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US4822829A Expired / Lapsed US ⏱️ 0.0 years remaining

Radiation-curable macromers based on (meth)acrylate-functional polyesters, and their use

Assignee: Huels Troisdorf AG
•
Filing: 1986-05-07
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Granted: 1989-04-18
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Expires: 2006-05-07
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Abstract

Abstract Radiation-setting (meth)acrylate-functional polyesters prepared from base polyesters which are fluid at room temperature and have molecular weights of 1,000 or more as well as aliphatic side chains bound to the main chain by ester bridges and, in some cases, ether bridges, and in which a maximum of 90% of the original hydroxyl groups of the base polyester are functionalized, are usable for coatings and especially as adhesives free of solvents.

Inventors

  • 👤 Hartmut Muller
  • 👤 Hans Huber

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-04 15:13
CPC Classifications
C; C09; C09J; C09J175/00; C09J175/04; C09J175/14; C09J175/16; C08; C08G; C08G18/00; C08G18/06; C08G18/28; C08G18/40; C08G18/42; C08G18/4291; C08G18/70; C08G18/81; C08G18/8108; C08G18/8116; C08G18/8141; C08G18/815; C08G18/8158; C08G18/8175; C08G63/00; C08G63/02; C08G63/12; C08G63/40; C08G63/42; C08G63/46; C08G63/66; C09J7/00; C09J7/30; C09J7/38; C09J2467/00; Y; Y10; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31551; Y10T428/31565; Y10T428/31786; Y10T428/31794

