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US5250109A Expired / Lapsed US ⏱️ 0.0 years remaining

Derivatives of polyoxyalkyleneamines as cosolvents for aqueous ink jet inks

Assignee: EIDP Inc
•
Filing: 1992-12-22
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Granted: 1993-10-05
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Expires: 2012-12-22
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Abstract

Abstract Aqueous ink jet ink compositions comprising an aqueous carrier medium, a colorant, and cosolvents which are selected amide, sulfonamide, urea and thiourea derivatives of polyoxyalkyleneamines having a solubility in water of at least 4.5% at 25° C., have high optical density, excellent print quality, excellent dispersion stability, and resist film formation on resistors without adversely affecting decap time or crusting.

Inventors

  • 👤 Dominic M. Chan
  • 👤 Howard Matrick
  • 👤 Glenn M. Russo

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-01 23:55
CPC Classifications
C; C09; C09D; C09D11/00; C09D11/30

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 234 words
An aqueous ink jet ink composition comprising: (a) an aqueous carrier medium; (b) a colorant selected from the group consisting of a pigment dispersion and a dye; and (c) a cosolvent having a solubility in water of at least 4.5% at 25° C., and which is selected from the group consisting of: (1) Monocarboxamide, monosulfonamide, monourea and monothiourea derivatives of polyoxyalkylene monoamines having the following structure: R--Y--NR'CHXCH.sub.2 (OCHXCH.sub.2).sub.n OR" wherein R=--H or an alkyl group of 1-4 carbons; R'=--H, an alkyl group of 1-3 carbons, or an alkyl group of 1-4 carbons containing one hydroxyl group; X=--H or --CH 3 independently; n=1-200; R"=an alkyl group of 1-4 carbons; and Y is a divalent connecting group of atoms selected from the group consisting of: ##STR8## (2) Bis-carboxamide, bis-sulfonamide, bis-urea and bis-thiourea derivatives of polyoxyalkylenediamines having the following structure: R--Y--R'NCXCH.sub.2 (OCHXCH.sub.2).sub.n OCH.sub.2 CHXNR'--Y--R wherein R, R', X, and Y are as defined above; and n=2-400; (3) Tris-carboxamide, tris-sulfonamide, tris-urea and tris-thiourea derivatives of polyoxyalkylenetriamines having the following structure: ##STR9## wherein R, R', X, and Y are as defined above; n+p+q=3-500; and a=0 or 1; (4) Monourea, monosulfonamide and monothiourea derivatives of bis-polyoxyalkyleneamines having the following structure: R"O(CH.sub.2 CHXO).sub.n CH.sub.2 CHXNR'--Y--NR'CHXCH.sub.2 (OCHXCH.sub.2).sub.n OR" wherein R, R', and X are as defined above; n=1-200; R"=an alkyl group of 1-3 carbons; and Y is a divalent connecting group of atoms selected from the group of: ##STR10## (5) mixtures thereof.
Claim 2
Dependent Claim 234 words
An aqueous ink jet ink composition comprising: (a) an aqueous carrier medium; (b) a colorant selected from the group consisting of a pigment dispersion and a dye; and (c) a cosolvent having a solubility in water of at least 4.5% at 25° C., and which is selected from the group consisting of: (1) Monocarboxamide, monosulfonamide, monourea and monothiourea derivatives of polyoxyalkylene monoamines having the following structure: R--Y--NR'CHXCH.sub.2 (OCHXCH.sub.2).sub.n OR" wherein R=--H or an alkyl group of 1-4 carbons; R'=--H, an alkyl group of 1-3 carbons, or an alkyl group of 1-4 carbons containing one hydroxyl group; X=--H or --CH 3 independently; n=1-200; R"=an alkyl group of 1-4 carbons; and Y is a divalent connecting group of atoms selected from the group consisting of: ##STR8## (2) Bis-carboxamide, bis-sulfonamide, bis-urea and bis-thiourea derivatives of polyoxyalkylenediamines having the following structure: R--Y--R'NCXCH.sub.2 (OCHXCH.sub.2).sub.n OCH.sub.2 CHXNR'--Y--R wherein R, R', X, and Y are as defined above; and