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Adhesives for laminating vinyl to various substrates

Assignee: EIDP Inc
•
Filing: 1992-06-26
•
Granted: 1993-05-11
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Expires: 2012-06-26
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Abstract

Abstract Adhesives suitable for preparing laminates of polyvinyl chloride or polyvinyl chloride copolymers with wood or metal are prepared from a three component polymer mixture of polyvinyl chloride or its copolymers itself, a direct ethylene copolymer preferably containing units derived from carbon monoxide, and another direct ethylene copolymer containing units derived from a monomer containing glycidyl units. The adhesive is especially useful for preparing PVC/wood laminates which are subject to outdoor weathering.

Inventors

  • 👤 Ronald B. Case
  • 👤 Robert J. Statz

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 00:58
CPC Classifications
B; B32; B32B; B32B7/00; B32B7/04; B32B7/12; B32B21/00; B32B21/04; B32B21/08; B32B27/00; B32B27/30; B32B27/304; C; C09; C09J; C09J127/00; C09J127/02; C09J127/04; C09J127/06; C09J173/00; C09J181/00; C09J181/06; B32B2307/00; B32B2307/70; B32B2307/712; B32B2327/00; B32B2327/06; C08; C08L; C08L23/00; C08L23/02; C08L23/04; C08L23/08; C08L2666/00; C08L2666/02; C08L2666/04; C08L27/00; C08L27/02; C08L27/04; C08L27/06; C08L33/00; C08L33/04; C08L33/06; C08L33/062; C08L33/068; C08L73/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31855; Y10T428/3188; Y10T428/31895; Y10T428/31906; Y10T428/31909; Y10T428/31928; Y10T428/31935

Claims Analysis

Total Claims: 10
Claim 1
Independent Claim 179 words
An adhesive for polyvinyl chloride and polyvinyl chloride copolymers, comprising: a) 5-65 weight percent of polyvinyl chloride or a polyvinyl chloride copolymer; b) 15-75 weight percent of a first ethylene copolymer, said first copolymer being a direct copolymer containing 30-95 weight percent ethylene, and (i) 0-50 weight percent of a moiety derived from a comonomer consisting of at least one alkyl acrylate, alkyl methacrylate, alkyl vinyl ether, vinyl acetate or mixtures thereof, where the alkyl radical contains 1-8 carbon atoms, and also containing (ii) 1-20 weight percent of a moiety derived from a comonomer consisting of carbon monoxide or sulfur dioxide, provided that (i) is present to an extent equal or greater than [50-(10×(ii)] weight percent, and c) 2-25 weight percent of a second direct ethylene copolymer containing from 0-50 weight percent of a moiety derived from at least one alkyl acrylate, alkyl methacrylate, alkyl vinyl ether, vinyl acetate or mixtures thereof, where the alkyl radical contains 1-8 carbon atoms, and also contains 1-15 weight percent of a moiety derived from glycidyl acrylate, glycidyl methacrylate or glycidyl vinyl ether.
Claim 2
Dependent Claim 179 words
An adhesive for polyvinyl chloride and polyvinyl chloride copolymers, comprising: a) 5-65 weight percent of polyvinyl chloride or a polyvinyl chloride copolymer; b) 15-75 weight percent of a first ethylene copolymer, said first copolymer being a direct copolymer containing 30-95 weight percent ethylene, and (i) 0-50 weight percent of a moiety derived from a comonomer consisting of at least one alkyl acrylate, alkyl methacrylate, alkyl vinyl ether, vinyl acetate or mixtures thereof, where the alkyl radical contains 1-8 carbon atoms, and also containing (ii) 1-20 weight percent of a moiety derived from a comonomer consisting of carbon monoxide or sulfur dioxide, provided that (i) is present to an extent equal or greater than [50-(10×(ii)] weight percent, and c) 2-25 weight percent of a second direct ethylene copolymer containing from 0-50 weight percent of a moiety derived from at least one alkyl acrylate, alkyl methacrylate, alkyl vinyl ether, vinyl acetate or mixtures thereof, where the alkyl radical contains 1-8 carbon atoms, and also contains 1-15 weight percent of a moiety derived from glycidyl acrylate, glycidyl methacrylate or glycidyl vinyl ether.
Claim 3
Dependent Claim 13 words
The adhesive of claim 1 wherein the first copolymer is ethylene/n-butyl acrylate/carbon monoxide.
Claim 4
Dependent Claim 17 words
The adhesive of claim 2 containing 20-40 weight percent n-butyl acrylate and 3-15 weight percent carbon monoxide.
Claim 5
Dependent Claim 13 words
The adhesive of claim 1 wherein the second copolymer is ethylene/n-butyl acrylate/glycidyl methacrylate.
Claim 6
Dependent Claim 17 words
The adhesive of claim 4 containing 10-40 weight percent n-butyl acrylate and 3-11 weight percent glycidyl methacrylate.
Claim 7
Dependent Claim 25 words
The adhesive of claim 3 wherein the second copolymer is ethylene/n-butyl acrylate/glycidyl methacrylate containing 10-40 weight percent n-butyl acrylate and 3-11 weight percent glycidyl methacrylate.
Claim 8
Dependent Claim 27 words
A laminate comprising a polyvinyl chloride or a polyvinyl chloride copolymer layer, a second layer, wherein the two layers are adhered with the adhesive of claim 1.
Claim 9
Dependent Claim 27 words
A laminate comprising a polyvinyl chloride or a polyvinyl chloride copolymer layer, a second layer, wherein the two layers are adhered with the adhesive of claim 6.
Claim 10
Dependent Claim 11 words
The laminate of claim 7 wherein the second layer is wood.

References Cited (Backward Citations)

US3780140A Cited
US4123585A Cited
US4489193A Cited
US4329278A Cited
JPS63118354A Cited
US4816306A Cited
JPH01249850A Cited
WO1990013600A1 Cited
WO1991018043A1 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-05-10 1996-11-09 1997-05-11 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-05-10 2000-11-09 2001-05-11 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-05-10 2004-11-09 2005-05-11 $7700.00 Window Closed / Lapsed

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