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Charge transporting layers formed from curable compositions

Assignee: Xerox Corp
•
Filing: 1992-02-05
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Granted: 1993-11-23
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Expires: 2012-02-05
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Abstract

Abstract A process for preparing a photoreceptor by forming a coating of a substrate followed by curing. The coating contains an electroactive material dissolved or dispersed in a polymerizable film forming monomer, which is first polymerized into a solid matrix.

Inventors

  • 👤 Milan Stolka
  • 👤 Ian D. Morrison
  • 👤 Bing R. Hseih

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-09 18:24
CPC Classifications
G; G03; G03G; G03G5/00; G03G5/02; G03G5/04; G03G5/05; G03G5/0525; H; H10; H10K; H10K85/00; H10K85/60; H10K85/631

Claims Analysis

Total Claims: 20
Claim 1
Independent Claim 87 words
A process for preparing a photoreceptor comprising the steps of: a) dissolving an aromatic amine charge transporting material in a solvent consisting essentially of a polymerizable film forming monomer or a mixture of polymerizable film forming monomers to form a coating solution, said solvent subject to addition polymerization in the presence of a cationic initiator; b) coating a substrate with said coating solution; and c) photochemically curing said coating solution such that said monomer forms a polymer that is miscible with said aromatic amine charge transporting material.
Claim 2
Dependent Claim 87 words
A process for preparing a photoreceptor comprising the steps of: a) dissolving an aromatic amine charge transporting material in a solvent consisting essentially of a polymerizable film forming monomer or a mixture of polymerizable film forming monomers to form a coating solution, said solvent subject to addition polymerization in the presence of a cationic initiator; b) coating a substrate with said coating solution; and c) photochemically curing said coating solution such that said monomer forms a polymer that is miscible with said aromatic amine charge transporting material.
Claim 3
Dependent Claim 16 words
The process of claim 1 wherein said polymerizable film forming monomer is a curable liquid monomer.
Claim 4
Dependent Claim 17 words
The process of claim 2 wherein said aromatic amine charge transporting material is a charge transporting molecule.
Claim 5
Dependent Claim 11 words
The process of claim 3 wherein said molecule is N,N'-bis(4-methylphenyl) -N,N'-bis(4-ethylphenyl)-[1,1'-(3,3'-dimethyl)biphenyl]4,4'-diamine.
Claim 6
Dependent Claim 17 words
The process of claim 2 wherein said aromatic amine charge transporting material is a charge transporting polymer.
Claim 7
Dependent Claim 13 words
The process of claim 5 wherein said polymer is a m-TBD/bisphenol-A siloxy copolymer.
Claim 8
Dependent Claim 25 words
The process of claim 2 wherein said curable liquid monomer is selected from the group consisting of epoxides, alkoxy styrenes, acrylates, methacrylates, and vinyl ethers.
Claim 9
Dependent Claim 13 words
The process of claim 7 wherein said curable liquid monomer is butanedioldivinyl ether.
Claim 10
Dependent Claim 17 words
The process of claim 1 wherein said aromatic amine charge transporting material is a charge transporting molecule.
Claim 11
Dependent Claim 10 words
The process of claim 9 wherein said molecule is N,N'-bis(4-methylpenyl)-N,N'-bis(4-ethylphenyl)-[1,1'-(3,3'-dimethyl)biphenyl]-4,4'-diamine.
Claim 12
Dependent Claim 17 words
The process of claim 1 wherein said aromatic amine charge transporting material is a charge transporting polymer.
Claim 13
Dependent Claim 14 words
The process of claim 11 wherein said polymer is a N,N'-diphenyl-N,N'-bis (3-methylphenyl)1,1'-diphenyl-4,4'-diamine/bisphenol-A siloxy copolymer.
Claim 14
Dependent Claim 20 words
The process of claim 1 wherein said cationic initiator initiator is added to said coating solution before coating said substrate.
Claim 15
Independent Claim 144 words
A method for forming a charge transporting layer comprising: obtaining a curable coating solution comprising a vinyl ether curable liquid monomer; a photoinitator selected from diaryl iodonium salts and their derivatives, triaryl sulfonium salts and their derivatives; and triphenyl phosphonium salts and their derivatives, and an aromatic amine charge transporting material comprising a compound of the genral formula: ##STR7## wherein R 1 and R 2 are aromatic groups selected from substituted or unsubstituted phenyl groups, naphthyl groups and polyphenyl groups, and wherein R 4 is selected from substituted or unsubstituted biphenyl groups, diphenyl ether groups, alkyl groups having from 1 to 18 carbon atoms, and cycloaliphatic groups having from 3 to 12 carbons; b) coating a substrate with said coating solution; and c) curing said coating solution such that said monomer forms a polymer that is miscible with said aromatic amine charge transporting material.
Claim 16
Independent Claim 144 words
A method for forming a charge transporting layer comprising: obtaining a curable coating solution comprising a vinyl ether curable liquid monomer; a photoinitator selected from diaryl iodonium salts and their derivatives, triaryl sulfonium salts and their derivatives; and triphenyl phosphonium salts and their derivatives, and an aromatic amine charge transporting material comprising a compound of the genral formula: ##STR7## wherein R 1 and R 2 are aromatic groups selected from substituted or unsubstituted phenyl groups, naphthyl groups and polyphenyl groups, and wherein R 4 is selected from substituted or unsubstituted biphenyl groups, diphenyl ether groups, alkyl groups having from 1 to 18 carbon atoms, and cycloaliphatic groups having from 3 to 12 carbons; b) coating a substrate with said coating solution; and c) curing said coating solution such that said monomer forms a polymer that is miscible with said aromatic amine charge transporting material.
Claim 17
Dependent Claim 15 words
The method of claim 14 wherein said vinyl ether curable liquid monomer is butanedioldivinyl ether.
Claim 18
Dependent Claim 17 words
The method of claim 15 wherein said aromatic amine charge transporting material comprises N,N'-diphenyl-N,N'-bis (3-methylphenyl)1,1'-diphenyl-4,4'-diamine/bisphenol-A siloxy copolymer.
Claim 19
Dependent Claim 16 words
The method of claim 14 wherein said aromatic amine charge transporting material is N,N'-bis(4-methylphenyl) N,N'-bis(4-ethylphenyl)-(1,1'-(3,3'-dimethyl) biphenyl)-4,4'-diamine.
Claim 20
Dependent Claim 12 words
The method of claim 14 wherein said photoinitator is di(i-butylphenyl) iodinium hexafluoroarsenate.

References Cited (Backward Citations)

GB1188330A Cited
US4296190A Cited
US4275133A Cited
JPS6466656A Cited
US4883731A Cited
US4988595A Cited

USPTO Annuity & Maintenance Windows

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