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US5128233A Expired / Lapsed US ⏱️ 0.0 years remaining

Element having improved adhesion of auxiliary layers to film supports containing antistatic layers

Assignee: EIDP Inc
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Filing: 1992-01-07
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Granted: 1992-07-07
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Expires: 2012-01-07
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Abstract

Abstract A film support having an auxiliary layer coated over an antistatic layer coated on one side thereof is described. This element, which is particularly useful for the application of subsequently applied photosensitive layers on side opposite said auxiliary layer, comprises gelatin, a crosslinking agent, optionally a conductive polymer and an adhesion promoting amount of an adhesion agent, said adhesion agent selected from the group consisting of: compounds containing at least one --NH 2 group and compounds containing at least two --NH groups, wherein said adhesion agent is sufficiently soluble in water that said adhesion promoting amount of adhesion agent may be dissolved in the dispersion used to coat said auxiliary layer, with the proviso that said adhesion agent is not malonamide. Preferred adhesion agents are urea, thiourea and 2-imidazolidone. Improved adhesion of the auxiliary layer to the antistatic layer is achieved.

Inventors

  • 👤 Rudolf W. Beisswenger
  • 👤 Kurt B. Gundlach

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 23:20
CPC Classifications
G; G03; G03C; G03C1/00; G03C1/76; G03C1/85; G03C1/7614; Y; Y10; Y10S; Y10S428/00; Y10S428/913; Y10T; Y10T428/00; Y10T428/31504; Y10T428/31511; Y10T428/31515; Y10T428/31855; Y10T428/31935

