Patent US5100589A successfully refreshed from Google Patents.
← Back to Patent Explorer
US5100589A Expired / Lapsed US ⏱️ 0.0 years remaining

Optical method for altering molecular alignment in selected regions of a non-linear optical polymeric structure

Assignee: Lockheed Martin Corp
•
Filing: 1989-12-04
•
Granted: 1992-03-31
•
Expires: 2009-12-04
📄 Original PDF 🌐 Google Patents 🔄 Sync Now

Abstract

Abstract A channel waveguide is integrally formed within a structure made of a non-linear optical polymer by focussing a beam of optical radiation into a specified region within the structure where the channel waveguide is to be located. The focussed beam of optical radiation raises the temperature of the polymer in the specified region to above the glass-transition temperature for the polymer. A poling electric field is applied to the structure to cause molecular alignment of the polymer to occur in the specified region of the structure. Then the beam of optical radiation is removed while the poling electric field is maintained, thereby maintaining molecular alignment of the polymer in the specified region as the temperature of the specified region falls below the glass-transition temperature. A change in index of refraction of the polymer in the specified region of the structure due to the molecular alignment of the polymer in the specified region enables the specified region to function as a channel waveguide.

Inventors

  • 👤 Anthony J. Ticknor

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-02 20:33
CPC Classifications
G; G02; G02B; G02B6/00; G02B6/10; G02B6/12; G02B6/13; G02F; G02F1/00; G02F1/01; G02F1/061; G02F1/065

