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US4080743A Expired / Lapsed US ⏱️ 0.0 years remaining

Membrane drying process

Assignee: EIDP Inc
•
Filing: 1976-06-22
•
Granted: 1978-03-28
•
Expires: 1996-06-22
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Abstract

Abstract Process for drying a water-wet membrane by contacting with a solution of water miscible and water immiscible solvents and then removing the solution.

Inventors

  • 👤 Philip Manos

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-25 06:27
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0081; B01D67/0095; B01D12/00

Claims Analysis

Total Claims: 7
Claim 1
Independent Claim 198 words
In the process for drying a semipermeable polymeric membrane that is wet with an aqueous membrane-wetting liquid by contacting the wet membrane with at least one replacement liquid to remove water from the membrane, and removing the replacement liquid from the membrane; the improvement which comprises first contacting the wet semipermeable polymeric membrane in which the polymer has a Critical Surface Tension of at least 42 dynes per centimeter with at least one replacement liquid consisting essentially of a homogeneous solution of (a) a major portion of at least one organic solvent selected from the class consisting of hydrocarbons having 4-8 carbon atoms and perchlorofluorocarbons having 1-3 carbon atoms and (b) a minor portion of at least one organic solvent substantially miscible with water having a hydrogen bonding parameter of at least about 1.5 (calories per cubic centimeter) 1/2 , wherein the components of the replacement liquid each exhibit, at 20° C, a viscosity of less than about 10 centipoise and a molar volume of less than about 200 cubic centimeters per mole; and after water has been substantially completely removed from the membrane, evaporating the replacement liquid to obtain a membrane free of water and replacement liquid.
Claim 2
Dependent Claim 198 words
In the process for drying a semipermeable polymeric membrane that is wet with an aqueous membrane-wetting liquid by contacting the wet membrane with at least one replacement liquid to remove water from the membrane, and removing the replacement liquid from the membrane; the improvement which comprises first contacting the wet semipermeable polymeric membrane in which the polymer has a Critical Surface Tension of at least 42 dynes per centimeter with at least one replacement liquid consisting essentially of a homogeneous solution of (a) a major portion of at least one organic solvent selected from the class consisting of hydrocarbons having 4-8 carbon atoms and perchlorofluorocarbons having 1-3 carbon atoms and (b) a minor portion of at least one organic solvent substantially miscible with water having a hydrogen bonding parameter of at least about 1.5 (calories per cubic centimeter) 1/2 , wherein the components of the replacement liquid each exhibit, at 20° C, a viscosity of less than about 10 centipoise and a molar volume of less than about 200 cubic centimeters per mole; and after water has been substantially completely removed from the membrane, evaporating the replacement liquid to obtain a membrane free of water and replacement liquid.
Claim 3
Dependent Claim 19 words
A process of claim wherein the water miscible solvent comprises about from 2% to 10% of the homogeneous solution.
Claim 4
Dependent Claim 21 words
A process of claim 1 wherein the water-wet membrane is an asymmetric membrane having a dense skin on one surface thereof.
Claim 5
Dependent Claim 23 words
A process of claim 1 wherein the semi-permeable membrane is selected from nitrogen-linked aromatic polymers, sulfonated poly(arylene ether sulfones), and sulfonated poly(phenylene oxides).
Claim 6
Dependent Claim 29 words
A process of claim 1 wherein the major portion of the homogeneous solution consists essentially of 1,1,2-trichloro-1,2,2-trifluoroethane and the minor portion of the homogeneous solution consists essentially of methanol.
Claim 7
Dependent Claim 24 words
A process of claim 5 wherein the resulting liquid-wet membrane is subsequently contacted with substantially pure 1,1,2-trichloro-1,2,2-trifluoroethane and the 1,1,2-trichloro-1,2,2-trifluoroethane is removed by evaporation.

References Cited (Backward Citations)

US3342729A Cited
US3710945A Cited
US3592672A Cited
US3822202A Cited
US3899309A Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1981-03-27 1981-09-26 1982-03-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1985-03-27 1985-09-26 1986-03-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 1989-03-27 1989-09-26 1990-03-28 $7700.00 Window Closed / Lapsed

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