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US5155195A Expired / Lapsed US ⏱️ 0.0 years remaining

Sidechain copolymers exhibiting nonlinear optical response

Assignee: Hoechst Celanese Chemical Co
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Filing: 1991-05-16
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Granted: 1992-10-13
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Expires: 2011-05-16
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Abstract

Abstract In one embodiment this invention provides a novel type of copolymer which can be formed into a thin film nonlinear optical medium which exhibits superior light transmission properties, and which has excellent adhesion properties when laminated with inorganic or organic layers. An invention copolymer is illustrated by the structure: ##STR1##

Inventors

  • 👤 Bernice I. Feuer

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-06 12:27
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/35; G02F1/355; G02F1/361; G02F1/3615; G02F1/3617; C; C08; C08F; C08F220/00; C08F220/02; C08F220/10; C08F220/34; C08F220/36; C08F230/00; C08F230/04; C08F230/08; C08F230/085

Claims Analysis

Total Claims: 8
Claim 1
Independent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR16## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --S--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CN) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.
Claim 2
Dependent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR16## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --S--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CN) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.
Claim 3
Dependent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR17## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --S--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CH) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.
Claim 4
Dependent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR17## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --S--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CH) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.
Claim 5
Dependent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR18## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --S--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CN) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.
Claim 6
Dependent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR18## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --S--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CN) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.
Claim 7
Dependent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR19## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --X--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CN) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.
Claim 8
Dependent Claim 136 words
A copolymer which is characterized by recurring monomeric units corresponding to the formula: ##STR19## where R is hydrogen or a C 1 -C 4 alkyl substituent; R 1 is a C 1 -C 8 alkyl substituent; R 2 moieties are selected from the group consisting of a C 1 -C 4 alkyl substituent, a C 1 -C 4 alkoxy group, and an olefinically unsaturated group, and from combinations thereof; n is an integer with a value of 2-12; n 1 is an integer with a value of 0-8; X is an electron-donating group that is --NR--, --O--, or --X--; Z is an electron-withdrawing group that is --NO 2 , --CN, --CF 3 , --CH═C(CN) 2 , --C(CN)═C(CN) 2 or --SO 2 CF 3 ; and the copolymer has a glass transition temperature between about 40°-220° C.

References Cited (Backward Citations)

US4625006A Cited
US4915491A Cited
US4742136A Cited
US4898895A Cited
US4865430A Cited
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US5041510A Cited
US5041509A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-10-13 1996-04-13 1996-10-13 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-10-13 2000-04-13 2000-10-13 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-10-13 2004-04-13 2004-10-13 $7700.00 Window Closed / Lapsed

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