Color toner containing organic pigment and process for producing the same

Claim 2

A color toner, comprising a binder resin and a colorant wherein said binder resin having been produced by suspension-polymerizing a monomer composition comprising a polymerizable monomer and the colorant, wherein the colorant comprises organic pigment particles having an --OH group, said particles having been treated with an isocyanic ester or a silicon-containing compound to enhance dispersibility of said organic pigment particles in the polymerizable monomer without inhibiting the suspension polymerization reaction.

Claim 3

A color toner according to claim 1, wherein the isocyanic ester comprises a compound represented by a formula: R--N═C═O, wherein R is selected from the group consisting of (i) an alkyl group having 1-20 carbon atoms and containing no active hydrogen, (ii) an alkenyl group, (iii) an alkyl group having 1-20 carbon atoms containing no active hydrogen and containing at least one species selected from the group consisting of N, S, O and halogen atom, (iv) an alkenyl group containing no active hydrogen and containing at least one species selected from the group consisting of N, S, O and halogen atom and (v) an aryl group.

Claim 4

A color toner according to claim 1, wherein the silicon-containing compound comprises at least one species selected from the group consisting of: γ-(2)-aminoethyl)aminopropyltrimethoxysilane, γ-aminopropyltriethoxysilane, γ-(2-aminoethyl)aminopropylmethyldimethoxysilane, γ-methacryloxypropyltrimethoxysilane, γ-glycidoxypropyltrimethoxysilane, methyltrimethoxysilane, ethyltriethoxysilane, γ-anilinopropyltrimethoxysilane, vinyltrimethoxysilane, and γ-chloropropylmethyldimethoxysilane.

Claim 5

A color toner according to claim 1, wherein the silicon-containing compound comprises a silicone compound represented by the following formula [I]: (R.sub.1 HSiO).sub.a (R.sub.2 R.sub.3 SiO).sub.b (R.sub.4 R.sub.5 R.sub.6 SiO.sub.1/2).sub.c [I], wherein R 1 , R 2 and R 3 respectively are the same or different groups each of which is a hydrogen atom or a hydrocarbon group having 1-10 carbon atoms and being capable of having a substituent of a halogen atom, provided that all of R 1 , R 2 and R 3 are not hydrogen atoms simultaneously; R 4 , R 5 and R 6 respectively are the same or different groups each of which is a hydrogen atom or a hydrocarbon group having 1-10 carbon atoms and being capable of having a substituent of a halogen atom; a is zero or an integer of 1 or larger; b is zero or an integer of 1 or larger; c is zero or an integer of 2, provided that the sum of (a+b) is an integer of 3 or larger in a case where C═O.

Claim 6

A color toner according to claim 4, wherein the silicon-containing compound comprises a compound represented by the following formula [II] or [III]: (R.sub.1 HSiO).sub.a (R.sub.2 R.sub.3 SiO).sub.b [II], wherein R 1 , R 2 and R 3 respectively are each an aryl group or lower alkyl group having 1-4 carbon atoms and being capable of having a substituent of a halogen atom, and the sum of (a+b) is 3 to 7; or (R.sub.1 HSiO).sub.a (R.sub.2 R.sub.3 SiO).sub.b (R.sub.4 R.sub.5 R.sub.6 SiO.sub.1/2).sub.2 [III], wherein R 1 to R 6 respectively are each an aryl group or lower alkyl group having 1-4 carbon atoms and being capable of having a substituent of a halogen atom, and the sum of (a+b) is 2 to 5.

Claim 7

A color toner according to claim 5, wherein the silicon-containing compound comprises a compound represented by a formula: ##STR10## wherein n denotes an integer of 3 to 7.

Claim 8

A color toner according to claim 5, wherein the silicon-containing compound comprises a compound represented by a formula: ##STR11## wherein n denotes an integer of 3 to 7.

Claim 9

A color toner according to claim 5, wherein the silicon-containing compound comprises a compound represented by a formula: ##STR12## wherein the sum of (a+b) denotes an integer of 3 to 7.

Claim 10

A color toner according to claim 5, wherein the silicon compound comprises a cyclic silicone compound selected from the group consisting of: dihydrogenhexamethylcyclotetrasiloxane, trihydrogenpentamethylcyclotetrasiloxane, tetrahydrogentetramethylcyclotetrasiloxane, dihydrogenoctamethylcyclopentasiloxane, trihydrogenheptamethylcyclopentasiloxane, tetrahydrogenhexamethylcyclopentasiloxane, and pentahydrogenpentamethylcyclopentasiloxane.

Claim 11

A color toner according to claim 5, wherein the silicon compound comprises a linear silicone compound selected from the group consisting of: 1,1,1,2,3,4,4,4-octamethyltetrasiloxane, 1,1,1,2,3,4,5,5,5-nonamethylpentasiloxane, and 1,1,1,2,3,4,5,6,6,6-decamethylhexasiloxane.

Claim 12

A color toner according to claim 1, wherein 0.5-50 wt. parts of the isocyanic ester has been used for the treatment with respect to 10 wt. parts of the organic pigment particles.

Claim 13

A color toner according to claim 1, wherein 0.005-50 wt. parts of the silicon-containing compound has been used for the treatment on the basis of the weight of the organic pigment particles.

Claim 14

A color toner according to claim 1, wherein the organic pigment particles have been treated with an isocyanic ester or a silicon-containing compound, after oxidation treatment thereof.

Claim 15

A color toner according to claim 13, wherein the organic pigment particles have been oxidation-treated so as to provide an --OH group on their surfaces.

Claim 16

A color toner according to claim 1, wherein the organic pigment particles have an --OH group, and have been treated with the isocyanic ester or silicon-containing compound so that the --OH group reacts with the isocyanic ester or silicon-containing compound.

Claim 17

A color toner according to claim 1, wherein the organic pigment particles have been treated so that their surfaces are oxidized to provide an --OH group thereon, and further treated with the isocyanic ester or silicon-containing compound so that the --OH group reacts with the isocyanic ester or silicon-containing compound.

Claim 18

A color toner according to claim 1, which contains 0.1-50 wt. parts of the organic pigment particles per 100 wt. parts of the binder resin.

Claim 19

A color toner according to claim 1, which contains 0.5-25 wt. parts of the organic pigment particles per 100 wt. parts of the binder resin.