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US5084415A Expired / Lapsed US ⏱️ 0.0 years remaining

Metallization processing

Assignee: Nokia Bell Labs
•
Filing: 1989-10-23
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Granted: 1992-01-28
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Expires: 2009-10-23
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Abstract

Abstract When forming a metallization layer in integrated-circuit semiconductor device fabrication, metal such as tungsten, for example, adheres poorly to dielectrics such as, e.g., silicon oxide, and tends to flake off from wafer areas not covered by a glue layer- such areas typically including the backside and the edge of the wafer, and clip marks on the face of the wafer. The invention prevents flaking by processing including: forming an adhesive or glue layer on the dielectric, forming a metal layer, forming a protective layer on metal on the glue layer, and etching to remove metal not covered by the protective layer.

Inventors

  • 👤 Ajit S. Manocha
  • 👤 Virendra V. S. Rana

Bibliographic Details

Application Number —
Jurisdiction US
Data Source google_patents
Last Synchronized 2026-10-30 08:33
CPC Classifications
H; H10; H10P; H10P14/00; H10P14/40; H10P14/412

Claims Analysis

Total Claims: 23
Claim 1
Independent Claim 86 words
In the manufacture of integrated-circuit devices, a method for forming a metal layer on a dielectric layer on a substrate comprising a semiconductor-device face, characterized by forming an adhesive layer on said dielectric, forming a metal layer in part on said adhesive layer and in part on said dielectric, forming a protective layer on portions of said metal layer on the adhesive layer, said protective layer does not cover a peripheral region of said face, and etching to remove metal not covered by the protective layer.
Claim 2
Dependent Claim 86 words
In the manufacture of integrated-circuit devices, a method for forming a metal layer on a dielectric layer on a substrate comprising a semiconductor-device face, characterized by forming an adhesive layer on said dielectric, forming a metal layer in part on said adhesive layer and in part on said dielectric, forming a protective layer on portions of said metal layer on the adhesive layer, said protective layer does not cover a peripheral region of said face, and etching to remove metal not covered by the protective layer.
Claim 3
Dependent Claim 12 words
The method of claim 1 in which said peripheral region is circumferential.
Claim 4
Dependent Claim 13 words
The method of claim 1 in which forming said peripheral region comprises rinsing.
Claim 5
Dependent Claim 13 words
The method of claim 1 in which forming said peripheral region comprises wiping.
Claim 6
Dependent Claim 12 words
The method of claim 1 in which etching is by wet etching.
Claim 7
Dependent Claim 11 words
The method of claim 1 in which said metal comprises tungsten.
Claim 8
Dependent Claim 11 words
The method of claim 1 in which said metal comprises copper.
Claim 9
Dependent Claim 11 words
The method of claim 1 in which said metal comprises aluminum.
Claim 10
Dependent Claim 12 words
The method of claim 1 in which said dielectric comprises silicon oxide.
Claim 11
Dependent Claim 12 words
The method of claim 9 in which said dielectric further comprises boron.
Claim 12
Dependent Claim 12 words
The method of claim 9 in which said dielectric further comprises phosphorus.
Claim 13
Dependent Claim 14 words
The method of claim 9 in which said dielectric further comprises boron and phosphorus.
Claim 14
Dependent Claim 12 words
The method of claim 1 in which said dielectric comprises silicon nitride.
Claim 15
Dependent Claim 12 words
The method of claim 1 in which said dielectric comprises silicon oxynitride.
Claim 16
Dependent Claim 51 words
The method of claim 1 in which said metal is selected from the group consisting of tungsten and copper, in which said dielectric comprises a silicon oxide, and in which said adhesive layer comprises a material selected from the group consisting of titanium, titanium nitride, titanium-tungsten, titanium-aluminum, titanium-vanadium, titanium-yttrium, and polysilicon.
Claim 17
Dependent Claim 14 words
The method of claim 1 in which said protective layer comprises a polymeric material.
Claim 18
Dependent Claim 14 words
The method of claim 16 in which said polymeric material is a photoresist material.
Claim 19
Dependent Claim 13 words
The method of claim 17 in which etching comprises exposure to photoresist developer.
Claim 20
Dependent Claim 15 words
The method of claim 1 in which said metal is deposited by chemical vapor deposition.
Claim 21
Dependent Claim 20 words
The method of claim 1, further comprising lithographic patterning of said protective layer and corresponding etching of said metal layer.
Claim 22
Dependent Claim 101 words
In the manufacture of integrated-circuit devices, a method for forming a metal layer on a dielectric layer on a wafer comprising a semiconductor-device face, characterized by forming an adhesive layer on the dielectric overlying semiconductor-device structures, forming a metal layer in part on said adhesive layer and in part on said dielectric, forming a protective layer on a position of said metal layer on the adhesive layer, and etching to remove metal from an area comprising the backside and the edge of said wafer, and clip marks on the face of said wafer, thereby preventing metal from flaking off said area.
Claim 23
Dependent Claim 101 words
In the manufacture of integrated-circuit devices, a method for forming a metal layer on a dielectric layer on a wafer comprising a semiconductor-device face, characterized by forming an adhesive layer on the dielectric overlying semiconductor-device structures, forming a metal layer in part on said adhesive layer and in part on said dielectric, forming a protective layer on a position of said metal layer on the adhesive layer, and etching to remove metal from an area comprising the backside and the edge of said wafer, and clip marks on the face of said wafer, thereby preventing metal from flaking off said area.

References Cited (Backward Citations)

US4404235A Cited
US4845050A Cited
GB2181456A Cited
JPS62219945A Cited
EP0267730A2 Cited

USPTO Annuity & Maintenance Windows

Annuity Stage Window Opens Payment Deadline Surcharge Period Until Estimated Fee Status
3.5 Years (Year 4) 1995-01-27 1995-07-29 1996-01-28 $2000.00 Window Closed / Lapsed
7.5 Years (Year 8) 1999-01-27 1999-07-29 2000-01-28 $3760.00 Window Closed / Lapsed
11.5 Years (Year 12) 2003-01-27 2003-07-29 2004-01-28 $7700.00 Window Closed / Lapsed

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