n=2-400; (3) Tris-carboxamide, tris-sulfonamide, tris-urea and tris-thiourea derivatives of polyoxyalkylenetriamines having the following structure: ##STR9## wherein R, R', X, and Y are as defined above; n+p+q=3-500; and a=0 or 1; (4) Monourea, monosulfonamide and monothiourea derivatives of bis-polyoxyalkyleneamines having the following structure: R"O(CH.sub.2 CHXO).sub.n CH.sub.2 CHXNR'--Y--NR'CHXCH.sub.2 (OCHXCH.sub.2).sub.n OR" wherein R, R', and X are as defined above; n=1-200; R"=an alkyl group of 1-3 carbons; and Y is a divalent connecting group of atoms selected from the group of: ##STR10## (5) mixtures thereof.
Claim 3
Dependent Claim 19 words
The ink composition of claim 1, wherein said colorant is a pigment dispersion comprising a pigment and a dispersant.
Claim 4
Dependent Claim 45 words
The ink composition of claim 2, wherein the dispersant comprises a block copolymer, said ink composition comprises approximately 0.1 to 8% pigment, 0.1 to 8% block copolymer, and 94 to 99.8% aqueous carrier medium and cosolvent, based upon the total weight of the ink composition.
Claim 5
Dependent Claim 22 words
The ink composition of claim 2, wherein the pigment comprises particles having a median particle size of approximately 0.01 to 0.4 micron.
Claim 6
Dependent Claim 41 words
The ink composition of claim 1, wherein said colorant is a dye and wherein said ink composition comprises approximately 0.01 to 20% dye, and 80 to 99.8% aqueous carrier medium and cosolvent, based on the total weight of the ink composition.
Claim 7
Dependent Claim 14 words
The ink composition of claim 1, wherein the cosolvent is represented by structure (1).
Claim 8
Dependent Claim 14 words
The ink composition of claim 1, wherein the cosolvent is represented by structure (2).
Claim 9
Dependent Claim 14 words
The ink composition of claim 1, wherein the cosolvent is represented by structure (3).
Claim 10
Dependent Claim 14 words
The ink composition of claim 1, wherein the cosolvent is represented by structure (4).
Claim 11
Dependent Claim 10 words
The ink composition of claim 1, wherein Y is: ##STR11##
Claim 12
Dependent Claim 10 words
The ink composition of claim 1, wherein Y is: ##STR12##
Claim 13
Dependent Claim 21 words
The ink composition of claim 1, wherein said cosolvent comprises 3-25% by weight of the total weight of the ink composition.
Claim 14
Dependent Claim 21 words
The ink composition of claim 1, wherein said cosolvent comprises 3-10% by weight of the total weight of the ink composition.
Claim 15
Dependent Claim 14 words
The ink composition of claim 1, wherein X is 50-100 mole per cent --H.
Claim 16
Dependent Claim 14 words
The ink composition of claim 1, wherein X is 80-100 mole per cent --H.
Claim 17
Dependent Claim 33 words
The ink composition of claim 6 wherein the cosolvent is the monoacetyl amide of a polyoxyalkyleneamine having the formula: CH.sub.3 OCH.sub.2 CH.sub.2 O(CH.sub.2 CH.sub.2 O).sub.n [CH.sub.2 CH(CH.sub.3)].sub.p CH.sub.2 CH(CH.sub.3)NH.sub.2, where n=18 and p=3.
Claim 18
Dependent Claim 37 words
The ink composition of claim 9 wherein the cosolvent is a 1,3-disubstituted urea derived from two moles of a polyoxyalkyleneamine having the formula: CH.sub.3 OCH.sub.2 CH.sub.2 O(CH.sub.2 CH.sub.2 O).sub.n [CH.sub.2 CH(CH.sub.3)].sub.p CH.sub.2 CH(CH.sub.3)NH.sub.2, where n=18 and p=3.
Claim 19
Dependent Claim 10 words
The ink composition of claim 1, further comprising a surfactant.

References Cited (Backward Citations)

US4508570A Cited
US5174815A Cited
US5019164A Cited
US5151128A Cited
US5149367A Cited
US5129948A Cited
US5156675A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-10-04 1997-04-05 1997-10-05 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-10-04 2001-04-05 2001-10-05 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-10-04 2005-04-05 2005-10-05 $7700.00 Window Closed / Lapsed

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