US5156919A
Expired / Lapsed
US
⏱️ 0.0 years remaining
Fluorocarbon coated magnesium alloy carriage and method of coating a magnesium alloy shaped part
Assignee: Seagate Technology LLC
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Filing: 1990-04-03
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Granted: 1992-10-20
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Expires: 2010-04-03
Abstract
Abstract A magnesium alloy structural member for supporting at least one actuator arm in a hard disk drive and a method for making a shaped magnesium part having a fluorocarbon coating is disclosed. The coating is applied by exposing the member to a reactive gas in the presence of a glow discharge plasma to prevent corrosion. The glow discharge is generated by providing a vacuum environment at a pressure of between 250 and 300 millitorr in a reaction chamber and applying power to a pair of electrodes contained within the reaction chamber. Power is supplied at between about 100 and about 200 watts at about 13.6 megahertz, forming a low temperature glow discharge plasma. A reactive gas comprising a fluorinated alkane is introduced to the reaction chamber, and a pressure of between about 100 and about 300 millitorr is maintained. The structural member is exposed to the reactive gas and the plasma for an amount of time sufficient to form a thin and uniform polymeric fluorocarbon coating on the surface of the part. After the coating is formed, the chamber is purged with a hydrocarbon gas to consume any fluorine free radicals.
Inventors
- 👤 Amarjit S. Brar
- 👤 Prativadi B. Narayan
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-29 21:40
CPC Classifications
G; G11; G11B; G11B5/00; G11B5/48; G11B5/4806; G11B5/4813; C; C23; C23C; C23C16/00; C23C16/22; C23C16/30; Y; Y10; Y10S; Y10S428/00; Y10S428/922; Y10S428/9335; Y10S428/938; Y10T; Y10T428/00; Y10T428/31504; Y10T428/3154; Y10T428/31678; Y10T428/31692; Y10T428/31699
Claims Analysis
Total Claims: 33
Claim 1
Independent Claim
96 words
An actuator arm carriage for supporting an actuator arm in a magnetic disk drive, the actuator arm carriage comprising: a carriage body having a shaped exterior surface that is susceptible to corrosion, wherein the body is formed from a magnesium alloy in which magnesium is a principal component; and a polymeric film consisting essentially of extended chain fluoropolymers in direct contact with and coating the exterior surface of the body, the film having a thickness sufficient to inhibit corrosion of the carriage body caused by reaction of magnesium with substances in an atmosphere surrounding the carriage.
Claim 2
Dependent Claim
96 words
An actuator arm carriage for supporting an actuator arm in a magnetic disk drive, the actuator arm carriage comprising: a carriage body having a shaped exterior surface that is susceptible to corrosion, wherein the body is formed from a magnesium alloy in which magnesium is a principal component; and a polymeric film consisting essentially of extended chain fluoropolymers in direct contact with and coating the exterior surface of the body, the film having a thickness sufficient to inhibit corrosion of the carriage body caused by reaction of magnesium with substances in an atmosphere surrounding the carriage.
Claim 3
Dependent Claim
23 words
The carriage of claim 1 wherein the magnesium alloy has a modulus of elasticity between about 6.0 million and about 12.0 million psi.
Claim 4
Dependent Claim
36 words
The carriage of claim 2 wherein the magnesium alloy includes zinc in an amount of about 1% by weight, aluminum in an amount 9% by weight, and manganese in an amount of about 0.2% by weight.
Claim 5
Dependent Claim
22 words
The carriage of claim 1 wherein the coating is a substantially saturated fluorocarbon polymer, having a C:F atomic ratio of about 1:2.
Claim 6
Dependent Claim
18 words
The carriage of claim 1 wherein the polymeric film is between about 50 and about 500 angstroms thick.
Claim 7
Dependent Claim
15 words
The carriage of claim 1 wherein the body is formed by a die cast method.
Claim 8
Dependent Claim
15 words
The carriage of claim 1 wherein the body is formed by a sand cast method.
Claim 9
Independent Claim
189 words
A method of inhibiting corrosion of a shaped mechanical part having exterior surfaces which are formed from a magnesium metal alloy comprising the steps of: positioning the part in a reaction chamber, the reaction chamber having an anode and a cathode; providing a vacuum at an initial pressure between about 250 and about 300 millitorr; forming a glow discharge plasma with a power supply to the anode and cathode of between about 100 and about 200 Watts, and at a frequency of about 13.6 megahertz; introducing a reactive gas comprising fluorinated alkanes to the reaction chamber, wherein the gas pressure is maintained between about 100 to about 300 millitorr; exposing the exterior surfaces to the reactive gas and plasma for an amount of time sufficient to form a polymeric film covering the exterior surfaces which are in direct contact with and formed from a magnesium metal alloy, the polymeric film consisting essentially of extended chain fluoropolymers; and exposing the exterior surfaces to a purge gas comprising at least one hydrocarbon for an amount of time sufficient to form a coating capable of protecting the mechanical part from atmospheric corrosion.
