US4080743A
Expired / Lapsed
US
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Membrane drying process
Assignee: EIDP Inc
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Filing: 1976-06-22
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Granted: 1978-03-28
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Expires: 1996-06-22
Abstract
Abstract Process for drying a water-wet membrane by contacting with a solution of water miscible and water immiscible solvents and then removing the solution.
Inventors
- 👤 Philip Manos
Bibliographic Details
Application Number
—
Jurisdiction
US
Data Source
google_patents
Last Synchronized
2026-10-25 06:27
CPC Classifications
B; B01; B01D; B01D67/00; B01D67/0081; B01D67/0095; B01D12/00
Claims Analysis
Total Claims: 7
Claim 1
Independent Claim
198 words
In the process for drying a semipermeable polymeric membrane that is wet with an aqueous membrane-wetting liquid by contacting the wet membrane with at least one replacement liquid to remove water from the membrane, and removing the replacement liquid from the membrane; the improvement which comprises first contacting the wet semipermeable polymeric membrane in which the polymer has a Critical Surface Tension of at least 42 dynes per centimeter with at least one replacement liquid consisting essentially of a homogeneous solution of (a) a major portion of at least one organic solvent selected from the class consisting of hydrocarbons having 4-8 carbon atoms and perchlorofluorocarbons having 1-3 carbon atoms and (b) a minor portion of at least one organic solvent substantially miscible with water having a hydrogen bonding parameter of at least about 1.5 (calories per cubic centimeter) 1/2 , wherein the components of the replacement liquid each exhibit, at 20° C, a viscosity of less than about 10 centipoise and a molar volume of less than about 200 cubic centimeters per mole; and after water has been substantially completely removed from the membrane, evaporating the replacement liquid to obtain a membrane free of water and replacement liquid.
Claim 2
Dependent Claim
198 words
In the process for drying a semipermeable polymeric membrane that is wet with an aqueous membrane-wetting liquid by contacting the wet membrane with at least one replacement liquid to remove water from the membrane, and removing the replacement liquid from the membrane; the improvement which comprises first contacting the wet semipermeable polymeric membrane in which the polymer has a Critical Surface Tension of at least 42 dynes per centimeter with at least one replacement liquid consisting essentially of a homogeneous solution of (a) a major portion of at least one organic solvent selected from the class consisting of hydrocarbons having 4-8 carbon atoms and perchlorofluorocarbons having 1-3 carbon atoms and (b) a minor portion of at least one organic solvent substantially miscible with water having a hydrogen bonding parameter of at least about 1.5 (calories per cubic centimeter) 1/2 , wherein the components of the replacement liquid each exhibit, at 20° C, a viscosity of less than about 10 centipoise and a molar volume of less than about 200 cubic centimeters per mole; and after water has been substantially completely removed from the membrane, evaporating the replacement liquid to obtain a membrane free of water and replacement liquid.
Claim 3
Dependent Claim
19 words
A process of claim wherein the water miscible solvent comprises about from 2% to 10% of the homogeneous solution.
Claim 4
Dependent Claim
21 words
A process of claim 1 wherein the water-wet membrane is an asymmetric membrane having a dense skin on one surface thereof.
Claim 5
Dependent Claim
23 words
A process of claim 1 wherein the semi-permeable membrane is selected from nitrogen-linked aromatic polymers, sulfonated poly(arylene ether sulfones), and sulfonated poly(phenylene oxides).
Claim 6
Dependent Claim
29 words
A process of claim 1 wherein the major portion of the homogeneous solution consists essentially of 1,1,2-trichloro-1,2,2-trifluoroethane and the minor portion of the homogeneous solution consists essentially of methanol.
Claim 7
Dependent Claim
24 words
A process of claim 5 wherein the resulting liquid-wet membrane is subsequently contacted with substantially pure 1,1,2-trichloro-1,2,2-trifluoroethane and the 1,1,2-trichloro-1,2,2-trifluoroethane is removed by evaporation.
References Cited (Backward Citations)
USPTO Annuity & Maintenance Windows
| Annuity Stage | Window Opens | Payment Deadline | Surcharge Period Until | Estimated Fee | Status |
|---|---|---|---|---|---|
| 3.5 Years (Year 4) | 1981-03-27 | 1981-09-26 | 1982-03-28 | $2000.00 | Window Closed / Lapsed |
| 7.5 Years (Year 8) | 1985-03-27 | 1985-09-26 | 1986-03-28 | $3760.00 | Window Closed / Lapsed |
| 11.5 Years (Year 12) | 1989-03-27 | 1989-09-26 | 1990-03-28 | $7700.00 | Window Closed / Lapsed |