Patent US5201926A successfully refreshed from Google Patents.
US5201926A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Method for the production of coated glass with a high transmissivity in the visible spectral range and with a high reflectivity for thermal radiation
Assignee: Balzers und Leybold Deutschland Holding AG
•
Filing: 1988-08-08
•
Granted: 1993-04-13
•
Expires: 2008-08-08
Abstract
Abstract Method for making glazing with a high transmissivity in the visible spectral range and with a high reflectivity for thermal radiation as well as low surface resistance. On substrates of mineral glass a system of coatings is built up in the following order: Coating 1: oxide from the group, tin oxide, silicon dioxide, aluminum oxide, tantalum oxide, zirconium oxide, or mixtures thereof, Coating 2: alloy of 80 weight-percent of nickel and 20 weight-percent of chromium, Coating 3: silver or a silver alloy with at least 50 weight-percent silver content, Coating 4: alloy of 80 weight-percent of nickel and 20 weight-percent of chromium, Coating 5: oxide from the group tin oxide, silicon dioxide, aluminum oxide, tantalum oxide, zirconium oxide, or mixtures thereof. Thereafter the substrate with the entire packet of coatings is heated to the softening temperature of the glass and bent to the final shape.
Inventors
- 👤 Joachim Szczyrbowski
- 👤 Anton Dietrich
- 👤 Klaus Hartig
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-08 08:08
CPC Classifications
C; C03; C03C; C03C17/00; C03C17/34; C03C17/36; C03C17/3602; C03C17/3618; C03C17/3644; C03C17/3652; C03C17/3657; C03C17/366; C03C17/3681; B; B60; B60J; B60J1/00; B60J1/002
Claims Analysis
Total Claims: 10
Claim 1
Independent Claim
173 words
Method for the production of coated glass with a high transmissivity in the visible spectral range and with a low surface electrical resistivity and a high reflectivity for thermal radiation by cathode sputtering of coatings on a substrate consisting of mineral glass, the cathode sputtering comprising providing on the mineral glass: a) a first coating comprising at least one oxide from the group consisting of tine oxide, silicon dioxide, aluminum oxide, tantalum oxide and zirconium oxide, b) a second coating of an alloy of about 80 weight-percent nickel and about 20 weight-percent of chromium, c) a third coating of silver or silver alloy containing at least 50 weight-percent of silver, d) a fourth coating of the alloy forming the second coating, and e) a fifth coating of an oxide form the oxides forming the group of said first coating, the substrate then being heated with the coatings a) through e) on it to at least the softening temperature of the glass, plastically shaped in the heated state, and cooled in the shaped state.
Claim 2
Dependent Claim
173 words
Method for the production of coated glass with a high transmissivity in the visible spectral range and with a low surface electrical resistivity and a high reflectivity for thermal radiation by cathode sputtering of coatings on a substrate consisting of mineral glass, the cathode sputtering comprising providing on the mineral glass: a) a first coating comprising at least one oxide from the group consisting of tine oxide, silicon dioxide, aluminum oxide, tantalum oxide and zirconium oxide, b) a second coating of an alloy of about 80 weight-percent nickel and about 20 weight-percent of chromium, c) a third coating of silver or silver alloy containing at least 50 weight-percent of silver, d) a fourth coating of the alloy forming the second coating, and e) a fifth coating of an oxide form the oxides forming the group of said first coating, the substrate then being heated with the coatings a) through e) on it to at least the softening temperature of the glass, plastically shaped in the heated state, and cooled in the shaped state.
Claim 3
Dependent Claim
68 words
Method according to claim 1, wherein a) said coatings b) and d) are applied in a thickness that leads to a greater absorption in the visible range before heat treatment than after heat treatment and b) the heat treatment of said substrate and coatings is performed in an oxidizing atmosphere until the average transmission in the visible range through the substrate and coatings has increased at least 5%.
Claim 4
Dependent Claim
49 words
Method according to claim 1, wherein the maximum transmission in the visible range through the substrate and coatings is established by selecting the thickness of the coatings b), c) and d), to be 70-80% transmission before the heat treatment, and increasing it by the heat treatment to 80-87% transmission.
Claim 5
Dependent Claim
30 words
Method according to claim 1, wherein thickness of the coating c) is adjusted so that, after the heat treatment, a surface electrical resistivity of between 2 and 10 ohms/square results.
Claim 6
Dependent Claim
33 words
Method according to claim 1 wherein the fifth coating comprises 5 to 15 weight-percent of tine and 4-8 weight-percent of at least one from the group consisting of antimony, fluorine, and indium oxide.
Claim 7
Dependent Claim
51 words
Method according to claim 1, wherein the first a) nd the fifth coating e) are produced by cathode sputtering of metal targets in a reactive atmosphere and the second b), third c) and fourth coating d) are produced by cathode sputtering of metal or metal alloy targets in an inert atmosphere.
Claim 8
Dependent Claim
74 words
Method as in claim 1 wherein the respective coatings are sputtered to the following thicknesses: a) first coating: 35 nm b) second coating: 2 nm c) third coating: 20 nm d) fourth coating: 2 nm e) fifth coating: 35 nm and wherein, the thickness of the second and fourth coatings may be varied so that the transmission of light through the substrate and coatings in the visible range is 77% prior to heat treatment.
Claim 9
Dependent Claim
14 words
Method as in claim 1 wherein the second coating consists wholly of tin oxide.
Claim 10
Dependent Claim
23 words
Method of claim 2 wherein the transmission of visible light through the substrate and coatings after heat treatment increases by at least 8%.
References Cited (Backward Citations)
US3944440A
Cited
US3978273A
Cited
US4337990A
Cited
US4188452A
Cited
US4166876A
Cited
EP0035906A2
Cited
US4413877A
Cited
US4334523A
Cited
US4414254A
Cited
US4462883A
Cited
US4650557A
Cited
US4548691A
Cited
US4497700A
Cited
JPS6081876A
Cited
JPS61284703A
Cited
JPS6241740A
Cited
US4715879A
Cited
DE3543178A1
Cited
US4919778A
Cited
US4749397A
Cited
US4718932A
Cited
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1996-04-12 | 1996-10-12 | 1997-04-13 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 2000-04-12 | 2000-10-12 | 2001-04-13 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2004-04-12 | 2004-10-12 | 2005-04-13 | $7700.00 | Window Closed / Lapsed |