US5096468A
Expired / Lapsed
US
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Cellulose acetate butyrate gas separation membranes
Assignee: WR Grace and Co Conn
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Filing: 1990-06-29
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Granted: 1992-03-17
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Expires: 2010-06-29
Abstract
Abstract High performance cellulose acetate butyrate gas separation membranes are prepared from a casting solution containing from about 10 to 30 percent polymer, 35 to 70 percent solvent, and 15 to 30 percent pore-forming agents. A film casting solution is cast onto a substantially flat support surface and a dense layer is formed on the exposed film surface. The film is gelled, washed, and dried to produce a particularly useful gas separation membrane. The cellulose acetate polymers used in this preparation have molecular weights of at least about 20,000, and have about 10 to about 45% butyryl groups, about 2 to about 35% acetyl groups, and about 0.8 to about 2 percent hydroxyl groups, by weight. The membranes may be used for separating a feed gas into a permeate fraction and a residual fraction, and are particularly useful for separating gases in the purge gas stream of ammonia plants to recover a permeate which is relatively rich in hydrogen. Cellulose acetate butyrate membranes may be used to improve the separation of ammonia plant purge gases which contain ammonia as well as hydrogen and nitrogen, especially when there is no pretreatment of the purge gas to remove ammonia gas.
Inventors
- 👤 Bhupender S. Minhas
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-11-07 05:54
CPC Classifications
B; B01; B01D; B01D71/00; B01D71/06; B01D71/08; B01D71/12; B01D71/14; B01D71/18; B01D53/00; B01D53/22; C; C01; C01C; C01C1/00; C01C1/02; C01C1/04; C01C1/0405; C01C1/0476; Y; Y02; Y02P; Y02P20/00; Y02P20/50; Y02P20/52
Claims Analysis
Total Claims: 12
Claim 1
Independent Claim
204 words
A process for using a gas separation membrane to separate a feed gas stream having at least two components into a permeate fraction which passes through the membrane and is relatively rich in at least one of the feed gas components and residual fraction which does not pass through the membrane and is relatively depleted in at least one of the feed gas components wherein the gas separation membrane comprises a cellulose acetate butyrate polymer having the formula: ##STR2## in which: R each independently is OH, OOCCH 3 , and OOCCH 2 CH 2 CH 3 such that the weight percent of the OOCCH 2 CH 2 CH 3 groups in the polymer is about 10 to 45, the weight percent of OOCCH 3 groups in the polymer is about 2 to about 35, and the weight percent of OH groups in the polymer is about 0.8 to about 2; and n is selected so that the number average molecular weight of the polymer is at least about 20,000; and provided that the membrane has a carbon dioxide permeability of at least about 5 SCFH per ft 2 per 100 psi and a carbon dioxide to methane separation factor of at least about 21.
Claim 2
Dependent Claim
204 words
A process for using a gas separation membrane to separate a feed gas stream having at least two components into a permeate fraction which passes through the membrane and is relatively rich in at least one of the feed gas components and residual fraction which does not pass through the membrane and is relatively depleted in at least one of the feed gas components wherein the gas separation membrane comprises a cellulose acetate butyrate polymer having the formula: ##STR2## in which: R each independently is OH, OOCCH 3 , and OOCCH 2 CH 2 CH 3 such that the weight percent of the OOCCH 2 CH 2 CH 3 groups in the polymer is about 10 to 45, the weight percent of OOCCH 3 groups in the polymer is about 2 to about 35, and the weight percent of OH groups in the polymer is about 0.8 to about 2; and n is selected so that the number average molecular weight of the polymer is at least about 20,000; and provided that the membrane has a carbon dioxide permeability of at least about 5 SCFH per ft 2 per 100 psi and a carbon dioxide to methane separation factor of at least about 21.
Claim 3
Dependent Claim
40 words
A process of claim 1 wherein the gas separation membrane has a carbon dioxide permeability of at least about 10 SCFH per ft 2 per 100 psi and a carbon dioxide to methane separation factor of at least about 25.
Claim 4
Dependent Claim
16 words
A process of claim 2 wherein the feed gas comprises at least 0.5 volume percent ammonia.
Claim 5
Dependent Claim
21 words
A process of claim 1 wherein the cellulose acetate butyrate has a number average molecular weight between about 40,000 and 250,000.
Claim 6
Dependent Claim
55 words
A process of claim 1 wherein the weight percent of OOCCH 2 CH 2 CH 3 groups in the polymer is about 15 to 40, the weight percent of OOCCH 3 groups in the polymer is about 10 to 30, or the weight percent of OH groups in the polymer is about 1.5 to 1.8.
Claim 7
Dependent Claim
17 words
A process of claim 1 wherein the feed gas stream comprises at least 0.5 volume percent ammonia.
Claim 8
Dependent Claim
140 words
An asymmetric gas separation membrane comprising a cellulose acetate butyrate polymer having the formula: ##STR3## in which: R each independently is OH, OOCCH 3 , and OOCCH 2 CH 2 CH 3 such that the weight percent of the OOCCH 2 CH 2 CH 3 group in the polymer is about 10 to 45, the weight percent of OOCCH 3 groups in the polymer is about 2 to about 35, and the weight percent of OH groups in the polymer is about 0.8 to about 2; and n is selected so that the number average molecular weight of the polymer is at least about 20,000; and provided that the membrane has a carbon dioxide permeability of at least about 5 SCFH per ft 2 per 100 psi and a carbon dioxide to methane separation factor of at least about 21.
Claim 9
Dependent Claim
140 words
An asymmetric gas separation membrane comprising a cellulose acetate butyrate polymer having the formula: ##STR3## in which: R each independently is OH, OOCCH 3 , and OOCCH 2 CH 2 CH 3 such that the weight percent of the OOCCH 2 CH 2 CH 3 group in the polymer is about 10 to 45, the weight percent of OOCCH 3 groups in the polymer is about 2 to about 35, and the weight percent of OH groups in the polymer is about 0.8 to about 2; and n is selected so that the number average molecular weight of the polymer is at least about 20,000; and provided that the membrane has a carbon dioxide permeability of at least about 5 SCFH per ft 2 per 100 psi and a carbon dioxide to methane separation factor of at least about 21.
Claim 10
Dependent Claim
38 words
An asymmetric gas separation membrane of claim 7 having a carbon dioxide permeability of at least about 10 SCFH per ft 2 per 100 psi and a carbon dioxide to methane separation factor of at least about 25.
Claim 11
Dependent Claim
24 words
An asymmetric gas separation membrane of claim 7 wherein the cellulose acetate butyrate has a number average molecular weight between about 40,000 and 250,000.
Claim 12
Dependent Claim
58 words
An asymmetric gas separation membrane of claim 7 wherein the weight percent of OOCCH 2 CH 2 CH 3 groups in the polymer is about 15 to 40, the weight percent of OOCCH 3 groups in the polymer is about 10 to 30, or the weight percent of OH groups in the polymer is about 1.5 to 1.8.
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USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1995-03-17 | 1995-09-16 | 1996-03-17 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1999-03-17 | 1999-09-16 | 2000-03-17 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 2003-03-17 | 2003-09-16 | 2004-03-17 | $7700.00 | Window Closed / Lapsed |