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US5100587A Expired / Lapsed US ⏱️ 0.0 years remaining

Solid-state radioluminescent zeolite-containing composition and light sources

Assignee: United States Department of Energy
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Filing: 1990-12-27
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Granted: 1992-03-31
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Expires: 2010-12-27
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Abstract

Abstract A new type of RL light source consisting of a zeolite crystalline material, the intralattice spaces of which a tritiated compound and a luminophore are sorbed, and which material is optionally further dispersed in a refractive index-matched polymer matrix.

Inventors

  • 👤 Roger L. Clough
  • 👤 John T. Gill
  • 👤 Daniel B. Hawkins
  • 👤 Clifford L. Renschler
  • 👤 Timothy J. Shepodd
  • 👤 Henry M. Smith

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-11-07 12:04
CPC Classifications
C; C09; C09K; C09K11/00; C09K11/06; C09K11/04; Y; Y10; Y10S; Y10S423/00; Y10S423/07

Claims Analysis

Total Claims: 11
Claim 1
Independent Claim 40 words
A solid state radioluminescent composition or light source, comprising: an optically clear polymer matrix, having a crystalline zeolite material, into the crystalline intralattice spaces thereof which have been sorbed at least one tritium containing compound and at least one luminophore.
Claim 2
Dependent Claim 40 words
A solid state radioluminescent composition or light source, comprising: an optically clear polymer matrix, having a crystalline zeolite material, into the crystalline intralattice spaces thereof which have been sorbed at least one tritium containing compound and at least one luminophore.
Claim 3
Dependent Claim 28 words
A solid state radioluminescent composition or light source, comprising a crystalline zeolite material having at least one tritium-containing compound and at least one luminophore occupying its intralattice spaces.
Claim 4
Dependent Claim 28 words
A solid state radioluminescent composition or light source, comprising a crystalline zeolite material having at least one tritium-containing compound and at least one luminophore occupying its intralattice spaces.
Claim 5
Dependent Claim 78 words
The light source of claim 2, wherein (a) the tritium-containing compound is selected from the group consisting of T + , T 2 O, CT 4 , NT 3 , NT 4 + , and trittiated organics and tritiated organometallics capable of being loaded in the zeolite lattice spaces, and (b) the luminophore is selected from the group consisting of rare metal ions, copper ions, and luminescent organic compounds capable of being sorbed in the zeolite lattice spaces.
Claim 6
Dependent Claim 25 words
The light source of claim 2, wherein tritium-exchanged 3-hydroxyflavone occupies the intralattice spaces, said flavone being a molecule which contains tritium and is a luminophore.
Claim 7
Dependent Claim 23 words
The light source of claim 3, wherein the luminophore is selected from the group consisting of ions of europium, terbium, neodymium, and copper.
Claim 8
Dependent Claim 42 words
The light source of claim 2, wherein the composition is present within an organic or silica polymer matrix, in which matrix the zeolite is insoluble but which matrix possesses a refractive index within 0.05 units of that of the crystalline zeolite material.
Claim 9
Dependent Claim 21 words
The light source of claim 2, wherein the crystalline zeolite material consists of large crystallites with dimensions greater than 1 mm.
Claim 10
Dependent Claim 24 words
The light source of claim 6, wherein the matrix is an organic polymer and the composition is present within a solvent for coating applications.
Claim 11
Dependent Claim 19 words
The light source of claim 6, wherein the matrix consists of two-part organic thermosetting polymer precursors for coating applications.

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-03-31 1995-09-30 1996-03-31 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-03-31 1999-09-30 2000-03-31 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-03-31 2003-09-30 2004-03-31 $7700.00 Window Closed / Lapsed

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