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Coating composition of a glycidyl acrylic polymer, an aminoester acrylic polymer and a polyester or a polyesterurethane

Assignee: EIDP Inc
•
Filing: 1990-12-18
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Granted: 1993-06-22
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Expires: 2010-12-18
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Abstract

Abstract A coating composition which cures at ambient temperatures and contains a binder and a solvent for the binder, wherein the binder contains about: A. an acrylic polymer A having pending from the polymer backbone aminoester groups, hydroxy aminoester groups or hydroxyamine groups, B. an acrylic crosslinking polymer B of polymerized monomers of at least 3% by weight of a glycidyl constituent of glycidyl methacrylate or acrylate, and the remainder of the monomers are alkyl methacrylate an acrylate each having 1-12 carbon atoms in the alkyl group; C. a polyester or polyesterurethane polymer C having at least 2 pendant groups of the formula <IMAGE> the composition is useful as an exterior finish for automobiles and trucks and for repairing finishes of automobiles and trucks.

Inventors

  • 👤 George T. Palmer
  • 👤 Ruth A. Theobald

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-27 15:00
CPC Classifications
C; C09; C09D; C09D133/00; C09D133/04; C09D133/06; C09D133/10; C08; C08L; C08L33/00; C08L33/04; C08L33/06; C08L67/00; C08L75/00; C08L75/04; C08L75/06; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31605; Y10T428/31678; Y10T428/31681; Y10T428/31786

