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US5180756A Expired / Lapsed US ⏱️ 0.0 years remaining

Agents curable by ultraviolet radiation

Assignee: BASF SE
•
Filing: 1990-04-06
•
Granted: 1993-01-19
•
Expires: 2010-04-06
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Abstract

Abstract Agents which are curable by ultraviolet radiation are based on a binder formulation of (1) from 99.0 to 20% by weight of a copolymer, (2) from 1.0 to 80% by weight of monoolefinically unsaturated compounds and (3) from 0.0 to 20% by weight of polyolefinically unsaturated compounds. The agents contain copolymers (1) which are obtainable by subjecting a mixture of (A) from 80 to 99.9% by weight of olefinically unsaturated monomers, (B) from 0 to 10% by weight of a copolymerizable olefinically unsaturated photoinitiator and (C) from 0 to 10% by weight of a polymerization-regulating photoinitiator to free radical polymerization, the sum of (B) and (C) being not less than 0.1% by weight and the stated percentages by weight being based on the sum of the weights of (A)+(B)+(C).

Inventors

  • 👤 Gerd Rehmer
  • 👤 Andreas Boettcher

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-03 22:31
CPC Classifications
C; C09; C09J; C09J4/00; C09J4/06

Claims Analysis

Total Claims: 14
Claim 1
Independent Claim 164 words
A composition which is curable by ultraviolet radiation and is based on a binder formulation of: 1) from 99.0 to 20% by weight of a copolymer, 2) from 1.0 to 80% by weight of monoolefinically unsaturated compounds, and 3) from 0 to 20% by weight of polyolefinically unsaturated compounds, wherein the composition contains a copolymer (1) which is obtainable by subjecting to a free-radical-initiated polymerization a mixture of: (A) from 20 to 99.9% by weight of olefinically unsaturated monomers, (B) from 0 to 10% by weight of a copolymerizable olefinically unsaturated photoinitiator, (C) from 0.1 to 10% by weight of a polymerizationregulating initiator selected from the group consisting of 1-(4-isopropylphenyl)-2-hydroxy-2-methylpropane-1-one, isopropyl thioxanthone, 4-isopropylbenzophenone, ethyl2,4,6-trimethylbenzo-ylphenylphosphinate, isopropyl benzoin ether, 2,2-diethoxyacetophenone and ethyl benzoin ether; which initiator reduces the degree of polymerization of the copolymer (1) during the free-radical-initiated polymerization, the sum of (B) and (C) being not less than 0.1% by weight and the stated percentages being based on the sum of the weights of (A)+(B)+(C).
Claim 2
Dependent Claim 164 words
A composition which is curable by ultraviolet radiation and is based on a binder formulation of: 1) from 99.0 to 20% by weight of a copolymer, 2) from 1.0 to 80% by weight of monoolefinically unsaturated compounds, and 3) from 0 to 20% by weight of polyolefinically unsaturated compounds, wherein the composition contains a copolymer (1) which is obtainable by subjecting to a free-radical-initiated polymerization a mixture of: (A) from 20 to 99.9% by weight of olefinically unsaturated monomers, (B) from 0 to 10% by weight of a copolymerizable olefinically unsaturated photoinitiator, (C) from 0.1 to 10% by weight of a polymerizationregulating initiator selected from the group consisting of 1-(4-isopropylphenyl)-2-hydroxy-2-methylpropane-1-one, isopropyl thioxanthone, 4-isopropylbenzophenone, ethyl2,4,6-trimethylbenzo-ylphenylphosphinate, isopropyl benzoin ether, 2,2-diethoxyacetophenone and ethyl benzoin ether; which initiator reduces the degree of polymerization of the copolymer (1) during the free-radical-initiated polymerization, the sum of (B) and (C) being not less than 0.1% by weight and the stated percentages being based on the sum of the weights of (A)+(B)+(C).
Claim 3
Dependent Claim 24 words
The composition of claim 1, wherein in said copolymer (1) component (A) is used in an amount of from 80 to 99.9% by weight.
Claim 4
Dependent Claim 23 words
The composition of claim 1, wherein said copolymer (1) component (A) is used in an amount of from 90 to 99.9% by weight.
Claim 5
Dependent Claim 52 words
The composition of claim 1, wherein said component (A) comprises methacrylates of alkanols of 1 to 24 carbon atoms, vinyl esters of saturated carboxylic acids of 1 to 20 carbon atoms, vinyl ethers of 3 to 22 carbon atoms or vinyl aromatics of 8 to 12 carbon atoms or a combination thereof.
Claim 6
Dependent Claim 25 words
The composition of claim 1, wherein said component (A) comprises polymerized monomers which contain one or more spacerbonded polar groups capable of forming hydrogen bridges.
Claim 7
Dependent Claim 18 words
The composition of claim 1, wherein said component (A) has a K value of from 8 to 100.
Claim 8
Dependent Claim 18 words
The composition of claim 6, wherein said component (A) has a K value of from 12 to 80.
Claim 9
Dependent Claim 18 words
The composition of claim 7, wherein said component (A) has a K value of from 12 to 70.
Claim 10
Dependent Claim 15 words
The composition of claim 1, wherein in said copolymer (1) component (B) comprises a (meth)acrylate.
Claim 11
Dependent Claim 24 words
The composition of claim 1, wherein in said copolymer (1) component (B) is used in an amount of from 0.01 to 5% by weight.
Claim 12
Dependent Claim 24 words
The composition of claim 1, wherein in said copolymer (1) component (B) is used in an amount of from 0.1 to 2.5% by weight.
Claim 13
Dependent Claim 24 words
The composition of claim 1, wherein in said copolymer (1) component (C) is used in an amount of from 0.1 to 7.5% by weight.
Claim 14
Dependent Claim 23 words
The composition of claim 1, wherein in said copolymer (1) component (C) is used in an amount from 1.0 to 5% by weight.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1996-01-19 1996-07-20 1997-01-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 2000-01-19 2000-07-20 2001-01-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2004-01-19 2004-07-20 2005-01-19 $7700.00 Window Closed / Lapsed

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