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Method of forming a gate insulating film involving a step of cleaning using an ammonia-peroxide solution

Assignee: Seiko Epson Corp
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Filing: 1991-08-13
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Granted: 1993-07-20
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Expires: 2011-08-13
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Abstract

Abstract A method of producing a semiconductor device which comprises; a first cleaning step of cleaning the surface of Si of a semiconductor device having an Si base or an Si thin film as a substrate (1) by using an APM solution; a second cleaning step of cleaning the surface of Si by using a dilute HF solution to thereby remove the uppermost surface layer (3) of a naturally oxidized film (2) formed in the first cleaning step; and a step of forming a silicon oxide film by thermally oxidizing the cleaned surface of the naturally oxidized film (2).

Inventors

  • 👤 Juri Kato

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 11:32
CPC Classifications
H; H10; H10P; H10P70/00; H10P70/10; H10P70/18; H10P14/00; H10P14/60; H10P14/63; H10P14/6302; H10P14/6322; H10P14/65; H10P14/6502; H10P14/6506; H10P14/6508; H10P70/15; H10P14/6304; H10P14/6306; H10P14/6308; H10P14/6309; Y; Y10; Y10S; Y10S438/00; Y10S438/906

Claims Analysis

Total Claims: 6
Claim 1
Independent Claim 94 words
A method of fabricating a semiconductor device comprising: a first step of cleaning a surface of a silicon body using an ammonia-peroxide solution and producing, by the cleaning step, a first layer of naturally formed oxide having a first thickness on said surface, a second step of removing, by use of a dilute hydrofluoric acid solution, a preselected thickness of said first layer while leaving a portion of said first layer on and protecting said surface; and a step of then forming a second layer of silicon oxide on said surface by thermal oxidation.
Claim 2
Independent Claim 94 words
A method of fabricating a semiconductor device comprising: a first step of cleaning a surface of a silicon body using an ammonia-peroxide solution and producing, by the cleaning step, a first layer of naturally formed oxide having a first thickness on said surface, a second step of removing, by use of a dilute hydrofluoric acid solution, a preselected thickness of said first layer while leaving a portion of said first layer on and protecting said surface; and a step of then forming a second layer of silicon oxide on said surface by thermal oxidation.
Claim 3
Dependent Claim 24 words
A method according to claim 1 including, after forming said second layer, removing a preselected thickness from an upper portion of said second layer.
Claim 4
Dependent Claim 16 words
A method according to claim 1 wherein said dilute hydrofluoric acid solution includes hydrogen peroxide acid.
Claim 5
Dependent Claim 27 words
A method according to claim 2 wherein a dilute hydrofluoric acid solution is used for removing said preselected thickness from the upper portion of said second layer.
Claim 6
Dependent Claim 29 words
A method according to claim 1 wherein said preselected thickness of said first layer removed during said second step is within the range from 1 Å to 8 Å.

References Cited (Backward Citations)

US3158517A Cited
US4264374A Cited
US4867799A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-07-19 1997-01-18 1997-07-20 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-07-19 2001-01-18 2001-07-20 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-07-19 2005-01-18 2005-07-20 $7700.00 Window Closed / Lapsed

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