Hydrolyzable silane copolymer compositions resistant to premature crosslinking and process

Claim 2

A filled, pelletized hydrolyzable silane copolymer composition consisting essentially of: (a) 40 to 95 weight percent of a random ethylene-vinyltriethoxysilane copolymer having a melt index from 0.1 to 50 and from 0.1 20 weight percent vinyltriethoxysilane copolymerized; and (b) 5 to 60 weight percent of a particulate filler selected from the group consisting of carbon black, aluminum trihydrate, magnesium hydroxide and mixtures thereof; said composition retaining at least 70 percent of the original melt index upon storage under ambient conditions for six months in the absence of silanol condensation catalyst but capable of being crosslinked by the action of water in the presence of a silanol condensation catalyst to a tensile strength greater than 1800 psi and elongation greater than 250 percent.

Claim 3

The composition of claim 1 which contains 0.001 to 1 weight percent antioxidant.

Claim 4

The composition of claim 1 wherein the ethylene-vinyltriethoxysilane copolymer has a melt index from 0.2 to 10 and contains from 0.5 to 7.5 weight percent copolymerized vinyltriethoxysilane.

Claim 5

The composition of claim 3 which contains 0.001 to 1 weight percent antioxidant selected from the group consisting of tetrakis[methylene 3-(3',5'-di-tertbutyl-4-hydrocinnamate)]methane, thiodiethylene bis-(3,5-ditertbutyl-4-hydroxyhydrocinnamate), n-octadecyl-β-(3,5-ditertbutyl-4-hydroxyphenyl)propionate, distearylthiodipropionate, dilaurylthiodipropionate, and polymerized 1,2-dihydro-2,2,4-trimethylquinoline.

Claim 6

A process for preparing a moisture crosslinked article whereby premature crosslinking and the problems associated therewith during processing are minimized, comprising: (1) combining (a) a filled, pelletized composition comprised of 40 to 95 weight percent of a hydrolyzable random ethylene-vinyltriethoxysilane copolymer having a melt index from 0.1 to 50 and from 0.1 to 20 weight percent vinyltriethoxysilane copolymerized, and 5 to 60 weight percent of a particulate filler selected from the group consisting of carbon black, aluminum trihydrate, magnesium hydroxide and mixtures thereof and (b) a second pelletized composition comprising an olefin polymer and 0.25 to 10 weight percent silanol condensation catalyst based on the weight of the olefin polymer; (2) processing the mixture of (a) and (b) to produce a homogeneous blend; (3) extruding the homogeneous blend to form an extruded article; and (4) contacting the extruded article with moisture to effect crosslinking.

Claim 7

A process for preparing a moisture crosslinked article whereby premature crosslinking and the problems associated therewith during processing are minimized, comprising: (1) combining (a) a filled, pelletized composition comprised of 40 to 95 weight percent of a hydrolyzable random ethylene-vinyltriethoxysilane copolymer having a melt index from 0.1 to 50 and from 0.1 to 20 weight percent vinyltriethoxysilane copolymerized, and 5 to 60 weight percent of a particulate filler selected from the group consisting of carbon black, aluminum trihydrate, magnesium hydroxide and mixtures thereof and (b) a second pelletized composition comprising an olefin polymer and 0.25 to 10 weight percent silanol condensation catalyst based on the weight of the olefin polymer; (2) processing the mixture of (a) and (b) to produce a homogeneous blend; (3) extruding the homogeneous blend to form an extruded article; and (4) contacting the extruded article with moisture to effect crosslinking.

Claim 8

The process of claim 5 wherein the ethylene-vinyltriethoxysilane copolymer contains from 0.5 to 7.5 weight percent copolymerized vinyltriethoxysilane and has a melt index of 0.2 to 10.

Claim 9

The process of claim 6 wherein the silanol condensation catalyst is selected from the group consisting of organic bases, carboxylic acids, organic titanates, and complexes or carboxylates of lead, cobalt, iron, nickel, zinc and tin.

Claim 10

The process of claim 7 wherein the olefin polymer is a homopolymer or copolymer of ethylene or propylene.

Claim 11

The process of claim 8 wherein the olefin polymer is polyethylene.

Claim 12

The process of claim 8 wherein the olefin polymer is an ethylene-vinyl acetate copolymer.

Claim 13

The process of claim 7 wherein the silanol condensation catalyst is a dialkyl tin carboxylate and constitutes from 0.5 to 5 weight percent of said second pelletized composition.

Claim 14

The process of claim 11 wherein the second pelletized composition comprises 1 to 30 weight percent of the mixture.

Claim 15

The process of claim 11 wherein the homogeneous mixture obtained from step (2) is extruded onto an electric conductor.

Claim 16

The process of claim 11 wherein step (4) is conducted at 95° C.