Claims Analysis

Total Claims: 31
Claim 1
Independent Claim 296 words
A method of forming an optically refractive element at a specified depth within a polymeric structure made of a non-linear optical polymer, said method comprising the steps of: (a) focussing optical radiation into a specified region at said specified depth within said polymeric structure according to a pattern that defines a desired configuration for said optically refractive element, said optical radiation having a frequency that is strongly absorbed by said polymer, said optical radiation that is focussed into said specified region thereby heating said polymer in said specified region within polymeric structure to a temperature above glass-transition temperature for said polymer, said polymer outside said specified region of said polymeric structure remaining at a temperature below glass-transition temperature for said polymer; (b) applying an electric field to said polymeric structure to induce poling of said heated polymer in said specified region in which the temperature of said polymer has been raised above glass-transition temperature, said poling of said polymer in said specified region within said polymeric structure thereby causing said polymer in said specified region to have a higher index of refraction than said polymer in an adjacent region of said polymeric structure outside said specified region; and (c) removing said focussed optical radiation from said specified region within said polymeric structure while continuing to apply said electric field to said polymeric structure so that poling of said polymer in said specified region within said polymeric structure is thereby maintained until after said specified region has been cooled to a temperature below glass-transition temperature for said polymer, said specified region within said polymeric structure thereby retaining said higher index of refraction while leaving said polymeric structure dimensionally substantially unchanged, whereby said specified region at said specified depth within said polymeric structure becomes said optically refractive element.
Claim 2
Independent Claim 296 words
A method of forming an optically refractive element at a specified depth within a polymeric structure made of a non-linear optical polymer, said method comprising the steps of: (a) focussing optical radiation into a specified region at said specified depth within said polymeric structure according to a pattern that defines a desired configuration for said optically refractive element, said optical radiation having a frequency that is strongly absorbed by said polymer, said optical radiation that is focussed into said specified region thereby heating said polymer in said specified region within polymeric structure to a temperature above glass-transition temperature for said polymer, said polymer outside said specified region of said polymeric structure remaining at a temperature below glass-transition temperature for said polymer; (b) applying an electric field to said polymeric structure to induce poling of said heated polymer in said specified region in which the temperature of said polymer has been raised above glass-transition temperature, said poling of said polymer in said specified region within said polymeric structure thereby causing said polymer in said specified region to have a higher index of refraction than said polymer in an adjacent region of said polymeric structure outside said specified region; and (c) removing said focussed optical radiation from said specified region within said polymeric structure while continuing to apply said electric field to said polymeric structure so that poling of said polymer in said specified region within said polymeric structure is thereby maintained until after said specified region has been cooled to a temperature below glass-transition temperature for said polymer, said specified region within said polymeric structure thereby retaining said higher index of refraction while leaving said polymeric structure dimensionally substantially unchanged, whereby said specified region at said specified depth within said polymeric structure becomes said optically refractive element.
Claim 3
Dependent Claim 39 words
The method of claim 1 wherein the step of focussing optical radiation into said specified region within said structure comprises focussing a directed beam of said optical radiation through lens means to a focal surface in said specified region.
Claim 4
Dependent Claim 16 words
The method of claim 2 wherein said directed beam of optical radiation is a laser beam.
Claim 5
Dependent Claim 14 words
The method of claim 2 wherein said directed beam of optical radiation is pulsed.
Claim 6
Dependent Claim 21 words
The method of claim 2 wherein said directed beam of optical radiation is scanned along said specified region within said structure.
Claim 7
Dependent Claim 35 words
The method of claim 1 wherein the step of applying said electric field to said structure comprises applying a difference of electrical potential between a pair of electrodes disposed on opposite sides of said structure.
Claim 8
Dependent Claim 41 words
The method of claim 6 wherein a first electrode of said pair is substantially transparent to said optical radiation, a substantial portion of said optical radiation passing through said first electrode in being focussed into said specified region within said structure.
Claim 9
Dependent Claim 24 words
The method of claim 1 wherein the step of applying said electric field to said structure comprises producing an electrical corona adjacent said structure.
Claim 10
Independent Claim 289 words
A method of selectively altering molecular alignment in a specified region at a specified depth within a polymeric structure consisting essentially of a non-linear optical polymer, said method comprising the steps of: (a) focussing optical radiation into said specified region at said specified depth, said optical radiation having a frequency that is strongly absorbed by said polymer, said optical radiation focussed into said specified region thereby heating said polymer in said specified region to a temperature above glass-transition temperature for said polymer, said polymer outside said specified region remaining at a temperature below glass-transition temperature for said polymer; (b) applying an electric field to said polymeric structure to induce poling of said heated polymer in said specified region in which the temperature of said polymer has been raised above glass-transition temperature, said poling of said polymer in said specified region within said polymeric structure thereby causing said polymer in said specified region to have a higher index of refraction than said polymer in an adjacent region of said polymeric structure outside said specified region, said polymer in said adjacent region of said polymeric structure outside said specified region remaining unpoled; and (c) removing said focussed optical radiation from said specified region within said polymeric structure while continuing to apply said electric field to said polymeric structure so that poling of said polymer in said specified region within said polymeric structure is thereby maintained until after said specified region has been cooled to a temperature below glass-transition temperature for said polymer, said specified region within said polymeric structure thereby retaining said higher index of refraction, molecular alignment in said specified region at said specified depth within said polymeric structure thus being altered while leaving said polymeric structure dimensionally substantially unchanged.
Claim 11
Independent Claim 289 words
A method of selectively altering molecular alignment in a specified region at a specified depth within a polymeric structure consisting essentially of a non-linear optical polymer, said method comprising the steps of: (a) focussing optical radiation into said specified region at said specified depth, said optical radiation having a frequency that is strongly absorbed by said polymer, said optical radiation focussed into said specified region thereby heating said polymer in said specified region to a temperature above glass-transition temperature for said polymer, said polymer outside said specified region remaining at a temperature below glass-transition temperature for said polymer; (b) applying an electric field to said polymeric structure to induce poling of said heated polymer in said specified region in which the temperature of said polymer has been raised above glass-transition temperature, said poling of said polymer in said specified region within said polymeric structure thereby causing said polymer in said specified region to have a higher index of refraction than said polymer in an adjacent region of said polymeric structure outside said specified region, said polymer in said adjacent region of said polymeric structure outside said specified region remaining unpoled; and (c) removing said focussed optical radiation from said specified region within said polymeric structure while continuing to apply said electric field to said polymeric structure so that poling of said polymer in said specified region within said polymeric structure is thereby maintained until after said specified region has been cooled to a temperature below glass-transition temperature for said polymer, said specified region within said polymeric structure thereby retaining said higher index of refraction, molecular alignment in said specified region at said specified depth within said polymeric structure thus being altered while leaving said polymeric structure dimensionally substantially unchanged.
