Radiation-curable prepolymer

Claim 2

A substantially NCO-free radiation-curable prepolymer which is the reaction product of (A) an organic diisocyanate with (B) a low-molecular weight hydroxyl-containing unsaturated monomer having both a hydroxyl group and a polymerizable double bond and (C) a polyester polyol containing 2 to 8 hydroxyl groups per molecule, the polyester polyol (C) having a number average molecular weight of 400 to 6,000 and a hydroxyl equivalent weight of 200 to 3,000 and containing a dimer acid residue derived from 9 to 70% based on the weight of the total weight of the starting materials, of dimer acid and an alcohol residue derived from 20 to 75%, based on the total weight of the starting materials, of an ethylene oxide or propylene oxide adduct of bisphenol A with the proportion of the oxide added being 2 to 4 moles per mole of bisphenol A.

Claim 3

A process for producing the radiation-curable prepolymer of claim 1 which comprises a first step of reacting the organic diisocyanate (A) with the unsaturated monomer (B), the ratio of the number of hydroxyl groups to that of isocyanate groups being 0.4 to 0.7:1; and a second step of reacting the isocyanate-containing product of the first step with the polyester polyol (C) in an amount substantially equal in gram-equivalent weight to the product of the first step.

Claim 4

An ultraviolet-curable metal coating composition consisting essentially of (1) 100 parts by weight of the radiation-curable prepolymer of claim 1 and (2) 0.1 to 10 parts by weight of a photoinitiator.

Claim 5

A radiation-curable resin composition consisting essentially of at least 30% by weight of the radiation-curable prepolymer of claim 1 and not more than 70% by weight of a reactive diluent containing 1 or 2 polymerizable double bonds per molecule and having a boiling point of at least 200° C.

Claim 6

The radiation-curable resin composition of claim 4 wherein the reactive diluent is a mixture consisting of 30 to 80% by weight of a compound of the general formula ##STR6## wherein R 1 represents a hydrogen atom or a methyl group, R 2 represents a glycol residue containing 2 to 10 carbon atoms or a glycol residue containing 2 to 10 carbon atoms with the carbon chain of the glycol having an oxygen atom interposed, and R 3 represents a phenyl group or a phenyl group substituted with an alkyl group having 1 to 4 carbon atoms, 10to 35% by weight of a compound of the general formula ##STR7## wherein R 1 represents a hydrogen atom or a methyl group, R 2 represents a glycol residue containing 2 to 10 carbon atoms or a glycol residue containing 2 to 10 carbon atoms with the carbon chain of the glycol having an oxygen atom interposed and 10 to 35% by weight of a compound of the general formula R.sub.3 COO--R.sub.2 --OCO--R.sub.3 wherein R 3 represents a phenyl group or a phenyl group substituted with an alkyl group containing 1 to 4 carbon atoms, and R 2 represents a glycol residue containing 2 to 10 carbon atoms or a glycol residue containing 2 to 10 carbon atoms with the carbon chain of the glycol having an oxygen atom interposed.

Claim 7

An ultraviolet-curable metal coating composition consisting essentially of (1) 100 parts by weight of the resin composition of claim 4 and (2) 0.1 parts by weight of a photoinitiator.