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US5124833A Expired / Lapsed US ⏱️ 0.0 years remaining

Electrochromic system with less than 30 seconds switching time

Assignee: Saint Gobain Vitrage SA
•
Filing: 1990-07-11
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Granted: 1992-06-23
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Expires: 2010-07-11
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Abstract

Abstract The invention relates to an electrochromic glazing consisting of two glass sheets (1, 4) coated with first and second transparent electroconductive layers (2, 5), separated by a layer of an electrochromic material (9), an electrolyte (8) and a counterelectrode (7), said transparent electroconductive layers (2, 5) each being provided with an electroconductive strip (3, 6) parallel to the length of the glazing, made of a material whose electric conductivity is high relative to that of transparent electroconductive layers (2, 5). The electroconductive strips (3, 6) are placed along the opposite edges of the glazing and are connected to a voltage generator which applies in coloring phase (or in fading phase), between two points A and B on the electroconductive strips (3, 6) a potential difference U 1 =(V A -V B ) (t) so that between point A on the electroconductive strip on the first electroconductive layer and a point R on the second electroconductive layers, directly facing point A, there is a potential difference U 2 =(V A -V R ) (t)=U o , where U o is constant and chosen from the stability range of the coloring (or fading) reaction.

Inventors

  • 👤 James Barton
  • 👤 Francois Lerbet

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-29 19:02
CPC Classifications
G; G02; G02F; G02F1/00; G02F1/01; G02F1/15; B; B60; B60J; B60J3/00; B60J3/04; G02F1/163

