Patent US5229243A successfully refreshed from Google Patents.
US5229243A
Expired / Lapsed
US
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Capsulated toner for heat pressure fixation
Assignee: Kao Corp
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Filing: 1992-02-11
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Granted: 1993-07-20
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Expires: 2012-02-11
Abstract
Abstract A capsulated toner for heat pressure fixation comprising a heat-meltable core material and an outer shell, said core material containing a colorant and a thermoplastic resin as a major constituent, produced by copolymerizing (A) an α,β-ethylenically copolymerizable monomer having an amino group and (B) α,β-ethylenically copolymerizable monomer other than (A), said outer shell being provided so as to cover the surface of the core material. When the capsulated toner of the present invention is used, the dependency of the amount of electrification upon the environment is small because the electrification can be regulated from within the capsulated toner. Further, because the offset resistance in a heat pressure fixation system, such as a heat roller, is excellent, the fixation can be conducted at a low temperature. Further, the blocking resistance is so good that a clear image, free from fogging, can be stably formed over a plurality of uses.
Inventors
- 👤 Mitsuhiro Sasaki
- 👤 Kuniyasu Kawabe
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-26 22:08
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/093; G03G9/0935; G03G9/09357; G03G9/09364; G03G9/09307; G03G9/09314; G03G9/09328
Claims Analysis
Total Claims: 18
Claim 1
Independent Claim
323 words
A capsulated toner for heat pressure fixation comprising a heat-meltable core material and an outer shell, wherein said core material contains a colorant and a thermoplastic resin produced by copolymerizing 0.5 to 20% by weight of (A) an α,β-ethylenically copolymerizable monomer having a amino group and 99.95 to 80% by weight of (B) α,β-ethylenically copolymerizable monomer other than (A), wherein the percentages of components (A) and (B) are based on the total weight of components (A) and (B); wherein said outer shell, being provided to cover the surface of the core material, comprises a resin produced by reacting (1) a monoisocyanate compound or a monoisothiocyanate compound or a mixture thereof in an amount of 0 to 30% by mole; (2) a di- or higher isocyanate compound, a di- or higher isothiocyanate compound, or a mixture thereof in an amount of 100 to 70% by mole; (3) a compound having one active hydrogen reactive with an isocyanate group, an isothiocyanate group, or a mixture thereof, in an amount of 0 to 30% by mole; and (4) a compound having two or more active hydrogens reactive with an isocyanate group, an isothiocyanate group, or a mixture thereof, in an amount of 100 to 70% by mole; wherein the mole percentages of components (1) and (2) are based upon the total moles components of (1) and (2), and wherein the mole percentages of components (3) and (4) are based upon the total moles of (3) and (4); wherein components (1), (2), (3), and (4) are present in such a proportion that the ratio of the total number of moles of components (1) and (2) to the total number of moles of the components (3) and (4) is in the range of from 1:1 to 1:20, and wherein said resin has a thermally dissociable bond occupying 30% or more of the total number of bonds in which the isocyanate group, isothiocyanate group or combination thereof, are involved.
Claim 2
Dependent Claim
323 words
A capsulated toner for heat pressure fixation comprising a heat-meltable core material and an outer shell, wherein said core material contains a colorant and a thermoplastic resin produced by copolymerizing 0.5 to 20% by weight of (A) an α,β-ethylenically copolymerizable monomer having a amino group and 99.95 to 80% by weight of (B) α,β-ethylenically copolymerizable monomer other than (A), wherein the percentages of components (A) and (B) are based on the total weight of components (A) and (B); wherein said outer shell, being provided to cover the surface of the core material, comprises a resin produced by reacting (1) a monoisocyanate compound or a monoisothiocyanate compound or a mixture thereof in an amount of 0 to 30% by mole; (2) a di- or higher isocyanate compound, a di- or higher isothiocyanate compound, or a mixture thereof in an amount of 100 to 70% by mole; (3) a compound having one active hydrogen reactive with an isocyanate group, an isothiocyanate group, or a mixture thereof, in an amount of 0 to 30% by mole; and (4) a compound having two or more active hydrogens reactive with an isocyanate group, an isothiocyanate group, or a mixture thereof, in an amount of 100 to 70% by mole; wherein the mole percentages of components (1) and (2) are based upon the total moles components of (1) and (2), and wherein the mole percentages of components (3) and (4) are based upon the total moles of (3) and (4); wherein components (1), (2), (3), and (4) are present in such a proportion that the ratio of the total number of moles of components (1) and (2) to the total number of moles of the components (3) and (4) is in the range of from 1:1 to 1:20, and wherein said resin has a thermally dissociable bond occupying 30% or more of the total number of bonds in which the isocyanate group, isothiocyanate group or combination thereof, are involved.
