Electroluminescent device having sub-interlayers for high luminous efficiency with device life

Claim 2

A highly luminous efficient electroluminescence device with a long device life having sequentially stacked elements on a transparent and electrically insulating substrate, comprising: a) a first transparent electrode; b) a luminescent layer; c) a current-limiting layer comprising a binder and a conductive powder, said conductive powder essentially consisting of carbon black; d) an interlayer containing a first semiconductor having a band gap of more than 2.4 eV, said interlayer being disposed between said current-limiting layer and said luminescent layer, said interlayer further comprising a first sub-interlayer and a second sub-interlayer which is placed below said first sub-interlayer, said first sub-interlayer essentially consisting of at least one element selected from the group consisting of CaS, SrS and BaS, said second sub-interlayer being essentially free of oxygen and having a resistivity of less than 10 3 Ω cm at more than a threshold voltage of said luminescence layer; and e) a second electrode placed above said current limiting layer.

Claim 3

An electroluminescence device according to claim 1, wherein said luminescent layer consists essentially of a second semiconductor and is doped with an element serving as a luminescent center.

Claim 4

An electroluminescence device according to claim 2, wherein said element serving as the luminescent center is doped in said first semiconductor.

Claim 5

An electroluminescence device according to claim 3, wherein said first and second semiconductors are of different types.

Claim 6

An electroluminescence device according to claim 3, wherein said first and second semiconductors are of the same type and have different band gaps.

Claim 7

An electroluminescence device according to claim 1, wherein said first semiconductor is at least one type of a semiconductor selected from the group consisting of ZnS, ZnSe, CaS, CaSe, SrS, SrSe and Cds.

Claim 8

An electroluminescence device according to claim 1, wherein an additional interlayer is formed between said first electrode and said luminescent layer. PG,56

Claim 9

An electroluminescence device according to claim 1, where said luminescent layer is divided into at least two sub-layers, an additional interlayer being formed between said divided sub-layers.

Claim 10

An electroluminescence device according to claim 1, wherein said interlayer has a film thickness of 10 nm to 300 nm.

Claim 11

An electroluminescence device according to claim 9, wherein said interlayer has a film thickness of 50 nm to 150 nm.

Claim 12

An electroluminescence device according to claim 1 wherein said second sub-interlayer essentially consists of a material selected from the group consisting of ZnS, ZnSe, CdS, silicon nitride, aluminum nitride, silicon oxynitride essentially free of oxygen and aluminum oxynitride essentially free of oxygen.

Claim 13

An electroluminescence device according to claim 1 where said second sub-interlayer essentially consists of a material selected from a group consisting of a silicide, a carbide and a boride of a transition metal.

Claim 14

An electroluminescence device comprising a first transparent electrode, a luminescent layer, a current-limiting layer comprising a conductive powder and a binder, wherein said conductive powder consists of particles each having at least one nib or aggregates thereof, said nib being electrically in point contact with a surface of said luminescent layer, and a second electrode, said first electrode, luminescent layers, current limiting layer and secured electrode being sequentially stacked on a transparent substrate which has electrical insulating properties.

Claim 15

An electroluminescence device comprising a first transparent electrode, a luminescent layer, a current-limiting layer comprising a conductive powder and a binder, wherein said conductive powder consists of particles each having at least one nib or aggregates thereof, said nib being electrically in point contact with a surface of said luminescent layer, and a second electrode, said first electrode, luminescent layers, current limiting layer and secured electrode being sequentially stacked on a transparent substrate which has electrical insulating properties.

Claim 16

An electroluminescence device according to claim 13, wherein a radius of curvature of said nib of said conductive powder to be electrically in point contact with the surface of said luminescent layer is not more than 5 nm.

Claim 17

An electroluminescence device according to claim 14, wherein a particle size of said conductive powder is not more than 10 nm.

Claim 18

An electroluminescence device according to claim 13, wherein a shape of said particles or aggregates is selected from the group consisting of a tetrahedron, a hexahedron an octahedron, an icositetrahedron, a column, a spindle or a needle.

