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US5187248A Expired / Lapsed US ⏱️ 0.0 years remaining

Monomers and their use for the production of a laser-optical recording element which can be repeatedly erased and recorded on

Assignee: BASF SE
•
Filing: 1991-12-30
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Granted: 1993-02-16
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Expires: 2011-12-30
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Abstract

Abstract Novel laser-optical recording elements which can be repeatedly erased and recorded on contain recording layers (a) which exhibit enantiotropic, ferroelectric smectic liquid crystalline (S c* ) behavior, so that they can be switched back and forth between two thermodynamically stable, optically distinguishable ferroelectric smectic liquid crystalline S C* order states on exposure to a laser beam of sufficient luminous power, by applying an external electric field. The recording layers (a) themselves consist mainly or exclusively of novel polymers P having chiral mesogenic side groups. The novel polymers P are prepared using the novel monomers of the general formula I ##STR1## where R is hydrogen, chlorine or methyl, A is a flexible space-maintaining long-chain molecular moiety, and C is an optically active chiral molecular moiety and B is a mesogenic molecular moiety composed of at least three aromatic nuclei which are bonded linearly or virtually linearly to one another, or they are prepared using the novel monomers I which contain specially selected molecular moieties B in a novel combination with selected molecular moieties C.

Inventors

  • 👤 Karl-Heinz Etzbach
  • 👤 Gerhard Wagenblast
  • 👤 Wolfgang Brox
  • 👤 Axel Paul
  • 👤 Volker Bach

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-08 03:57
CPC Classifications
G; G11; G11B; G11B7/00; G11B7/24; G11B7/241; G11B7/242; G11B7/244; G11B7/25; C; C09; C09K; C09K19/00; C09K19/04; C09K19/38; C09K19/3833; C09K19/3842; C09K19/3852; C09K19/3857