Claim 10
Independent Claim
189 words
A method of inhibiting corrosion of a shaped mechanical part having exterior surfaces which are formed from a magnesium metal alloy comprising the steps of: positioning the part in a reaction chamber, the reaction chamber having an anode and a cathode; providing a vacuum at an initial pressure between about 250 and about 300 millitorr; forming a glow discharge plasma with a power supply to the anode and cathode of between about 100 and about 200 Watts, and at a frequency of about 13.6 megahertz; introducing a reactive gas comprising fluorinated alkanes to the reaction chamber, wherein the gas pressure is maintained between about 100 to about 300 millitorr; exposing the exterior surfaces to the reactive gas and plasma for an amount of time sufficient to form a polymeric film covering the exterior surfaces which are in direct contact with and formed from a magnesium metal alloy, the polymeric film consisting essentially of extended chain fluoropolymers; and exposing the exterior surfaces to a purge gas comprising at least one hydrocarbon for an amount of time sufficient to form a coating capable of protecting the mechanical part from atmospheric corrosion.
Claim 11
Dependent Claim
32 words
The method of claim 8 and further comprising the step of providing an argon atmosphere at a pressure of between about 250 and about 300 millitorr prior to introducing the reactive gas.
Claim 12
Dependent Claim
23 words
The method of claim 8 wherein the shaped mechanical part contacts the cathode while the part is being exposed to the reactive gas.
Claim 13
Dependent Claim
16 words
The method of claim 10, wherein the shaped mechanical part is inductively coupled to the cathode.
Claim 14
Dependent Claim
31 words
The method of claim 8, wherein the shaped mechanical part is out of physical contact with the anode and cathode, and the part is positioned substantially between the anode and cathode.
Claim 15
Dependent Claim
13 words
The method of claim 8 wherein power is supplied at about 150 watts.
Claim 16
Dependent Claim
24 words
The method of claim 8 wherein the exterior surfaces are exposed to the reactive gas for between about 45 minutes and about 2 hours.
Claim 17
Dependent Claim
14 words
The method of claim 14 wherein the surfaces are exposed for about an hour.
Claim 18
Dependent Claim
27 words
The method of claim 8 wherein the pressure in the chamber is at about 250 millitorr pressure when the part is being exposed to the reactive gas.
Claim 19
Dependent Claim
13 words
The method of claim 8 wherein the fluorinated alkane is CF 4 .
Claim 20
Dependent Claim
19 words
The method of claim 8 wherein the reactive gas is a mixture of CF 4 and F 2 .
Claim 21
Dependent Claim
44 words
The method of claim 8 and further comprising the step of exposing the part to an argon glow discharge plasma prior to exposing the exterior surfaces to the reactive gas for between about 45 minutes and about 2 hours for cleaning the outer surfaces.
Claim 22
Dependent Claim
8 words
The product of the process of claim 8.
Claim 23
Dependent Claim
17 words
The product of claim 20, wherein the coating thickness is between about 50 and about 500 angstroms.
Claim 24
Dependent Claim
19 words
The method of claim 8 wherein a pressure sensor and pressure controller maintain a selected pressure in the chamber.
Claim 25
Dependent Claim
32 words
The method of claim 8 wherein prior to positioning the part in the reaction chamber, the exterior surfaces are coated with machine oil immediately after forming the part to inhibit environmental corrosion.
Claim 26
Dependent Claim
33 words
The method of claim 23 wherein after contacting the exterior surfaces with oil, the part is washed in an ultrasonic bath containing a solvent, for removing all but trace amounts of machine oil.
Claim 27
Dependent Claim
12 words
The method of claim 8 wherein the fluorinated alkane is carbon tetrafluoride.
Claim 28
Dependent Claim
32 words
The method of claim 8 wherein the ratio of carbon atoms to fluorine atoms in the reactive gas is less than or equal to about one carbon atom per two fluorine atoms.
Claim 29
Dependent Claim
15 words
The method of claim 8 wherein the magnesium containing part is formed from Alloy AZ91B.
Claim 30
Dependent Claim
15 words
The method of claim 8 wherein the magnesium containing part is formed from Alloy AZ31B.
Claim 31
Dependent Claim
11 words
The method of claim 8 wherein the purge gas is methane.
Claim 32
Dependent Claim
37 words
The method of claim 8 wherein after the coating is formed, the power to the electrodes is shut off, and a vacuum between about 400 and about 500 millitorr is provided before introduction of the purge gas.
Claim 33
Dependent Claim
29 words
The method of claim 29 wherein a pressure of about 400 millitorr is maintained for a period of between about ten and about fifteen minutes during the purging step.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-10-20 | 1996-04-20 | 1996-10-20 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-10-20 | 2000-04-20 | 2000-10-20 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-10-20 | 2004-04-20 | 2004-10-20 | $7700.00 | Window Closed / Lapsed |