Claim 19

An electroluminescence device according to claim 13, wherein said particles each having a nib or aggregates thereof are radial aggregates in which needle-like crystals are radially aggregated.

Claim 20

An electroluminescence device according to claim 17, wherein an aspect ratio of a major axis to a minor axis of said needle-like crystal is not less than 5:1.

Claim 21

An electroluminescence device according to claim 18, wherein said aspect ratio is not less than 10:1.

Claim 22

An electroluminescence device according to claim 18, wherein said needle-like crystal is an elongated spindle elongated in a major axis direction thereof.

Claim 23

An electroluminescence device according to claim 17, wherein a length of two minor axes perpendicular to each other of said needle-like crystal is 1 nm to 10 nm, and a length of a major axis thereof is 50 nm to 200 nm.

Claim 24

An electroluminescence device according to claim 17, wherein said radial aggregate of needle-like crystals consists of α-MnO 2 or γ-MnO 2 produced by a reaction in an aqueous solution of potassium permanganate and manganese sulfate, δ-MnO 2 produced by a reaction in an aqueous solution of potassium permanganate and hydrochloric acid, or tetra pod-like ZnO produced by a vapor phase reaction.

Claim 25

An electroluminescence device according to claim 13, wherein said binder comprises a polymeric organic resin selected from the group consisting of a polar group such as a hydroxyl group, a carboxyl group, a sulfonyl group or a nitro group, or a reactive group such as an epoxy group, an isocyanuric group and a silanol group.

Claim 26

An electroluminescence device according to claim 23, wherein a volume mixing ratio of said conductive powder to said binder resin falls within a range of 2:8 to 6:4.

Claim 27

An electroluminescence device according to any one of claim 1, 15 or 13, wherein said first electrode is divided into stripes in an X direction on an X-Y plane, and said current-limiting layer and said second electrode are divided into stripes in a Y direction.

Claim 28

An electroluminescence device according to any one of claim 1, 15, or 13, wherein at least said first electrode is divided into a predetermined pattern on a plan thereof.

Claim 29

An electroluminescence device having a transparent first electrode, a luminescent layer, a current-limiting layer consisting of at least a binder resin consisting of a polymeric organic resin selected from the group consisting of a polar group such as a hydroxyl group, a carboxyl group, a sulfonyl group, a nitro group, and a reactive group including an epoxy group, an isocyanuric group and a silanol group and a conductive powder essentially consisting of carbon black which comprises a barium titanate powder, wherein said barium titanate powder and said binder resin satisfy the following relations (1) to (3): C/A≧1.5 (1) B≧50% (2) C≧5% (3) where A is the ratio of the solid volume of said barium titanate to the volume of said current-limiting layer, B is the ratio of the solid volume of said binder resin to the volume of said current-limiting layer, and C is the ratio of the solid volume of said carbon black to the volume of said current-limiting layer; a second electrode; and a transparent substrate having electrical insulating properties, said first electrode, said luminescent layer, said current-limiting layer and said second electrode being sequentially stacked on said transparent substrate.

Claim 30

An electroluminescence device having a transparent first electrode, a luminescent layer, a current-limiting layer consisting of at least a binder resin consisting of a polymeric organic resin selected from the group consisting of a polar group such as a hydroxyl group, a carboxyl group, a sulfonyl group, a nitro group, and a reactive group including an epoxy group, an isocyanuric group and a silanol group and a conductive powder essentially consisting of carbon black which comprises a barium titanate powder, wherein said barium titanate powder and said binder resin satisfy the following relations (1) to (3): C/A≧1.5 (1) B≧50% (2) C≧5% (3) where A is the ratio of the solid volume of said barium titanate to the volume of said current-limiting layer, B is the ratio of the solid volume of said binder resin to the volume of said current-limiting layer, and C is the ratio of the solid volume of said carbon black to the volume of said current-limiting layer; a second electrode; and a transparent substrate having electrical insulating properties, said first electrode, said luminescent layer, said current-limiting layer and said second electrode being sequentially stacked on said transparent substrate.