Claims Analysis

Total Claims: 19
Claim 1
Independent Claim 367 words
A polymer I (a) having chiral mesogenic pendant side groups (b) exhibiting ferroelectric smectic liquid crystalline behavior and (c) comprising monomer units which are derived from monomers of the structure I ##STR128## where R is hydrogen, chlorine or methyl, A is a flexible space-maintaining long-chain molecular moiety, C is an optically active chiral molecular moiety and B is a mesogenic molecular moiety which consists of three or more aromatic nuclei bonded linearly or virtually linearly to one another and which is selected from the group consisting of i) moieties B which contain one or more naphth-2,6-ylene groups, ii) moieties B of the formula III ##STR129## where B 2 is a p-phenylene or a biphenyl-4,4'-diyl group Y is an ether, methylene ether (--CH 2 --O-- or --O--CH 2 --), ester ##STR130## or thioester group ##STR131## or a carbon-carbon single bond and m and n are each 0 or an integer ≧1; iii) moieties B of the formula IV ##STR132## where m and n and Y have the abovementioned meanings and B 3 is selected from the group consisting of the p-phenylene, the biphenyl-4,4'-diyl group and the group III-1 ##STR133## where Y has the abovementioned meanings; and iv) moieties B, selected from the group consisting of the groups X-1 to X-7 ##STR134## where Y has the abovementioned meanings and the groups X-1 to X-7 are bonded via the ether group to moiety A, with the proviso that the moiety C of the molecule is exclusively selected from the group consisting of the pinan-3-yl, the camphan-2-yl and the p-menthan-3-yl group and the group of the formula VII ##STR135## where R 3 is methyl or trifluoromethyl, x and r independently of one another are each 0 or 1 and s is an integer from 1 to 3, the group of the formula VIII ##STR136## where s has the abovementioned meaning, and the group of the formula IX ##STR137## where t, u and v independently of one another are each an integer of from 1 to 10 and t and u independently of one another may furthermore be 0, and y is 0 or 1, whenever one of the said groups X-1 to X-7 is selected for moiety B of the molecule.
Claim 2
Dependent Claim 367 words
A polymer I (a) having chiral mesogenic pendant side groups (b) exhibiting ferroelectric smectic liquid crystalline behavior and (c) comprising monomer units which are derived from monomers of the structure I ##STR128## where R is hydrogen, chlorine or methyl, A is a flexible space-maintaining long-chain molecular moiety, C is an optically active chiral molecular moiety and B is a mesogenic molecular moiety which consists of three or more aromatic nuclei bonded linearly or virtually linearly to one another and which is selected from the group consisting of i) moieties B which contain one or more naphth-2,6-ylene groups, ii) moieties B of the formula III ##STR129## where B 2 is a p-phenylene or a biphenyl-4,4'-diyl group Y is an ether, methylene ether (--CH 2 --O-- or --O--CH 2 --), ester ##STR130## or thioester group ##STR131## or a carbon-carbon single bond and m and n are each 0 or an integer ≧1; iii) moieties B of the formula IV ##STR132## where m and n and Y have the abovementioned meanings and B 3 is selected from the group consisting of the p-phenylene, the biphenyl-4,4'-diyl group and the group III-1 ##STR133## where Y has the abovementioned meanings; and iv) moieties B, selected from the group consisting of the groups X-1 to X-7 ##STR134## where Y has the abovementioned meanings and the groups X-1 to X-7 are bonded via the ether group to moiety A, with the proviso that the moiety C of the molecule is exclusively selected from the group consisting of the pinan-3-yl, the camphan-2-yl and the p-menthan-3-yl group and the group of the formula VII ##STR135## where R 3 is methyl or trifluoromethyl, x and r independently of one another are each 0 or 1 and s is an integer from 1 to 3, the group of the formula VIII ##STR136## where s has the abovementioned meaning, and the group of the formula IX ##STR137## where t, u and v independently of one another are each an integer of from 1 to 10 and t and u independently of one another may furthermore be 0, and y is 0 or 1, whenever one of the said groups X-1 to X-7 is selected for moiety B of the molecule.
Claim 3
Dependent Claim 88 words
A polymer I as claimed in claim 1, wherein the said moiety B of the molecule which comprises at least one naphth-2,6-ylene group is a group of the structure II ##STR138## where B 1 is independently a p-phenylene or a biphenyl-4,4'-diyl group, Y is ether, methylene ether (--CH 2 --O-- or --O--CH 2 --), an ester ##STR139## or a thioester ##STR140## or a carbon-carbon single bond and m and n are each 0 or an integer≧1, with the proviso that n cannot be 0 when m is 0.
Claim 4
Dependent Claim 32 words
A polymer I as claimed in claim 2, wherein the said moiety B of the molecule which comprises at least one naphth-2,6-ylene group is selected from the groups II-1 to II-5: ##STR141##
Claim 5
Dependent Claim 28 words
A polymer I as claimed in claim 3, wherein the groups II-1 to II-5 are bonded to the said moiety A of the molecule via the ether group.
Claim 6
Dependent Claim 30 words
A polymer I as claimed in claim 1, wherein the group III-1 ##STR142## where Y has the abovementioned meanings is used as the said moiety B of the structure III.
Claim 7
Dependent Claim 26 words
A polymer I as claimed in claim 5, wherein the group III-1 is bonded to the said moiety A of the molecule via the ether group.
Claim 8
Dependent Claim 30 words
A polymer I as claimed in claim 1, wherein the group IV-1 ##STR143## where Y has the abovementioned meanings, is used as the said moiety B of the structure IV.
Claim 9
Dependent Claim 26 words
A polymer I as claimed in claim 7, wherein the group IV-1 is bonded to the said moiety A of the molecule via the ether group.
Claim 10
Dependent Claim 39 words
A polymer I as claimed in claim 7, wherein an alkylene of the formula V --(--CH.sub.2 --).sub.k -- (V) where k is an integer of from 6 to 11, is used as the said moiety A of the molecule.
Claim 11
Dependent Claim 75 words
A polymer I as claimed in claim 1, wherein the molecular moiety C is a group of the formula VI ##STR144## where R 1 is halogen, R 2 is methyl, cyano or halogen, l is 0 or an integer of from 1 to 10, q is 0 or 1 and p is 0 or an integer of from 1 to 10, with the proviso that p may not be 0 when R 2 is methyl.
Claim 12
Dependent Claim 20 words
A polymer I as claimed in claim 1, wherein the molecular moiety C is a pinan-3-yl, camphan-2-yl or p-menthan-3-yl group.
Claim 13
Dependent Claim 50 words
A polymer I as claimed in claim 1, wherein the molecular moiety C is a group of the formula VII ##STR145## where R 3 is methyl or trifluoromethyl, r and x independently of one another are each 0 or 1 and s is an integer of from 1 to 3.
Claim 14
Dependent Claim 36 words
A polymer I as claimed in claim 1, wherein the molecular moiety C is a group of the formula VIII ##STR146## here s has the meanings and s is an integer of from 1 to 3.
Claim 15
Dependent Claim 56 words
A polymer I as claimed in claim 1, wherein the molecular moiety C is a group of the formula IX ##STR147## where t, u and v independently of one another are each an integer of from 1 to 10, t and u independently of one another may furthermore be 0, and y is 0 or 1.
Claim 16
Dependent Claim 18 words
A polymer I as claimed in claim 1, further comprising known pendant side groups exhibiting liquid crystalline behavior.
Claim 17
Dependent Claim 15 words
A polymer I as claimed in claim 15, further comprising pendent side groups containing chromophores.
Claim 18
Dependent Claim 15 words
A polymer I as claimed in claim 1, further comprising pendent side groups containing chromophores.
Claim 19
Dependent Claim 14 words
The polymer of the structure I as defined in claim 1, which is ##STR148##

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-02-16 1996-08-17 1997-02-16 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-02-16 2000-08-17 2001-02-16 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-02-16 2004-08-17 2005-02-16 $7700.00 Window Closed / Lapsed

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