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 183 words
An electrochromic system comprising of two glass sheets (1, 4) coated with first and second electroconductive layers (2, 5) separated by a layer of an electrochromic material (9), an electrolyte (8) and a counterelectrode (7), said electroconductive layers (2, 5) each being provided with an electroconductive strip (3, 6) made of a material whose electric conductivity is high relative to that of electroconductive layers (2, 5), said electroconductive strips (3, 6) being placed along the opposite edges of the electroconductive layers and connected to a voltage generator which applies in coloring phase (or in fading phase), between two points A and B on the first and second electroconductive layers, respectively, (2, 5) which are in the immediate vicinity of the electroconductive strips (3, 6) a potential difference U 1 =(V A -V B )(t) so that between point A and a point R on the second electroconductive layer, directly facing point A, there is a potential difference U 2 =(V A -V R )(t)=U o , where U o is constant and chosen from the stability range of the coloring (or fading) reaction.
Claim 2
Dependent Claim 183 words
An electrochromic system comprising of two glass sheets (1, 4) coated with first and second electroconductive layers (2, 5) separated by a layer of an electrochromic material (9), an electrolyte (8) and a counterelectrode (7), said electroconductive layers (2, 5) each being provided with an electroconductive strip (3, 6) made of a material whose electric conductivity is high relative to that of electroconductive layers (2, 5), said electroconductive strips (3, 6) being placed along the opposite edges of the electroconductive layers and connected to a voltage generator which applies in coloring phase (or in fading phase), between two points A and B on the first and second electroconductive layers, respectively, (2, 5) which are in the immediate vicinity of the electroconductive strips (3, 6) a potential difference U 1 =(V A -V B )(t) so that between point A and a point R on the second electroconductive layer, directly facing point A, there is a potential difference U 2 =(V A -V R )(t)=U o , where U o is constant and chosen from the stability range of the coloring (or fading) reaction.
Claim 3
Dependent Claim 15 words
An electrochromic system according to claim 1 wherein electroconductive strips (3, 6) are of copper.
Claim 4
Dependent Claim 24 words
An electrochromic system according to claim 1 wherein the layer of an electrochromic material (9) comprises a cathode electrochromic material such as tungsten trioxide.
Claim 5
Dependent Claim 19 words
An electrochromic system according to claim 1, wherein counterelectrode (7) comprises an anode electrochromic material such as iridium oxide.
Claim 6
Dependent Claim 16 words
An electrochromic system according to claim 1, wherein electrolyte (8) is an electrolyte with proton conduction.
Claim 7
Dependent Claim 30 words
An electrochromic system according to claim 5 wherein electrolyte (8) with proton conduction is a polymer complex consisting of a film of poly(ethylene oxide) with evenly dispersed anhydrous orthophosphoric acid.
Claim 8
Dependent Claim 18 words
An electrochromic system according to claim 1 wherein electrolyte (8) is an electrolyte with ion conduction in lithium.
Claim 9
Dependent Claim 25 words
An electrochromic system according to claim 1 wherein the potential difference U 1 to be applied at time t is determined previously by voltammetric recordings.
Claim 10
Dependent Claim 20 words
An electrochromic system according to claim 1 wherein the potential difference U 1 =f(t) is approximated by an exponential function.
Claim 11
Dependent Claim 58 words
An electrochromic system according to claim 1 further comprising a third electroconductive strip (6') on the second electroconductive layer in the immediate vicinity of point R and wherein the potential difference U 1 is applied so that voltage U 2 is constant between the electroconductive strip (3) on the first electroconductive layer and said third electroconductive strip (6').
Claim 12
Dependent Claim 46 words
An electrochromic system according to claim 10 wherein the electroconductive strips (6, 6') on the second electroconductive layer are connected to a voltage generator for applying a potential difference U 3 , which is used for heating the cell when applied voltage U 2 is zero.
Claim 13
Dependent Claim 14 words
An electrochromic system according to claim 11 wherein the difference U 3 is alternating.
Claim 14
Dependent Claim 22 words
An electrochromic system according to claim 12 wherein U 3 is equivalent to 0.5 volt per centimeter of distance between the electrodes.
Claim 15
Dependent Claim 273 words
An electrochromic system comprising: two rectangular and parallel sheets of chemically inert transparent material where the north edge and south edge of the sheets are greater than or of equal length to the east and west edges of the sheets; first and second electroconductive layers coating the inner faces of the two transparent sheets and separated by: a layer of an electrochemical material; an electrolyte; and a counterelectrode; a first electroconductive strip made of a material whose electrical conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the first electroconductive layer; a second electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the south edge of the second electroconductive layer; a third electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the second electroconductive layer; and a voltage generator which applies in coloring phase (or in fading phase), between two points A and B associated with the first and second electroconductive strips, respectively, a potential difference U 1 =(V A -V B ) (t) so that between point A and a point R associated with the third electroconductive strip, point R directly facing point A, there is a potential difference U 2 =(V A -V R )(t)=U o , where U o is constant and chosen from the stability range of the coloring (or fading) reaction.
Claim 16
Dependent Claim 273 words
An electrochromic system comprising: two rectangular and parallel sheets of chemically inert transparent material where the north edge and south edge of the sheets are greater than or of equal length to the east and west edges of the sheets; first and second electroconductive layers coating the inner faces of the two transparent sheets and separated by: a layer of an electrochemical material; an electrolyte; and a counterelectrode; a first electroconductive strip made of a material whose electrical conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the first electroconductive layer; a second electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the south edge of the second electroconductive layer; a third electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the second electroconductive layer; and a voltage generator which applies in coloring phase (or in fading phase), between two points A and B associated with the first and second electroconductive strips, respectively, a potential difference U 1 =(V A -V B ) (t) so that between point A and a point R associated with the third electroconductive strip, point R directly facing point A, there is a potential difference U 2 =(V A -V R )(t)=U o , where U o is constant and chosen from the stability range of the coloring (or fading) reaction.
Claim 17
Independent Claim 270 words
A method of varying light transmission in an electrochromic system comprising: employing an electrochromic system comprising two rectangular and parallel sheets of chemically inert transparent material where the north edge and south edge of the sheets are greater than or of equal length to the east and west edges of the sheets, first and second electroconductive layers coating the inner faces of the two transparent sheets, and separated by a layer of an electrochromic material, an electrolyte, and a counterelectrode, a first electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the first electroconductive layer, a second electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the south edge of the second electroconductive layer, and a third electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the second electroconductive layer; applying a potential difference, between points A and B associated with the first and second electroconductive strips, respectively, equal to U 1 =(V A -V B ) (t); and maintaining a potential difference, between points A and R, point R associated with the third electroconductive strips, equal to U 2 =(V A -V R )(t)=U o , where U o is a constant and chosen from the stability range of the coloring (or fading) reaction.
Claim 18
Independent Claim 270 words
A method of varying light transmission in an electrochromic system comprising: employing an electrochromic system comprising two rectangular and parallel sheets of chemically inert transparent material where the north edge and south edge of the sheets are greater than or of equal length to the east and west edges of the sheets, first and second electroconductive layers coating the inner faces of the two transparent sheets, and separated by a layer of an electrochromic material, an electrolyte, and a counterelectrode, a first electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the first electroconductive layer, a second electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the south edge of the second electroconductive layer, and a third electroconductive strip made of a material whose electric conductivity is high relative to that of the first and second electroconductive layers and connected along the entire length of the north edge of the second electroconductive layer; applying a potential difference, between points A and B associated with the first and second electroconductive strips, respectively, equal to U 1 =(V A -V B ) (t); and maintaining a potential difference, between points A and R, point R associated with the third electroconductive strips, equal to U 2 =(V A -V R )(t)=U o , where U o is a constant and chosen from the stability range of the coloring (or fading) reaction.
Claim 19
Dependent Claim 24 words
The method according to claim 15 wherein the potential difference U 1 to be applied at time t is determined previously by voltammetric recordings.
Claim 20
Dependent Claim 19 words
The method according to claim 15 wherein the potential difference U 1 =f(t) is approximated by an exponential function.
Claim 21
Dependent Claim 46 words
The method according to claim 15 wherein the second and third electroconductive strips on the second electroconductive layer are connected to a voltage generator for applying a potential difference U 3 , which is used for heating the cell when applied voltage U 2 is zero.
Claim 22
Dependent Claim 14 words
The method according to claim 18 wherein the potential difference U 3 is alternating.
Claim 23
Dependent Claim 25 words
The method according to claim 18 wherein U 3 is equivalent to 0.5 volts per centimeter of distance between the second and third electroconductive strips.

References Cited (Backward Citations)

US4346964A Cited
US4902110A Cited
US4801195A Cited
US4807977A Cited
US4844591A Cited
US4824221A Cited
US4927246A Cited
US4865428A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-06-23 1995-12-23 1996-06-23 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-06-23 1999-12-23 2000-06-23 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-06-23 2003-12-23 2004-06-23 $7700.00 Window Closed / Lapsed

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