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US5264462A Expired / Lapsed US ⏱️ 0.0 years remaining

Polymeric foams

Assignee: Imperial Chemical Industries Ltd
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Filing: 1993-03-01
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Granted: 1993-11-23
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Expires: 2013-03-01
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Abstract

Abstract A method for the preparation of a polymeric foam which comprises vaporising a fluorine-containing ether in the presence of a foamable polymer or the precursors of a foamable polymer.

Inventors

  • 👤 Roger J. Hodson
  • 👤 Richard L. Powell
  • 👤 David Randall

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 04:04
CPC Classifications
C; C08; C08J; C08J9/00; C08J9/04; C08J9/12; C08J9/14; C08J9/143

Claims Analysis

Total Claims: 21
Claim 1
Independent Claim 35 words
A method for the preparation of a polymeric foam which comprises vaporising a fluorine-containing ether which contains no other halogen atoms in the presence of a foamable polymer or the precursors of a foamable polymer.
Claim 2
Independent Claim 35 words
A method for the preparation of a polymeric foam which comprises vaporising a fluorine-containing ether which contains no other halogen atoms in the presence of a foamable polymer or the precursors of a foamable polymer.
Claim 3
Dependent Claim 26 words
A method according to claim 1 wherein the fluorine-containing ether has a boiling point in the range from - 50° to 80° C. at 1 bar.
Claim 4
Dependent Claim 22 words
A method according to claim 2 wherein the ether has a boiling point of from -35° to 70° C. at 1 bar.
Claim 5
Dependent Claim 20 words
A method according to claim 1 wherein the fluorine-containing ether comprises a dimethyl ether containing one or more fluorine atoms.
Claim 6
Dependent Claim 16 words
A method according to claim 1 wherein the fluorine-containing ether contains three or more carbon atoms.
Claim 7
Dependent Claim 18 words
A method according to claim 5 wherein the fluorine-containing ether contains at least one hydrogen atom per molecule.
Claim 8
Dependent Claim 17 words
A method according to claim 6 wherein the ether contains two or more hydrogen atoms per molecule.
Claim 9
Dependent Claim 15 words
A method according to claim 7 wherein the ether contains more fluorine than hydrogen atoms.
Claim 10
Dependent Claim 27 words
A method according to claim 6 wherein the ether has at least one hydrogen atom attached to one or both carbon atoms adjacent to the oxygen atom.
Claim 11
Dependent Claim 36 words
A method according to claim 4 wherein the fluorine-containing ether comprises CF 3 3 OCF 3 2 H, CF 3 OCH 2 F, CF 3 3 OCH 3 or CF 3 2 HOCF 3 2 H.
Claim 12
Dependent Claim 67 words
A method according to claim 5 wherein the fluorine-containing ether comprises (CF 3 ) 2 CHOCH 2 F, HCF 2 CF 2 OCH 3 , CF 3 CF 2 OCHF 2 , CHF 2 CF 2 OCHF 2 , CF 3 2 CH 2 OCHF 2 , CF 3 CHFOCHF 2 , CF 2 HCHFOCHF 2 , CF 3 CF 2 OCF 2 CHF 2 or 2,2,3,3-tetrafluoro-oxacyclobutane.
Claim 13
Dependent Claim 29 words
A method according to claim 11 which comprises the step of incorporating a fluorine-containing ether in a foamable polymer or in one or more precursors of a foamable polymers.
Claim 14
Dependent Claim 16 words
A method according to claim 12 which comprises extruding a styrene polymer containing a fluorine-containing ether.
Claim 15
Dependent Claim 20 words
A method according to claim 13 wherein the styrene polymer contains from 5 to 20% by weight of fluorine-containing ether.
Claim 16
Dependent Claim 28 words
A method according to claim 1 which comprises reacting an organic polyisocyanate with a polymeric polyol in the presence of a fluorine-containing ether to form a polyurethane foam.
Claim 17
Dependent Claim 14 words
A method according to claim 15 wherein the organic polyisocyanate comprises a diphenylmethane diisocyanate.
Claim 18
Dependent Claim 22 words
A method according to claim 15 or claim 16 wherein the polymeric polyol has a hydroxyl number of from 200 to 800.
Claim 19
Dependent Claim 19 words
A method according to claim 17 wherein the polymeric polyol has a hydroxyl number of from 300 to 600.
Claim 20
Dependent Claim 19 words
A method according to claim 15 wherein the polymeric polyol has a hydroxyl functionality of from 2 to 8.
Claim 21
Dependent Claim 19 words
A method according to claim 19 wherein the polymeric polyol has a hydroxyl functionality of from 3 to 8.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-11-22 1997-05-24 1997-11-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-11-22 2001-05-24 2001-11-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-11-22 2005-05-24 2005-11-23 $7700.00 Window Closed / Lapsed

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