Dependent Claim 128 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an alkyl-bis-oxyalkyldiol compound represented by the formula: D--C.sub.n H.sub.2n --D where n=2-6, and D is a compound represented by the formula: ##STR30## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 on each of D represents the bond between D and --C n H 2n ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, and c is 0 or 1.
Claim 8
Dependent Claim 10 words
The ink composition of claim 5, wherein n is 3-5.
Claim 9
Dependent Claim 10 words
The ink composition of claim 5, wherein n is 4.
Claim 10
Dependent Claim 123 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an olefin oxyalkyl diol compound represented by the formula: ##STR31## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 represents --C(R) 2 (CH 2 ) d CR═C(R) 2 , where d=0 or 1 and R is --H or --CH 3 ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, and c is 0 or 1.
Claim 11
Dependent Claim 10 words
The ink composition of claim 8, wherein R=--H and d=0.
Claim 12
Dependent Claim 26 words
The ink composition of claim 5 or 9, wherein R 1 , R 2 and R 3 are --H, and a, b and c are 0.
Claim 13
Dependent Claim 112 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an alkyl-tris-oxyalkyldiol compound represented by the formula: ##STR32## wherein X 1 , X 2 , and X 3 represent --H or --CH 2 CH(OH)CH 2 OH, with the proviso that any two of X 1 , X 2 , or X 3 represent --CH 2 CH(OH)CH 2 OH; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, and c is 0 or 1.
Claim 14
Dependent Claim 38 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an alkyl-tetrakis-oxyalkyldiol compound represented by the formula: ##STR33## where L is a tetravalent alkyl group, and J is is --OCH 2 CH(OH)CH 2 OH or --OH.
Claim 15
Dependent Claim 25 words
The ink composition of claim 1, wherein the ink composition comprises a 3-10% alkylpolyol ether cosolvent based on the total weight of the ink composition.

References Cited (Backward Citations)

US4291102A Cited
US4237320A Cited
US4431450A Cited
JPS6210547A Cited
US4923515A Cited
US5049188A Cited
US5174815A Cited
US5151128A Cited
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USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-12-06 1997-06-07 1997-12-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-12-06 2001-06-07 2001-12-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-12-06 2005-06-07 2005-12-07 $7700.00 Window Closed / Lapsed

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