US5268027A
Expired / Lapsed
US
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Alkylpolyol ethers as cosolvents for ink jet inks
Assignee: EIDP Inc
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Filing: 1992-12-22
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Granted: 1993-12-07
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Expires: 2012-12-22
Abstract
Abstract An aqueous ink jet ink comprises an aqueous carrier medium, a colorant and at least one alkylpolyol ether cosolvent selected from the group of alkyl-bis-oxyalkyldiols, olefinic oxyalkyl diols, alkyl-tris-oxyalkyldiols and alkyl-tetrakis-oxyalkyldiols exhibit rapid drying, excellent image definition, are storage stable, have low odor and have excellent decap properties.
Inventors
- 👤 Dominic M. Chan
- 👤 Howard Matrick
- 👤 Glenn M. Russo
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-30 16:32
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30
Claims Analysis
Total Claims: 15
Claim 1
Independent Claim
401 words
An aqueous ink jet ink composition comprising: (a) an aqueous carrier medium, (b) a colorant; and (c) from 1% to 70% by weight of at least one alkylpolyol ether cosolvent having a solubility in water of at least 4.5% at 25° C., and which is selected from the group consisting of: (1) alkyl-bis-oxyalkyldiol compounds represented by the formula: D--C.sub.n H.sub.2n --D where n=2-6, and D is a compound represented by the formula: ##STR26## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 on each of D represents the bond between D and --C n H 2n ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (2) olefinic-oxyalkyl diol compounds represented by the formula: ##STR27## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 represents --C(R) 2 (CH 2 ) d CR═C(R) 2 , where d=0 or 1 and R is --H or --CH 3 ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (3) alkyl-tris-oxyalkyldiol compounds represented by the formula: ##STR28## wherein X 1 , X 2 , and X 3 represent --H or --CH 2 CH(OH)CH 2 OH, with the proviso that any two of X 1 , X 2 , or X 3 represent --CH 2 CH(OH)CH 2 OH; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1, and (4) alkyl-tetrakis-oxyalkyldiol compounds represented by the formula: ##STR29## where L is a tetravalent alkyl group, and J is is --OCH 2 CH(OH)CH 2 OH or --OH.
Claim 2
Dependent Claim
401 words
An aqueous ink jet ink composition comprising: (a) an aqueous carrier medium, (b) a colorant; and (c) from 1% to 70% by weight of at least one alkylpolyol ether cosolvent having a solubility in water of at least 4.5% at 25° C., and which is selected from the group consisting of: (1) alkyl-bis-oxyalkyldiol compounds represented by the formula: D--C.sub.n H.sub.2n --D where n=2-6, and D is a compound represented by the formula: ##STR26## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 on each of D represents the bond between D and --C n H 2n ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (2) olefinic-oxyalkyl diol compounds represented by the formula: ##STR27## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 represents --C(R) 2 (CH 2 ) d CR═C(R) 2 , where d=0 or 1 and R is --H or --CH 3 ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1; (3) alkyl-tris-oxyalkyldiol compounds represented by the formula: ##STR28## wherein X 1 , X 2 , and X 3 represent --H or --CH 2 CH(OH)CH 2 OH, with the proviso that any two of X 1 , X 2 , or X 3 represent --CH 2 CH(OH)CH 2 OH; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, c is 0 or 1, and (4) alkyl-tetrakis-oxyalkyldiol compounds represented by the formula: ##STR29## where L is a tetravalent alkyl group, and J is is --OCH 2 CH(OH)CH 2 OH or --OH.
Claim 3
Dependent Claim
19 words
The ink composition of claim 1, wherein said colorant is a pigment dispersion comprising a pigment and a dispersant.
Claim 4
Dependent Claim
13 words
The ink composition of claim 2, wherein the dispersant is a polymeric dispersant.
Claim 5
Dependent Claim
50 words
The ink composition of claim 3, wherein said polymeric dispersant comprises a block copolymer and wherein the ink composition comprises approximately 0.1 to 8% pigment, 0.1 to 8% block copolymer, and 94 to 99.8% aqueous carrier medium and alkylpolyol ether cosolvent, based upon the total weight of the ink composition.
Claim 6
Dependent Claim
45 words
The ink composition of claim 1, wherein said colorant is a dye, and wherein said ink composition comprises approximately 0.2 to 20% dye, and 80 to 99.8% aqueous carrier medium and alkylpolyol ether alkylpolyol ether cosolvent, based on the total weight of the ink composition.
Claim 7
Dependent Claim
128 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an alkyl-bis-oxyalkyldiol compound represented by the formula: D--C.sub.n H.sub.2n --D where n=2-6, and D is a compound represented by the formula: ##STR30## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 on each of D represents the bond between D and --C n H 2n ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, and c is 0 or 1.
Claim 8
Dependent Claim
10 words
The ink composition of claim 5, wherein n is 3-5.
Claim 9
Dependent Claim
10 words
The ink composition of claim 5, wherein n is 4.
Claim 10
Dependent Claim
123 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an olefin oxyalkyl diol compound represented by the formula: ##STR31## wherein X 1 , X 2 , and X 3 represent --H, with the proviso that one of X 1 , X 2 , or X 3 represents --C(R) 2 (CH 2 ) d CR═C(R) 2 , where d=0 or 1 and R is --H or --CH 3 ; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, and c is 0 or 1.
Claim 11
Dependent Claim
10 words
The ink composition of claim 8, wherein R=--H and d=0.
Claim 12
Dependent Claim
26 words
The ink composition of claim 5 or 9, wherein R 1 , R 2 and R 3 are --H, and a, b and c are 0.
Claim 13
Dependent Claim
112 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an alkyl-tris-oxyalkyldiol compound represented by the formula: ##STR32## wherein X 1 , X 2 , and X 3 represent --H or --CH 2 CH(OH)CH 2 OH, with the proviso that any two of X 1 , X 2 , or X 3 represent --CH 2 CH(OH)CH 2 OH; R 1 is --H, --CH 3 or --CH 2 CH 3 , R 2 is --H or C x H 2x+1 wherein x is 1-4, and R 3 is --H, --CH 3 or --CH 2 CH 3 ; a is 1-4, b is 0 or 1, and c is 0 or 1.
Claim 14
Dependent Claim
38 words
The ink composition of claim 1, wherein the alkylpolyol ether cosolvent is an alkyl-tetrakis-oxyalkyldiol compound represented by the formula: ##STR33## where L is a tetravalent alkyl group, and J is is --OCH 2 CH(OH)CH 2 OH or --OH.
Claim 15
Dependent Claim
25 words
The ink composition of claim 1, wherein the ink composition comprises a 3-10% alkylpolyol ether cosolvent based on the total weight of the ink composition.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-12-06 | 1997-06-07 | 1997-12-07 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-12-06 | 2001-06-07 | 2001-12-07 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-12-06 | 2005-06-07 | 2005-12-07 | $7700.00 | Window Closed / Lapsed |