Claims Analysis

Total Claims: 25
Claim 1
Independent Claim 158 words
Radiation-curable macromers based on (meth)acrylate-functional polyesters, comprising (a) base polyesters which are hydroxyl polyesters liquid at room temperature having hydroxyl numbers of 10 to 100, acid numbers lower than 5, a glass transition temperature lower than 0° C., and average molecular weight of from 2,000 to 5,000, said polyesters being fluid at 20° C. and having straight-chain alkyl or branched alkyl side chains of 4 to 36 carbon atoms directly bound through ester bonds or ether bonds of at least one of trifunctional or polyfunctional carboxylic acids, triols or polyfunctional polyols and hydroxydicarboxyclic acids along the main chain of the polyesters, the molar ratio of ester segments of the main chain to the alkyl side chains ranging from 1:0.2 to 1:2.0, and in which 10 to 90% of the hydroxyl groups of said polyesters have been reacted with (b) acrylate compounds or methacrylate compounds having additional reactive groups capable of reacting with the hydroxyl groups of said polyesters.
Claim 2
Dependent Claim 158 words
Radiation-curable macromers based on (meth)acrylate-functional polyesters, comprising (a) base polyesters which are hydroxyl polyesters liquid at room temperature having hydroxyl numbers of 10 to 100, acid numbers lower than 5, a glass transition temperature lower than 0° C., and average molecular weight of from 2,000 to 5,000, said polyesters being fluid at 20° C. and having straight-chain alkyl or branched alkyl side chains of 4 to 36 carbon atoms directly bound through ester bonds or ether bonds of at least one of trifunctional or polyfunctional carboxylic acids, triols or polyfunctional polyols and hydroxydicarboxyclic acids along the main chain of the polyesters, the molar ratio of ester segments of the main chain to the alkyl side chains ranging from 1:0.2 to 1:2.0, and in which 10 to 90% of the hydroxyl groups of said polyesters have been reacted with (b) acrylate compounds or methacrylate compounds having additional reactive groups capable of reacting with the hydroxyl groups of said polyesters.
Claim 3
Dependent Claim 95 words
The macromers of claim 1 in which the acrylate compounds or methacrylate compounds are selected from the group consisting of (b1) isocyanatoalkylacrylate or isocyanatoalkylmethacrylate, (b2) adducts of di- or tri-isocyanates or polyisocyanates or isocyanato prepolymers of polyesters or polyethers of low molecular weight with hydroxyalkylacrylates or hydroxyalkylmethacrylates. (b3) methylacrylamidoglycolate methyl ethers, (b4) methacrylic acid or acrylic acid or their derivatives, (b5) the reaction product of glycidylacrylate or glycidylmethacrylate with carbonyl groups formed by the reaction of the hydroxyl groups of the polyesters with a dicarboxylic acid, a tricarboxylic acid or their anhydrides, and mixtures thereof.
Claim 4
Dependent Claim 24 words
The macromers of claim 1, wherein 30 to 70% of the hydroxyl groups of the polyesters are reacted with acrylate compounds or methacrylate compounds.
Claim 5
Dependent Claim 30 words
The macromers of claim 1, wherein the portion of the hydroxyl groups of the polyesters that has not reacted with acrylate compounds or methacrylate compounds is preserved as hydroxyl groups.
Claim 6
Dependent Claim 14 words
The macromers of claim 1, further containing tackifying resins, pigments, anti-aging agents or fillers.
Claim 7
Dependent Claim 36 words
The macromers of claim 2, in which the acrylate compounds or methacrylate compounds are adducts of di- or tri-isocyanates or polyisocyanates or isocyanato prepolymers of polyesters or polyethers of low molecular weight with hydroxyalkylacrylates or hydroxyalkylmethacrylates.
Claim 8
Dependent Claim 26 words
The macromers of claim 6, in which the acrylate compounds or methacrylate compounds are prepared from substantially equivalent amounts of isocyanate compounds and hydroxyalkylacrylates or hydroxyalkylmethacrylates.
Claim 9
Dependent Claim 25 words
The macromers according to claim 7, in which the isocyanate compounds is selected from the group consisting of toluylene diisocyanate, methylenediphenyl-4,4'-diisocyanate, hexamethylenediisocyanate, benzene-1,4-diisopropylisocyanate, and isophoronediisocyanate.
Claim 10
Dependent Claim 17 words
The macromers according to claim 8, in which the acrylate compound is prepared from isophoronediisocyanate and 2-hydroxyethylacrylate.
Claim 11
Dependent Claim 18 words
The macromers according to claim 8, in which the acrylate compound is prepared from toluylene diisocyanate and 2-hydroxyethylacrylate.
Claim 12
Dependent Claim 17 words
The macromers of claim 1, wherein the base polyesters have glass transition temperatures lower than -20° C.
Claim 13
Dependent Claim 19 words
The macromers of claim 1, wherein the base polyesters bear alkyl side chains of 4 to 18 carbon atoms.
Claim 14
Dependent Claim 19 words
The macromers of claim 12 wherein the base polyesters bear alkyl side chains of 8 to 18 carbon atoms.
Claim 15
Dependent Claim 16 words
The macromers of claim 12, wherein the alkyl side chains of the base polyesters are branched.
Claim 16
Dependent Claim 23 words
The macromers of claim 1, wherein the base polyesters, prior to the reaction with acrylate compounds, have hydroxyl numbers from 20 to 60.
Claim 17
Dependent Claim 30 words
The macromers of claim 1, wherein, in the polyesters, the molar ratio of the ester segments of the main chain to the alkyl side chains ranges from 1:0.05 to 1:1.0.
Claim 18
Dependent Claim 34 words
The macromers of claim 16, wherein the alkyl side chains are the alkyl groups of aliphatic monoalcohol partial esters of tri or polycarboxylic acids said esters having an average of two polyester-forming carboxyl groups.
Claim 19
Dependent Claim 13 words
The macromers of claim 17, wherein partial esters are monoester of tricarboxylic acid.
Claim 20
Dependent Claim 32 words
The macromers of claim 16, wherein the alkyl side chains are the alkyl groups of aliphatic monocarboxylic acid partial esters of polyols, said esters having an average of two polyester-forming hydroxyl groups.
Claim 21
Dependent Claim 15 words
The macromers of claim 19, wherein the partial esters are glycidyl monoesters or trimethylolpropane monoesters.
Claim 22
Dependent Claim 31 words
The macromers of claim 16, wherein the alkyl side chains are the alkyl groups of aliphatic monoalcohol partial ethers of polyols, said ethers having an average of two polyester-forming hydroxyl groups.
Claim 23
Dependent Claim 13 words
The macromers of claim 21, wherein the partial esters are monoether of triol.
Claim 24
Dependent Claim 17 words
The macromers of claim 16, in which the base polyester is prepared from trimellitic acid tri-2-ethylhexyl ester.
Claim 25
Dependent Claim 17 words
The macromers of claim 16, in which the base polyester is prepared from trimethylolpropane mono-2-ethylhexanoic acid ester.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1992-04-17 1992-10-17 1993-04-18 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1996-04-17 1996-10-17 1997-04-18 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2000-04-17 2000-10-17 2001-04-18 $7700.00 Window Closed / Lapsed

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