Claim 12
Dependent Claim 27 words
The method of claim 9 wherein molecular alignment in said specified region within said structure is altered from a generally poled state to a generally random state.
Claim 13
Dependent Claim 27 words
The method of claim 9 wherein molecular alignment in said specified region within said structure is altered from a generally random state to a generally poled state.
Claim 14
Dependent Claim 37 words
The method of claim 9 wherein the step of focussing optical radiation into said specified region within said structure comprises focussing a directed beam of optical radiation through lens means to a focal surface within said structure.
Claim 15
Dependent Claim 16 words
The method of claim 12 wherein said directed beam of optical radiation is a laser beam.
Claim 16
Dependent Claim 14 words
The method of claim 12 wherein said directed beam of optical radiation is pulsed.
Claim 17
Dependent Claim 21 words
The method of claim 12 wherein said directed beam of optical radiation is scanned along said specified region within said structure.
Claim 18
Dependent Claim 35 words
The method of claim 9 wherein the step of applying said electric field to said structure comprises applying a difference of electrical potential between a pair of electrodes disposed on opposite sides of said structure.
Claim 19
Dependent Claim 41 words
The method of claim 16 wherein a first electrode of said pair is substantially transparent to said optical radiation, a substantial portion of said optical radiation passing through said first electrode in being focussed into said specified region within said structure.
Claim 20
Dependent Claim 27 words
The method of claim 9 wherein the step of applying said electric field to said structure comprises producing an electrical corona adjacent a surface of said structure.
Claim 21
Independent Claim 312 words
An apparatus for forming an optically refractive element at a specified depth within a polymeric structure made of a non-linear optical polymer, said apparatus comprising: (a) means for focussing optical radiation into a specified region at said specified depth within said polymeric structure according to a pattern that defines a desired configuration for said optically refractive element, said optical radiation having a frequency that is strongly absorbed by said polymer so that said optical radiation when focussed into said specified region thereby heats said polymer in said specified region to a temperature above glass-transition temperature for said polymer, said polymer outside said specified region of said polymeric structure remaining at a temperature below glass-transition temperature for said polymer; (b) means for applying an electric field to said polymeric structure to induce poling of said heated polymer in said specified region in which the temperature of said polymer has been raised above glass-transition temperature, said poling of said polymer in said specified region within said polymeric structure thereby causing said polymer in said specified region to have a higher index of reaction than said polymer in an adjacent region of said polymeric structure outside said specified region, said polymer in said adjacent region of said polymeric structure outside said specified region remaining unpoled; and (c) means for removing said focussed optical radiation from said specified region within said polymeric structure while said electric field continues to be applied to said polymeric structure so that poling of said polymer in said specified region of said polymeric structure is thereby maintained until after said specified region has been cooled to a temperature below glass-transition temperature for said polymer, said specified region within said polymeric structure thereby retaining said higher index of refraction while leaving said polymeric structure dimensionally substantially unchanged, said optically refractive element thereby being formed in said specified region within said polymeric structure.
Claim 22
Independent Claim 312 words
An apparatus for forming an optically refractive element at a specified depth within a polymeric structure made of a non-linear optical polymer, said apparatus comprising: (a) means for focussing optical radiation into a specified region at said specified depth within said polymeric structure according to a pattern that defines a desired configuration for said optically refractive element, said optical radiation having a frequency that is strongly absorbed by said polymer so that said optical radiation when focussed into said specified region thereby heats said polymer in said specified region to a temperature above glass-transition temperature for said polymer, said polymer outside said specified region of said polymeric structure remaining at a temperature below glass-transition temperature for said polymer; (b) means for applying an electric field to said polymeric structure to induce poling of said heated polymer in said specified region in which the temperature of said polymer has been raised above glass-transition temperature, said poling of said polymer in said specified region within said polymeric structure thereby causing said polymer in said specified region to have a higher index of reaction than said polymer in an adjacent region of said polymeric structure outside said specified region, said polymer in said adjacent region of said polymeric structure outside said specified region remaining unpoled; and (c) means for removing said focussed optical radiation from said specified region within said polymeric structure while said electric field continues to be applied to said polymeric structure so that poling of said polymer in said specified region of said polymeric structure is thereby maintained until after said specified region has been cooled to a temperature below glass-transition temperature for said polymer, said specified region within said polymeric structure thereby retaining said higher index of refraction while leaving said polymeric structure dimensionally substantially unchanged, said optically refractive element thereby being formed in said specified region within said polymeric structure.
Claim 23
Dependent Claim 42 words
The apparatus of claim 19 wherein said means for focussing said optical radiation into said specified region within said structure comprises means for focussing a directed beam of said optical radiation through lens means to a focal surface in said specified region.
Claim 24
Dependent Claim 67 words
The apparatus of claim 20 wherein said lens means comprises an anamorphic lens positionable adjacent said structure, said anamorphic lens serving to focus said optical radiation so as to produce a rise in temperature of said polymer in said specified region to above glass-transition temperature for said polymer, said anamorphic lens having a configuration corresponding to said pattern defining said desired configuration for said optically refractive element.
Claim 25
Dependent Claim 18 words
The apparatus of claim 20 further comprising a laser device for providing said directed beam of optical radiation.
Claim 26
Dependent Claim 24 words
The apparatus of claim 20 further comprising means for scanning said directed beam of optical radiation on said focal surface in said specified region.
Claim 27
Dependent Claim 35 words
The apparatus of claim 20 further comprising means for scanning said directed beam of optical radiation along said anamorphic lens in order to focus said optical radiation into said specified region according to said pattern.
Claim 28
Dependent Claim 14 words
The apparatus of claim 21 wherein said anamorphic lens comprises an elongate cylindrical lens.
Claim 29
Dependent Claim 28 words
The apparatus of claim 19 wherein said means for applying said electric field to said structure comprises a pair of electrodes positionable on opposite sides of said structure.
Claim 30
Dependent Claim 43 words
The apparatus of claim 19 wherein a first electrode of said pair is substantially transparent to said optical radiation, whereby a substantial portion of said optical radiation can pass through said first electrode in being focussed into said specified region within said structure.
Claim 31
Dependent Claim 26 words
The apparatus of claim 19 wherein said means for applying said electric field to said structure comprises means for producing an electrical corona adjacent said structure.

References Cited (Backward Citations)

US3170008A Cited
US3665206A Cited
US4673241A Cited
US4582655A Cited
US4711514A Cited
US4859876A Cited
US4822682A Cited
US4886538A Cited
US4792208A Cited
US4796971A Cited
US4925263A Cited
US4909598A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-03-31 1995-09-30 1996-03-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-03-31 1999-09-30 2000-03-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-03-31 2003-09-30 2004-03-31 $7700.00 Window Closed / Lapsed

Assigned Categories & Tags

No categories assigned to this patent yet.

Assign Category Tag