Film composite having repositionable adhesive by which it can become permanently bonded to a plasticized substrate

Claim 2

An adhesive-backed film composite comprising a thin flexible backing bearing a layer of adhesive by which the film composite can become permanently bonded to a substrate containing monomeric plasticizer, said adhesive comprising, by weight, a blend of 1) from about 10 to 99% of an acrylic latex adhesive, wherein said acrylic latex adhesive has a glass transition temperature of 0° C. to -50° C. and is an acrylic emulsion polymer of a) from 84 to 100 parts of acrylic acid ester of nontertiary alcohol, the alkyl groups of which contain an average of from 2 to 12 carbon atoms, and b) correspondingly from 16 to 0 parts of an ethylenically unsaturated copolymerizable monomer, wherein said monomer is selected from the group consisting of acrylic acid, methacrylic acid, acrylamide, methacrylamide, itaconic acid, acrylonitrile, methacrylonitrile, methlmethacrylate, vinyl acetate, N-vinyl pyrrolidone and styrene sulfonate; 2) from 1 to 90% of a heat-activatable urethane latex adhesive, a film of which has an elongation of at least 100%, wherein said blend has been coated onto the backing rom an aqueous emulsion.

Claim 3

The adhesive-backed film composite as defined in claim 1 wherein said acrylic acid ester is a mixture of, by weight, from 50 to 90% of ethyl acrylate and correspondingly from 50 to 10% of n-butyl acrylate, and said ethylenically unsaturated, copolymerizable monomer is 1 to 16% of highly polar monomer, wherein said polar monomer is selected from the group consisting of acrylic acid, methacrylic acid, acrylamide, methacrylamide, itaconic acid, acrylonitrile, and methacrylonitrile.

Claim 4

The adhesive-backed film composite as defined in claim 2 wherein the amount of said highly polar monomer is from 2 to 12% by weight.

Claim 5

A laminate of a vinyl substrate containing migratable plasticizer and an adhesive-backed film composite comprising a thin flexible backing selected from vinyl, polyurethane, and polyolefin films, which backing bears a layer of adhesive comprising, by weight, a blend of 1) from about 10 to 99% of an acrylic latex adhesive, wherein said acrylic latex adhesive is an acrylic emulsion polymer of a) from 84 to 100 parts of acrylic acid ester of nontertiary alcohol, the alkyl groups of which contain an average of from 2 to 12 carbon atoms, and b) correspondingly from 16 to 0 parts of an ethylenically unsaturated, copolymerizable monomer, wherein said monomer is selected from the group consisting of acrylic acid, methacrylic acid, acrylamide, methacrylamide, itaconic acid, acrylonitrile, methacrylonitrile, methylmethacrylate, vinyl acetate, N-vinyl pyrrolidone and styrene sulfonate; 2) from 1 to 90% of a heat-activatable urethane latex adhesive, wherein said urethane latex adhesive is polyester polyurethane and a film of which has an elongation of at least 100%, wherein said blend has been coated onto the backing from an aqueous emulsion.

Claim 6

A laminate of a vinyl substrate containing migratable plasticizer and an adhesive-backed film composite comprising a thin flexible backing selected from vinyl, polyurethane, and polyolefin films, which backing bears a layer of adhesive comprising, by weight, a blend of 1) from about 10 to 99% of an acrylic latex adhesive, wherein said acrylic latex adhesive is an acrylic emulsion polymer of a) from 84 to 100 parts of acrylic acid ester of nontertiary alcohol, the alkyl groups of which contain an average of from 2 to 12 carbon atoms, and b) correspondingly from 16 to 0 parts of an ethylenically unsaturated, copolymerizable monomer, wherein said monomer is selected from the group consisting of acrylic acid, methacrylic acid, acrylamide, methacrylamide, itaconic acid, acrylonitrile, methacrylonitrile, methylmethacrylate, vinyl acetate, N-vinyl pyrrolidone and styrene sulfonate; 2) from 1 to 90% of a heat-activatable urethane latex adhesive, wherein said urethane latex adhesive is polyester polyurethane and a film of which has an elongation of at least 100%, wherein said blend has been coated onto the backing from an aqueous emulsion.

Claim 7

The laminate as defined in claim 4 wherein said vinyl substrate is selected from the group consisting of vinyl films, vinyl-coated paper, fabric, and scrim.