Claim 3
Dependent Claim
40 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said thermally dissociable bond is a bond derived from a reaction of a phenolic hydroxyl group and/or a thiol group with an isocyanate group and/or an isothiocyanate group.
Claim 4
Dependent Claim
25 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said thermoplastic resin has a glass transition temperature of 10° to 50° C.
Claim 5
Dependent Claim
24 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said capsulated toner has a softening point of 80° to 150° C.
Claim 6
Dependent Claim
291 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said thermally dissociable bond is a bond derived from a reaction of a phenolic hydroxyl group of at least one compound selected from the group consisting of compounds represented by the following formulae (I) to (III) and/or a thiol group with an isocyanate group and/or an isothiocyanate group: ##STR6## wherein R 1 , R 2 , R 3 , R 4 and R 5 each independently stand for hydrogen atom, an alkyl group having 1 to 9 carbon atoms, an alkenyl group having 1 to 9 carbon atoms, an alkoxy group having 1 to 9 carbon atoms, an alkanoyl group having 1 to 9 carbon atoms, a carboalkoxy group having 2 to 9 carbon atoms, an aryl group having 6 to 9 carbon atoms or a halogen atom; ##STR7## wherein R 6 , R 7 , R 8 and R 9 each independently stand for hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkanoyl group having 1 to 6 carbon atoms, a carboalkoxy group having 2 to 6 carbon atoms, an aryl group having 6 carbon atoms or a halogen atom; and ##STR8## wherein R 10 , R 11 , R 12 and R 13 each independently stand for hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl group having 1 to 6 carbon atoms, an alkoxy group having 1 to 6 carbon atoms, an alkanoyl group having 1 to 6 carbon atoms, a carboalkoxy group having 2 to 6 carbon atoms, an aryl group having 6 carbon atoms or a halogen atom.
Claim 7
Dependent Claim
41 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said thermally dissociable bond is a bond derived from a reaction of a phenolic hydroxyl group and/or a thiol group with an aromatic isocyanate group and/or an isothiocyanate group.
Claim 8
Dependent Claim
23 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said amino group of component (A) is a tertiary amino group.
Claim 9
Dependent Claim
35 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said component (A) is selected from the group consisting of dimethylaminoethyl methacrylate, diethylaminoethylmethacrylate, dimethylaminopropyl methacrylamide, 2-vinylpyridine, 4-vinylpyridine, 1-vinylimidazole, 1-vinyl-2-pyrrolidinone, N-vinyl-2-pyrrolidone, and 9-vinyl carbazole.
Claim 10
Dependent Claim
146 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said component (B) is selected from the group consisting of o-methylstyrene, m-methylstyrene, p-methylstyrene, α-methylstyrene, p-ethylstyrene, 2,4-dimethylstyrene, p-chlorostyrene, vinylnaphthalene, ethylene, propylene, butylene, isobutylene, vinyl chloride, vinyl bromide, vinyl fluoride, vinyl acetate, vinyl propionate, vinyl formate, vinyl caproate, acrylic acid, methyl acrylate, ethyl acrylate, n-propyl acrylate, isopropyl acrylate, n-butyl acrylate, isobutyl acrylate, tert-butyl acrylate, amyl acrylate, cyclohexyl acrylate, n-octyl acrylate, isooctyl acrylate, decyl acrylate, lauryl acrylate, 2-ethylhexyl acrylate, stearyl acrylate, methoxyethyl acrylate, 2-hydroxyethyl acrylate, glycidyl acrylate, 2-chloroethyl acrylate, phenyl acrylate, methyl α-chloroacrylate, methacrylic acid, methyl methacrylate, ethyl methacrylate, n-propyl methacrylate, isopropyl methacrylate, n-butyl methacrylate, isobutyl methacrylate, tert-butyl methacrylate, amyl methacrylate, cyclohexyl methacrylate, n-octyl methacrylate, isooctyl methacrylate, decyl methacrylate, lauryl methacrylate, 2-ethylhexyl methacrylate, stearyl methacrylate, methoxyethyl methacrylate, 2-hydroxyethyl methacrylate, glycidyl methacrylate, phenyl methacrylate, acrylonitrile, methacrylonitrile, acrylamide, dimethyl maleate, vinyl methyl ketone, vinyl ethyl ether, and vinylidene chloride.
