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EP0453857A1 Expired / Lapsed EP ⏱️ 0.0 years remaining

Encapsulated toner for heat-and-pressure fixing

Assignee: Kao Corp
•
Filing: 1991-04-09
•
Granted: —
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Expires: 2011-04-09
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Abstract

Abstract An encapsulated toner for heat-and-pressure fixing which is composed of a heat-fusible core containing at least a coloring material and a shell formed so as to cover the surface of the core, wherein the main component of the shell is a resin prepared by reacting an iso(thio)cyanate compound comprising (1) 0 to 30 mole % of monovalent isocyanate and/or isothiocyanate compounds and (2) 100 to 70 mole % of at least divalent isocyanate and/or isothiocyanate compounds with an active hydrogen compound comprising (3) 0 to 30 mole % of a compound having one active hydrogen atom reactive with isocyanate and/or isothiocyanate groups and (4) 100 to 70 mole % of a compound having at least two active hydrogen atoms reactive with isocyanate and/or isothiocyanate groups at a molar ratio of the components (1) and (2) to the components (3) and (4) of between 1 : 1 and 1 : 20, and wherein at least 30% of the whole linkages in which an isocyanate or isothiocyanate group participates are thermally dissociating linkages. This toner is excellent in blocking resistance and triboelectric properties and enables low-energy fixing.

Inventors

  • 👤 Mitsuhiro Sasaki
  • 👤 Kuniyasu Kawabe

Bibliographic Details

Application Number —
Jurisdiction EP
Data Source google_patents
Last Synchronized 2026-11-03 01:06
CPC Classifications
G; G03; G03G; G03G9/00; G03G9/08; G03G9/093; G03G9/09307; G03G9/09314; G03G9/09328

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 171 words
An encapsulated toner for heat-and-pressure fixing which is composed of a heat-fusible core containing at least a coloring material and a shell formed so as to cover the surface of the core, wherein the main component of the shell is a resin prepared by reacting an iso(thio)cyanate compound comprising (1) 0 to 30 mole % of monovalent isocyanate and/or isothiocyanate compounds and (2) 100 to 70 mole % of at least divalent isocyanate and/or isothiocyanate compounds with an active hydrogen compound comprising (3) 0 to 30 mole % of a compound having one active hydrogen atom reactive with isocyanate and/or isothiocyanate groups and (4) 100 to 70 mole % of a compound having at least two active hydrogen atoms reactive with isocyanate and/or isothiocyanate groups at a molar ratio of the components (1) and (2) to the components (3) and (4) of between 1 : 1 and 1 : 20, and wherein at least 30% of the whole linkages in which an isocyanate or isothiocyanate group participates are thermally dissociating linkages.
Claim 2
Dependent Claim 34 words
The encapsulated toner for heat-and-pressure fixing according to claim 1, wherein said thermally dissociating linkage is one formed by the reaction of a phenolic hydroxyl or thio group with an isocyanate or isothiocyanate group.
Claim 3
Dependent Claim 35 words
The encapsulated toner for heat-and-pressure fixing according to claim 1, wherein the main component of the heat-fusible core is a thermoplastic resin and the glass transition point assignable to the resin is 10 to 50°C.
Claim 4
Dependent Claim 18 words
The encapsulated toner for heat-and-pressure fixing according to claim 1, wherein the softening point is 80 to 150°C.
Claim 5
Dependent Claim 136 words
The encapsulated toner for heat-and-pressure fixing according to claim 2, wherein the compound having a phenolic hydroxyl group is at least one compound selected from among those represented by the following formulas (I), (II) and (III): wherein R₁, R₂, R₃, R₄ and R₅ each independently represent a hydrogen atom, an alkyl group having 1 to 9 carbon atoms, an alkenyl, alkoxy, alkanoyl, carboalkoxy or aryl group or a halogen atom; wherein R₆, R₇, R₈ and R₉ each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl, alkoxy, alkanoyl, carboalkoxy or aryl group or a halogen atom; wherein R₁₀, R₁₁, R₁₂ and R₁₃ each independently represent a hydrogen atom, an alkyl group having 1 to 6 carbon atoms, an alkenyl, alkoxy, alkanoyl, carboalkoxy or aryl group or a halogen atom.
Claim 6
Dependent Claim 24 words
The encapsulated toner for heat-and-pressure fixing according to claim 3, wherein the thermoplastic resin contained in the heat-fusible core is mainly a vinyl resin.
Claim 7
Dependent Claim 29 words
The encapsulated toner for heat-and-pressure fixing according to claim 2, wherein the isocyanate group to be reacted with a phenolic hydroxyl group is directly bonded to an aromatic ring.

References Cited (Backward Citations)

GB2107892A Cited
GB2135469A Cited
US4636451A Cited

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