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US5256387A Expired / Lapsed US ⏱️ 0.0 years remaining

Catalyst for the production of nitric acid by oxidation of ammonia

Assignee: ADVANCED CATALYST LLC
•
Filing: 1992-11-09
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Granted: 1993-10-26
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Expires: 2012-11-09
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Abstract

Abstract Reticulated ceramic or metal substrate coated with Cobalt compounds, noble metals or mixtures thereof are superior catalysts for the oxidation of ammonia to produce nitric oxide.

Inventors

  • 👤 Larry E. Campbell

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 04:58
CPC Classifications
B; B01; B01J; B01J37/00; B01J37/02; B01J37/0215; B01J23/00; B01J23/70; B01J23/89; B01J23/8913; C; C01; C01B; C01B21/00; C01B21/20; C01B21/24; C01B21/26; C01B21/265

Claims Analysis

Total Claims: 16
Claim 1
Independent Claim 65 words
A method of preparing nitric oxide comprising contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of a reticulated ceramic foam or a reticulated metal foam having coated substantially uniformly thereover from 1 to 70 weight % cobalt, a noble metal or mixtures thereof.
Claim 2
Independent Claim 65 words
A method of preparing nitric oxide comprising contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of a reticulated ceramic foam or a reticulated metal foam having coated substantially uniformly thereover from 1 to 70 weight % cobalt, a noble metal or mixtures thereof.
Claim 3
Dependent Claim 23 words
The method according to claim 1 wherein from about 2 to 20 weight % of said noble metal is coated on said substrate.
Claim 4
Dependent Claim 20 words
The method according to claim 2 wherein in said noble metal is Pt, Pd, Rh, Ru, Os or mixtures thereof.
Claim 5
Dependent Claim 13 words
The method according to claim 1 wherein said substrate is coated substantially continuously.
Claim 6
Dependent Claim 16 words
The method according to claim 3 wherein said metal coating on said substrate is electrically conductive.
Claim 7
Dependent Claim 11 words
The method according to claim 1 wherein said coating comprises platinum.
Claim 8
Independent Claim 59 words
A method of preparing nitric oxide comprising contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of a reticulated ceramic foam or a reticulated metal foam having coated substantially uniformly thereover from 15 to 30 weight % cobalt.
Claim 9
Independent Claim 59 words
A method of preparing nitric oxide comprising contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of a reticulated ceramic foam or a reticulated metal foam having coated substantially uniformly thereover from 15 to 30 weight % cobalt.
Claim 10
Independent Claim 82 words
A method of preparing nitric acid comprising: (a) contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of reticulated ceramic foam or reticulated metal foam having coated substantially continuously thereover from 1 to 70 weight % Co, Pt, Pd, Rh or mixtures thereof to produce a vaporous reaction product containing nitric oxide and (b) contacting said vaporous reaction product with water.
Claim 11
Independent Claim 82 words
A method of preparing nitric acid comprising: (a) contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of reticulated ceramic foam or reticulated metal foam having coated substantially continuously thereover from 1 to 70 weight % Co, Pt, Pd, Rh or mixtures thereof to produce a vaporous reaction product containing nitric oxide and (b) contacting said vaporous reaction product with water.
Claim 12
Dependent Claim 23 words
The method according to claim 8 wherein said coating comprises from about 2 to 20 weight % Pt, Pd, Rh or mixtures thereof.
Claim 13
Dependent Claim 16 words
The method according to claim 8 wherein said metal coating on said substrate is electrically conductive.
Claim 14
Dependent Claim 11 words
The method according to claim 8 wherein said coating comprises platinum.
Claim 15
Independent Claim 76 words
A method of preparing nitric acid comprising: (a) contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of reticulated ceramic foam or reticulated metal foam having coated substantially continuously thereover from 15 to 30 weight % cobalt to produce a vaporous reaction product containing nitric oxide and (b) contacting said vaporous reaction product with water.
Claim 16
Independent Claim 76 words
A method of preparing nitric acid comprising: (a) contacting ammonia and a free oxygen containing gas in vapor phase in the presence of a catalyst structure for the oxidation of ammonia to produce nitric oxide comprising a substrate of reticulated ceramic foam or reticulated metal foam having coated substantially continuously thereover from 15 to 30 weight % cobalt to produce a vaporous reaction product containing nitric oxide and (b) contacting said vaporous reaction product with water.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-10-25 1997-04-26 1997-10-26 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-10-25 2001-04-26 2001-10-26 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-10-25 2005-04-26 2005-10-26 $7700.00 Window Closed / Lapsed

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