Claims Analysis

Total Claims: 22
Claim 1
Independent Claim 240 words
A photographic element comprising: (A) a polymeric film support having carboxyl groups attached to the surface thereof; (B) a photosensitive layer coated on one side of the support; (C) a permanent antistatic layer coated directly on the surface of the support opposite the photosensitive layer, said antistatic layer consisting essentially of the reaction product of: (1) a water-soluble, electrically conductive polymer having functionally attached carboxyl groups integral to the polymer, and (2) a polyfunctional substituted aziridine wherein at least one hydrogen atom on a carbon atom of the aziridine ring is substituted with an alkyl substituent wherein alkyl is of 1 to 6 carbon atoms, wherein the aziridine interlinks the water-soluble, electrically conductive polymer having functionally attached carboxyl groups integral to the polymer and the carboxyl groups on the surface of the support to form an antistatic layer; and (D) an auxiliary layer coated over said antistatic layer, said auxiliary layer consisting essentially of an aqueous dispersion of gelatin, a gelatin crosslinking agent, and an adhesion promoting amount of an adhesion agent selected from the group consisting of 1) a compound containing at least one --NH 2 group, 2) a compound containing at least two --NH groups, and 3) mixtures thereof, wherein said adhesion agent is sufficiently soluble in water that said adhesion promoting amount of adhesion agent may be dissolved in the dispersion used to coat said auxiliary layer, with the proviso that said adhesion agent is not malonamide.
Claim 2
Dependent Claim 240 words
A photographic element comprising: (A) a polymeric film support having carboxyl groups attached to the surface thereof; (B) a photosensitive layer coated on one side of the support; (C) a permanent antistatic layer coated directly on the surface of the support opposite the photosensitive layer, said antistatic layer consisting essentially of the reaction product of: (1) a water-soluble, electrically conductive polymer having functionally attached carboxyl groups integral to the polymer, and (2) a polyfunctional substituted aziridine wherein at least one hydrogen atom on a carbon atom of the aziridine ring is substituted with an alkyl substituent wherein alkyl is of 1 to 6 carbon atoms, wherein the aziridine interlinks the water-soluble, electrically conductive polymer having functionally attached carboxyl groups integral to the polymer and the carboxyl groups on the surface of the support to form an antistatic layer; and (D) an auxiliary layer coated over said antistatic layer, said auxiliary layer consisting essentially of an aqueous dispersion of gelatin, a gelatin crosslinking agent, and an adhesion promoting amount of an adhesion agent selected from the group consisting of 1) a compound containing at least one --NH 2 group, 2) a compound containing at least two --NH groups, and 3) mixtures thereof, wherein said adhesion agent is sufficiently soluble in water that said adhesion promoting amount of adhesion agent may be dissolved in the dispersion used to coat said auxiliary layer, with the proviso that said adhesion agent is not malonamide.
Claim 3
Dependent Claim 18 words
An element according to claim 1 wherein said adhesion agent has a boiling point greater than 65° C.
Claim 4
Dependent Claim 53 words
An element of claim 1 wherein said adhesion agent is selected from the group consisting of amides containing at least one --NH 2 group, amides containing at least two --NH groups, urea, substituted ureas containing at least one --NH 2 group, substituted ureas containing at least two --NH groups, guanidine hydrochloride, and thiourea.
Claim 5
Dependent Claim 25 words
An element according to claim 3 wherein said auxiliary layer has a coating weight of about 20 mg/dm 2 to about 100 mg/dm 2 .
Claim 6
Dependent Claim 12 words
An element according to claim 1 wherein said adhesion agent is urea.
Claim 7
Dependent Claim 12 words
An element according to claim 1 wherein said adhesion agent is 2-imidazolidone.
Claim 8
Dependent Claim 12 words
An element according to claim 1 wherein said adhesion agent is thiourea.
Claim 9
Dependent Claim 30 words
An element according to claim 1 wherein said photosensitive layer comprises a gelatino silver halide emulsion layer coated on the side of said support opposite the antistatic and auxiliary layers.
Claim 10
Dependent Claim 15 words
An element according to claim 1 wherein antihalation dyes are present in said auxiliary layer.
Claim 11
Dependent Claim 24 words
An element according to claim 3 wherein said adhesion agent is present in the amount of 10-150 millimoles per 200 gm of gelatin present.
Claim 12
Dependent Claim 30 words
An element according to claim 3 wherein said photosensitive layer comprises a gelatino silver halide emulsion layer coated on the side of said support opposite the antistatic and auxiliary layers.
Claim 13
Dependent Claim 27 words
An element according to claim 11 wherein said antistatic layer is applied at a coating weight of about 4 mg/dm 2 to about 15 mg/dm 2 .
Claim 14
Dependent Claim 26 words
An element according to claim 11 wherein in the antistatic layer, on a weight basis, the proportions of (1) to (2) range from 100:4 to 100:30.
Claim 15
Dependent Claim 21 words
An element according to claim 11 wherein a hydrogen atom on an aziridinyl carbon atom is substituted with a methyl group.
Claim 16
Dependent Claim 28 words
An element according to claim 11 wherein said conductive polymer (1) is copolymer of the sodium salt of styrene sulfonic acid and the disodium salt of maleic acid.
Claim 17
Dependent Claim 39 words
An element according to claim 15 wherein said adhesion agent is selected from the group consisting of urea, substituted ureas containing at least one --NH 2 group, substituted ureas containing at least two --NH groups, guanidine hydrochloride, and thiourea.
Claim 18
Dependent Claim 12 words
An element according to claim 16 wherein said adhesion agent is urea.
Claim 19
Dependent Claim 12 words
An element according to claim 16 wherein said adhesion agent is 2-imidazolidone.
Claim 20
Dependent Claim 12 words
An element according to claim 16 wherein said adhesion agent is thiourea.
Claim 21
Dependent Claim 24 words
An element according to claim 16 wherein said adhesion agent is present in the amount of 10-150 millimoles per 200 gm of gelatin present.
Claim 22
Dependent Claim 25 words
An element according to claim 16 wherein said auxiliary layer has a coating weight of about 35 mg/dm 2 to about 65 mg/dm 2 .

References Cited (Backward Citations)

US4571379A Cited
US4585730A Cited
US4859570A Cited
US4863801A Cited
US4891308A Cited
US4940655A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-07-07 1996-01-06 1996-07-07 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-07-07 2000-01-06 2000-07-07 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-07-07 2004-01-06 2004-07-07 $7700.00 Window Closed / Lapsed

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