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US5114514A Expired / Lapsed US ⏱️ 0.0 years remaining

Bonding of thermoplastic sheet material to roughened substrates

Assignee: Avery Dennison Corp
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Filing: 1990-05-30
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Granted: 1992-05-19
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Expires: 2010-05-30
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Abstract

Abstract A protective and decorative sheet material, such as a paint-coated film, which is bonded by an adhesive layer and vacuum thermoforming to a substrate, can develop surface roughness when exposed to heat for extended periods of time. This defect is unexpectedly reduced or eliminated by raising the surface energy of the substrate and roughening the surface of the substrate within certain limits, prior to application of the sheet material.

Inventors

  • 👤 Newton C. M. Landis

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-24 13:34
CPC Classifications
B; B32; B32B; B32B37/00; B32B37/14; B32B37/144; B29; B29C; B29C63/00; B29C63/48; B29C65/00; B29C65/48; B29C65/4805; B29C65/481; B29C65/4825; B29C66/00; B29C66/01; B29C66/02; B29C66/022; B29C66/0224; B29C66/02245; B29C66/026; B29C66/05; B29C66/10; B29C66/11; B29C66/112; B29C66/1122; B29C66/40; B29C66/41; B29C66/45; B29C66/70; B29C66/72; B29C66/723; B29C66/73; B29C66/731; B29C66/7316; B29C66/73161; B29C66/739; B29C66/7392; B32B38/00; B32B38/0012; C; C09; C09J; C09J5/00; B29C65/02; B29C65/10; B29C65/14; B29C65/1403; B29C65/1406; B29C65/1412; B29C66/71; B29C66/7232; B29C66/72321; B29C66/72322; B29C66/72323; B29C66/72324; B29C66/72325; B29C66/72326; B29C66/73921; B29K; B29K2995/00; B29K2995/0037; B29K2995/0072; Y; Y10; Y10T; Y10T156/00; Y10T156/10; Y10T156/1002; Y10T156/1028; Y10T428/00; Y10T428/14; Y10T428/1462; Y10T428/31

Claims Analysis

Total Claims: 15
Claim 1
Independent Claim 178 words
A process for adhesively bonding a protective and decorative, stretchable, thermoplastic polymeric film to a substrate, wherein said process reduces or eliminates the tendency of the bonded polymeric film to develop an undesirable surface texture, said process comprising the steps of: (a) applying a layer of a pressure-sensitive adhesive composition to a surface of said film; (b) treating a surface of the substrate which is to be bonded to said film to roughen the surface and to raise its surface energy to a level corresponding to a critical surface tension of wetting of at least about 40 dynes per cm and to provide a substantially uniform surface roughness; and (c) pressing the adhesive layer of said film into bonding contact with the treated surface of the substrate, wherein the roughness of the roughened surface ranges from about 1 to about 100 microinches, and the surface being sufficiently smooth such that said film when bonded thereto has a 20° glass of at least about 80 and a DOI of at least about 80 as measured by ASTM TEST E-430.
Claim 2
Dependent Claim 178 words
A process for adhesively bonding a protective and decorative, stretchable, thermoplastic polymeric film to a substrate, wherein said process reduces or eliminates the tendency of the bonded polymeric film to develop an undesirable surface texture, said process comprising the steps of: (a) applying a layer of a pressure-sensitive adhesive composition to a surface of said film; (b) treating a surface of the substrate which is to be bonded to said film to roughen the surface and to raise its surface energy to a level corresponding to a critical surface tension of wetting of at least about 40 dynes per cm and to provide a substantially uniform surface roughness; and (c) pressing the adhesive layer of said film into bonding contact with the treated surface of the substrate, wherein the roughness of the roughened surface ranges from about 1 to about 100 microinches, and the surface being sufficiently smooth such that said film when bonded thereto has a 20° glass of at least about 80 and a DOI of at least about 80 as measured by ASTM TEST E-430.
Claim 3
Dependent Claim 14 words
The process of claim 1 wherein the substrate is an exterior automobile body panel.
Claim 4
Dependent Claim 51 words
The process of claim 1 wherein said film comprises a thermoplastic carrier film, a protective and decorative layer adhered to one surface of said carrier film, a pressure-sensitive adhesive layer on the opposite side from said protective and decorative layer, and a clear topcoat layer overlying said protective and decorative layer.
Claim 5
Dependent Claim 16 words
The process of claim 3 wherein said film is bonded to the substrate by vacuum thermoforming.
Claim 6
Dependent Claim 15 words
The process of claim 3 wherein the protective and decorative layer is a paint layer.
Claim 7
Dependent Claim 13 words
The process of claim 1 wherein the pressure-sensitive adhesive comprises an acrylic composition.
Claim 8
Dependent Claim 14 words
The process of claim 1 wherein the substrate has an unprimed, roughened metal surface.
Claim 9
Dependent Claim 17 words
The process of claim 1 wherein the substrate is a metal having a roughened pigmented surface coat.
Claim 10
Dependent Claim 17 words
The process of claim 1 wherein the substrate is a plastic having a roughened pigmented surface coat.
Claim 11
Dependent Claim 14 words
The process of claim 8 wherein the surface coat has been roughened by sandpaper.
Claim 12
Dependent Claim 14 words
The process of claim 8 wherein the surface coat has been roughened by sandblasting.
Claim 13
Dependent Claim 17 words
The process of claim 1 wherein the sheet material is bonded to the substrate surface by thermoforming.
Claim 14
Dependent Claim 18 words
The process of claim 1 wherein the sheet material is bonded to the substrate surface by physical pressure.
Claim 15
Dependent Claim 15 words
The process of claim 1 wherein the sheet material is a toning and styling film.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-05-19 1995-11-18 1996-05-19 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-05-19 1999-11-18 2000-05-19 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-05-19 2003-11-18 2004-05-19 $7700.00 Window Closed / Lapsed

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