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Etching of nanoscale structures

Assignee: EIDP Inc
•
Filing: 1991-08-30
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Granted: 1993-05-11
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Expires: 2011-08-30
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Abstract

Abstract A process for etching with an atomic force microscope using a two-dimensional metal chalcogenide as the substrate, is disclosed.

Inventors

  • 👤 Edward J. Delawski
  • 👤 Bruce A. Parkinson

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 17:23
CPC Classifications
G; G03; G03F; G03F7/00; G03F7/004; G03F7/0042; G03F7/0043; G11; G11B; G11B9/00; G11B9/12; G11B9/14; G11B9/1463; B; B82; B82B; B82B3/00; G01; G01Q; G01Q80/00; H; H01; H01J; H01J2237/00; H01J2237/30; H01J2237/317; H01J2237/3174; H01J2237/31747; Y; Y10; Y10S; Y10S977/00; Y10S977/84; Y10S977/849; Y10S977/855; Y10S977/856

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 56 words
A process for etching a nanoscale structure using an atomic force microscope comprising scanning the microscope tip over a two dimensional substrate of at least one metal chalcogenide at a force of from about 10 -12 to about 10 -6 newtons to generate the controlled ablation of one or more molecular layers of the metal chalcogenide.
Claim 2
Dependent Claim 56 words
A process for etching a nanoscale structure using an atomic force microscope comprising scanning the microscope tip over a two dimensional substrate of at least one metal chalcogenide at a force of from about 10 -12 to about 10 -6 newtons to generate the controlled ablation of one or more molecular layers of the metal chalcogenide.
Claim 3
Dependent Claim 12 words
The process of claim 1 wherein a single molecular layer is ablated.
Claim 4
Dependent Claim 14 words
The process of claim 1 wherein more than one molecular layer is ablated simultaneously.
Claim 5
Dependent Claim 39 words
The process of claim 1 wherein the metal chalcogenide comprises InSe, ZrS 2 , TiSe 2 , SnSe 2 , SnS 2 , NbSe 2 , TaS 2 , MoSe 2 , or WSe 2 or solid solutions thereof.
Claim 6
Dependent Claim 23 words
The process of claim 4 wherein the metal chalcogenide comprises SnSe 2 , NbSe 2 , SnS 2 , or TaS 2 .
Claim 7
Dependent Claim 32 words
The process of claim 1 wherein the substrate comprises a layered material prepared by molecular beam epitaxy wherein at least one portion of the top layer is a two dimensional metal chalcogenide.
Claim 8
Dependent Claim 36 words
The process of claim 6 wherein the metal chalcogenide comprises InSe, ZrS 2 , TiSe 2 , SnSe 2 , SnS 2 , NbSe 2 , TaS 2 , MoSe 2 , or WSe 2 .
Claim 9
Dependent Claim 16 words
The process of claim 1 wherein the structure etched can be viewed simultaneously with its creation.
Claim 10
Dependent Claim 29 words
The process of claim 1 wherein the depth of the etched structure is controlled to a precision of (0.0003 ×n) nanometer, wherein n is the number of layers etched.
Claim 11
Dependent Claim 14 words
The process of claim 1 wherein the substrate remains free of deformation or residue.
Claim 12
Dependent Claim 17 words
The process of claim 1 wherein the structure etched has a bottom surface that is atomically flat.
Claim 13
Dependent Claim 10 words
The etched structure resulting from the process of claim 1.
Claim 14
Independent Claim 37 words
A method for determining small deviations from stoichiometry comprising scanning with an AFM a substrate area of known size, counting the resulting nucleation sites, and subtracting the number of nucleation sites from the number of atoms scanned.
Claim 15
Independent Claim 37 words
A method for determining small deviations from stoichiometry comprising scanning with an AFM a substrate area of known size, counting the resulting nucleation sites, and subtracting the number of nucleation sites from the number of atoms scanned.

References Cited (Backward Citations)

US4724318A Cited
US4987312A Cited
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US5138174A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-05-10 1996-11-09 1997-05-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-05-10 2000-11-09 2001-05-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-05-10 2004-11-09 2005-05-11 $7700.00 Window Closed / Lapsed

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