Claim 11
Dependent Claim
82 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said monoisocyanate compound (1) is selected from the group consisting of ethyl isocyanate, octyl isocyanate, 2-chloroethyl isocyanate, chlorosulfonyl isocyanate, n-dodecyl isocyanate, butyl isocyanate, n-hexyl isocyanate, lauryl isocyanate, phenyl isocyanate, m-chlorophenyl isocyanate, 4-chlorophenyl isocyanate, p-cyanophenyl isocyanate, 3,4-dichlorophenyl isocyanate, o-tolyl isocyanate, m-tolyl isocyanate, p-tolyl isocyanate, p-toluenesulfonyl isocyanate, 1-naphthyl isocyanate, o-nitrophenyl isocyanate, m-nitrophenyl isocyanate, p-nitrophenyl isocyanate, phenyl isocyanate, p-bromophenyl isocyanate, o-methoxyphenyl isocyanate, m-methoxyphenyl isocyanate, p-methoxyphenyl isocyanate, ethyl isocyanatoacetate, butyl isocyanatoacetate and trichloroacetyl isocyanate.
Claim 12
Dependent Claim
79 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said di- or higher isocyanate compound (2) is selected from the group consisting of 2,4-tolylene diisocyanate, a dimer of 2,4-tolylene diisocyanate, 2,6-tolylene diisocyanate, p-xylylene diisocyanate, m-xylylene diisocyanate, 4,4'-diphenylmethane diisocyanate, 1,5-naphthylene diisocyanate, 3,3'-dimethyldiphenyl-4,4'-diisocyanate, 3,3'-dimethyldiphenylmethane-4,4'-diisocyanate, m-phenylene diisocyanate, triphenylmethane-triisocyanate, polymethylenephenyl isocyanate, hexamethylene diisocyanate, trimethylhexamethylene diisocyanate, lysine diisocyanate, dimer acid diisocyanate, isophorone diisocyanate, 4,4'-methylenebis(cyclohexylisocyanate), methylcyclohexane-2,4-(or 2,6-)diisocyanate, 1,3-(isocyanatemethyl)cyclohexane, and an adduct of 3 moles of tolylene diisocyanate with one mole of trimetylolpropane.
Claim 13
Dependent Claim
115 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said compound having one active hydrogen reactive with an isocyanate group, isothiocyanate group, or mixture thereof (3) is selected from the group consisting of methyl alcohol, ethyl alcohol, n-propyl alcohol, isopropyl alcohol, n-butyl alcohol, isobutyl alcohol, tert-butyl alcohol, pentyl alcohol, hexyl alcohol, cyclohexyl alcohol, heptyl alcohol, octyl alcohol, nonyl alcohol, decyl alcohol, lauryl alcohol, stearyl alcohol, phenol, o-cresol, m-cresol, p-cresol, 4-n-butyl phenol, 2-sec-butyl phenol, 2-tert-butyl phenol, isononyl phenol, 2-propenyl phenol, 3-propenyl phenol, 3-tert-butyl phenol, 4-tert-butyl phenol, nonyl phenol, 4-propenyl phenol, 2-methoxy phenol, 3-methoxy phenol, 4-methoxy phenol, 3-acetyl phenol, 3-carbomethoxy phenol, 2-chlorophenol, 3-chlorophenol, 4-chlorophenol, 2-bromophenol, 3-bromophenol, 4-bromophenol, benzyl alcohol, 1-naphthol, 2-naphthol, 2-acetyl-1-naphthol and ε-caprolactam.