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 279 words
A coating composition comprising 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder consists essentially of about: A. 50-70% by weight, based on the weight of the binder, of an acrylic polymer A consisting essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone reactive groups selected from the group consisting of aminoester groups of the formula ##STR12## where R is an alkylene group having 2-3 carbon atoms, hydroxyamino ester groups of the formula ##STR13## where R 1 is an alkyl group of 1-8 carbon atoms; B. 20-30% by weight, based on the weight of the binder, of an acrylic crosslinking polymer B comprising polymerized monomers of at least 3% by weight, based on the weight of the crosslinking polymer, of a glycidyl constituent selected from the group consisting of glycidyl methacrylate and glycidyl acrylate, and the remainder of the monomers being selected from the group consisting of alkyl methacrylate and alkyl acrylate or mixtures thereof each having 1-12 carbon atoms in the alkyl groups; and C. 5-48% by weight, based on the weight of the binder, of polymer C of a polyester or polyesterurethane polymer having at least 2 pendant groups of the formula ##STR14## wherein said polymers A and B each have a weight average molecular weight of about 5,000-40,000 and polymer C has a weight average molecular weight of about 300-10,000 each determined by gel permeation chromatography using polymethyl methacrylate as a standard.
Claim 2
Dependent Claim 279 words
A coating composition comprising 20-80% by weight of a binder and 80-20% by weight of a solvent for the binder, wherein the binder consists essentially of about: A. 50-70% by weight, based on the weight of the binder, of an acrylic polymer A consisting essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone reactive groups selected from the group consisting of aminoester groups of the formula ##STR12## where R is an alkylene group having 2-3 carbon atoms, hydroxyamino ester groups of the formula ##STR13## where R 1 is an alkyl group of 1-8 carbon atoms; B. 20-30% by weight, based on the weight of the binder, of an acrylic crosslinking polymer B comprising polymerized monomers of at least 3% by weight, based on the weight of the crosslinking polymer, of a glycidyl constituent selected from the group consisting of glycidyl methacrylate and glycidyl acrylate, and the remainder of the monomers being selected from the group consisting of alkyl methacrylate and alkyl acrylate or mixtures thereof each having 1-12 carbon atoms in the alkyl groups; and C. 5-48% by weight, based on the weight of the binder, of polymer C of a polyester or polyesterurethane polymer having at least 2 pendant groups of the formula ##STR14## wherein said polymers A and B each have a weight average molecular weight of about 5,000-40,000 and polymer C has a weight average molecular weight of about 300-10,000 each determined by gel permeation chromatography using polymethyl methacrylate as a standard.
Claim 3
Dependent Claim 17 words
The coating composition of claim 1 containing pigments in a pigment-to-binder weight ratio of 1:100 to 200:100.
Claim 4
Dependent Claim 73 words
The coating composition of claim 1 in which the acrylic polymer A consists essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate, each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone reactive aminoester groups of the formula ##STR15## where R is an alkylene group having 2-3 carbon atoms.
Claim 5
Dependent Claim 91 words
The coating composition of claim 3 in which the acrylic polymer A consists essentially of about 20-35% by weight, based on the acrylic polymer, of methyl methacrylate 30-40% by weight, based on the weight of the acrylic polymer, of styrene, 25-35% by weight, based on the weight of the acrylic polymer, of an alkyl methacrylate having 4-12 carbon atoms in the alkyl group and 10-15% by weight, based on the weight of the acrylic polymer, of methacrylic acid; said polymer reacted with an alkylene imine to provide said amino ester groups.
Claim 6
Dependent Claim 63 words
The coating composition of claim 1 in which the acrylic polymer A consists essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate, each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the carbon-carbon atoms of the polymer backbone hydroxyamino ester groups of the formula ##STR16##
Claim 7
Dependent Claim 67 words
The coating composition of claim 1 in which the acrylic polymer A consists essentially of polymerized monomers of methyl methacrylate and monomers selected from the group consisting of styrene, alkyl methacrylate and alkyl acrylate, each having 2-12 carbon atoms in the alkyl group and said polymer having pending from the backbone groups of the formula ##STR17## where R 1 is an alkyl group of 1-8 carbon atoms.
Claim 8
Dependent Claim 98 words
The coating composition of claim 3 in which the acrylic crosslinking polymer B consists essentially of about 3-80% by weight, based on the weight of the acrylic crosslinking polymer, of glycidyl methacrylate, or glycidyl acrylate 15-40% by weight, based on the weight of the acrylic crosslinking polymer, of an alkyl methacrylate having 1-12 carbon atoms in the alkyl group and 30-57% by weight, based on the weight of the acrylic crosslinking polymer of an alkyl methacrylate or alkyl acrylate each having 1-4 carbon atoms in the alkyl group and each having a pendant group of the formula ##STR18##
Claim 9
Dependent Claim 80 words
The coating composition of claims 4, 5 or 6 in which the acrylic crosslinking polymer B consists essentially of about 3-80% by weight based on the weight of the acrylic crosslinking polymer, of glycidyl metharylate, 15-40% by weight, based on the weight of the acrylic crosslinking polymer, of an alkyl methacrylate having 4-12 carbon atoms in the alkyl group and 3-57% by weight, based on the weight of the acrylic crosslinking polymer of acetoacetoxy ethyl methacrylate or acetoacetoxy ethyl acrylate.
Claim 10
Dependent Claim 43 words
The coating composition of claim 1 in which polymer C comprises a polyester having reactive hydroxyl groups of an aliphatic diol and an aliphatic dicarboxylic acid wherein the hydroxyl groups have been reacted with an alkylate of acetoacetic acid or an alkyl acetoacetate.
Claim 11
Dependent Claim 18 words
The coating composition of claim 9 in which polymer C comprises neopentyl adipate polyol reacted with butyl acetoacetate.
Claim 12
Dependent Claim 36 words
The coating composition of claim 1 in which polymer C comprises a polyesterurethane of a polyester of an aliphatic diol and an aliphatic dicarboxylic acid reacted with an organic diisocyanate and an alkylate of acetoacetic acid.
Claim 13
Dependent Claim 40 words
The coating composition of claim 1 in which polymer C is a polyesterurethane which comprises the reaction product of neopentyl glycol adipate, an aliphatic polyurethane polyol, trimethylol propane, cycloaliphatic diisocyanate that is subsequently reacted with an alkylate of acetoacetic acid.
Claim 14
Dependent Claim 73 words
The coating composition of claim 1 containing about 2-30% by weight, based on the eight of the binder of an organosilane of the formula ##STR19## wherein R 1 is an organic group having an epoxy group, R 2 is hydrogen, a hydrocarbon group having 1-6 carbon atoms b is an integer of 0-2, R 3 is a hydrocarbon group having 1-5 carbon atoms or an alkoxyalkyl group, a is an integer of 1-3.
Claim 15
Dependent Claim 22 words
The coating composition of claim 13 wherein the organosilane is selected from the group consisting of glycidoxypropyl trimethoxysilane and beta-(3,4-epoxy cyclohexyl)ethyl trimethoxysilane.
Claim 16
Dependent Claim 41 words
The coating composition of claim 1 containing about 0.1-4% by weight, based on the weight of the binder, of a catalyst selected from the group consisting of resorcinol, resorcinol monobenzoate, boron trifluoride amine complex, phenol, para methoxy phenol, and parahydroxymethyl benzoate.
Claim 17
Dependent Claim 21 words
The coating composition of claim 1 containing 0.1-5% by weight, based on the weight of the binder, of ultraviolet light stabilizer.
Claim 18
Dependent Claim 216 words
The coating composition of claim 2 in which the binder consists essentially of A. acrylic polymer A consist essentially of about 20-35% by weight, based on the weight of the acrylic polymer, of methyl methacrylate, 30-40% by weight, based on the weight of the acrylic polymer, of styrene, 25-35% by weight, based on the weight of the acrylic polymer, of alkyl methacrylate methacrylate having 4-12 carbon atoms in the alkyl group and 10-15% by weight, based on the weight of the acrylic polymer, of methacrylic acid; said polymer reacted with an alkylene imine to provide amino ester groups pendant from the carbon-carbon polymer backbone of the formula ##STR20## where R is an alkylene group having 2-3 carbon atoms; B. acrylic crosslinking polymer B consists essentially of about 3-80% by weight, based on the weight of the acrylic crosslinking polymer, of glycidyl methacrylate, 15-40% by weight, based on the weight of the acrylic crosslinking polymer, of alkyl methacrylate having 4-12 carbons in the alkyl group and 5-57% by weight, based on the weight of the acrylic crosslinking polymer, of acetoacetoxy ethyl methacrylate and C. crosslinking polymer C consists essentially of a polyester urethane of a polyester of neopentyl glycol adipate, aliphatic urethane diol, trimethylol propane and a cyclohexyl diisocyanato that is subsequently reacted with an alkyl acetoacetate.
Claim 19
Dependent Claim 13 words
A substrate coated with a dried layer of the composition of claim 1.
Claim 20
Dependent Claim 13 words
The coated substrate of claim 18 in which the substrate is a metal.
Claim 21
Dependent Claim 13 words
The coated substrate of claim 18 in which the substrate is a plastic.
Claim 22
Dependent Claim 29 words
A substrate coated with a dried layer of a pigmented composition and having a second dried clear layer of the coating composition of claim 1 in superimposed adherence thereto.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-06-21 1996-12-21 1997-06-22 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-06-21 2000-12-21 2001-06-22 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-06-21 2004-12-21 2005-06-22 $7700.00 Window Closed / Lapsed

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