Claim 14
Dependent Claim
107 words
The capsulated toner for heat pressure fixation according to claim 1, wherein said compound having two or more active hydrogens reactive with an isocyanate group, an isothiocyanate group, or mixture thereof (4) is selected from the group consisting of catechol, resorcin, hydroquinone, 4-methylcatechol, 4-tert-butylcatechol, 4-acetylcatechol, 3-methoxycatechol, 4-phenylcatechol, 4-methylresorcin, 4-ethylresorcin, 4-tert-butyl-resorcin, 4-hexyl-resorcin, 4-chlororesorcin, 4-benzylresorcin, 4-acetylresorcin, 4-carbomethoxyresorcin, 2-methylresorcin, 5-methylresorcin, tert-butylhydroquinone, 2,5-di-tert-butylhydroquinone, 2,5-di-tertamyl-hydroquinone, tetramethylhydroquinone, tetrachlorohydroquinone, methylcarboaminohydroquinone, methylureidohydroquinone, benzonorbornene-3,6-diol, bisphenol A, bisphenol S, 3,3'-dichlorobisphenol S, 2,2'-dihydroxybenzophenone, 2,4-dihydroxybenzophenone, 4,4'-dihydroxybenzophenone, 2,2'-dihydroxydiphenyl, 4,4'-dihydroxydiphenyl, 2,2'-dihydroxydiphenylmethane, 3,4-bis(p-hydroxyphenyl)hexane, 1,4-bis(p-hydroxyphenyl)propyl)benzene, bis(4-hydroxyphenyl)methylamine, 1,3-dihydroxynaphthalene, 1,4-dihydroxynaphthalene, 1,5-dihydroxynaphthalene, 2,6-dihydroxynaphthalene, 1,5-dihydroxyanthraquinone, 2-hydroxybenzyl alcohol, 4-hydroxybenzyl alcohol, 2-hydroxy-3,5-di-tert-butylbenzyl alcohol, 4-hydroxy-3,5-di-tert-butylbenzyl alcohol, 4-hydroxyphenethyl alcohol, 2-hydroxyethyl-4-hydroxybenzoate, 2-hydroxyethyl-4-hydroxyphenyl acetate, resorcin mono-2-hydroxyethyl ether, hydroxyhydroquinone, gallic acid and ethyl 3,4,5-trihydroxybenzoate.
Claim 15
Dependent Claim
101 words
The capsulated toner for heat pressure fixation according to claim 1, comprising a heat-meltable core material and an outer shell, wherein said core material contains a colorant and a thermoplastic resin, produced by copolymerising 0.05 to 20% by weight of (A) an α,β-ethylenically copolymerizable monomer having an amino group, 99.95 to 80% by weight of (B) an α,β-ethylenically copolymerizable monomer other than (A), and 0.001 to 15% by weight of a crosslinking agent, wherein the above percentages are based upon the total weight of components (A) and (B), said outer shell being provided to cover the surface of the core material.
Claim 16
Dependent Claim
27 words
A toner composition for heat pressure fixation comprising the capsulated toner as set forth in claims 1 or 9 and a fine powder of a hydrophobic silica.
Claim 17
Dependent Claim
60 words
The capsulated toner for heat pressure fixation according to claim 14, wherein said crosslinking agent is selected from the group consisting of divinylbenzene, divinylnaphthalene, polyethylene glycol dimethacrylate, diethylene glycol diacrylate, triethylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,6-hexylene glycol dimethacrylate, neopentyl glycol dimethacrylate, dipropylene glycol dimethacrylate, polypropylene glycol demethacrylate, 2,2'-bis(4-methacryloxydiethoxyphenyl)propane, 2,2'-bis(4-acryloxydiethoxyphenyl)propane, trimethylolpropane trimethacrylate, trimethylolpropanetriacrylate, tetramethylolmethanetetraacrylate, bromoneopentyl glycol dimethacrylate and diallyl phthalate.
Claim 18
Dependent Claim
35 words
The capsulated toner for heat pressure fixation according to claim 14, wherein said crosslinking agent is present in an amount of 0.1 to 10% by weight, based upon the total weight of (A) and (B).
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
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| 3.5 Years (Year 4) | 1996-07-19 | 1997-01-18 | 1997-07-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-07-19 | 2001-01-18 | 2001-07-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-07-19 | 2005-01-18 | 2005-07-20 | $7700.00 | Window Closed / Lapsed |